Process for acid bleaching of lignocellulose-containing pulp with a magnesium compound
First Claim
1. A process for delignification and bleaching of a chemically digested lignocellulose-containing pulp, wherein the pulp is bleached at a pH in the range from about 1 up to about 6 with a bleaching chemical selected from the group consisting of chlorine dioxide, ozone, peracetic acid and acid peroxides, whereupon a water-soluble chemical containing magnesium is added at a pH in the range from about 1 up to about 7 and in an amount of from about 0.01 up to about 10 kg/ton of dry pulp, calculated as magnesium, and that subsequently the pulp is bleached with hydrogen peroxide at a pH of from about 8 up to about 12.
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Abstract
A process for delignification and bleaching of chemically digested lignocellulose-containing pulp. In a first embodiment, the pulp is acid treated at a pH of between about 1 and about 6, whereupon a water-soluble compound containing an alkaline earth metal is added at a pH of between about 1 and about 7 before the pulp is treated with a chlorine-free bleaching agent. In a second embodiment, the acid and alkaline earth metal treatments are carried out in a single step. The chlorine-free bleaching agent includes peroxide compounds, ozone, oxygen and sodium dithionite in an optional sequence or mixture. After the treatment according to the invention, the pulp may be finally bleached to the desired brightness, suitably with a chlorine-free bleaching agent, such as ozone, to completely avoid formation and discharge of AOX.
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Citations
9 Claims
- 1. A process for delignification and bleaching of a chemically digested lignocellulose-containing pulp, wherein the pulp is bleached at a pH in the range from about 1 up to about 6 with a bleaching chemical selected from the group consisting of chlorine dioxide, ozone, peracetic acid and acid peroxides, whereupon a water-soluble chemical containing magnesium is added at a pH in the range from about 1 up to about 7 and in an amount of from about 0.01 up to about 10 kg/ton of dry pulp, calculated as magnesium, and that subsequently the pulp is bleached with hydrogen peroxide at a pH of from about 8 up to about 12.
Specification