Composition based on a blend of inorganic fibers and inorganic fiber whiskers

• US 6,402,951 B1
• Filed: 06/28/2000
• Issued: 06/11/2002
• Est. Priority Date: 02/05/1999
• Status: Expired due to Fees

• Current Assignee: HITCO Carbon Composites, Inc. (Sgl Carbon Se)
• Original Assignee: HITCO Carbon Composites, Inc. (Sgl Carbon Se)
• Inventors: Awasthi, Shrikant, Pruett, Gary, Wilson, Doug
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US09/605,906
• Time in Patent Office: 713 Days
• Field of Search: 210/505, 210/503, 210/508, 210/651, 210/500.26, 210/500.25, 210/509, 210/198.2, 555/23, 555/24, 428/224, 428/359, 428/408, 428/315.5, 162/146, 162/152, 501/95.3, 501/96.5, 264/43
• US Class Current: 210/500.25
• CPC Class Codes: B01D 2239/0492 on fibres
• CPC Class Codes: B01D 2239/0613 Woven
• CPC Class Codes: B01D 2239/0618 Non-woven
• CPC Class Codes: B01D 2239/064 The fibres being mixed
• CPC Class Codes: B01D 2239/086 Binders between particles or fibres
• CPC Class Codes: B01D 2239/1225 Fibre length
• CPC Class Codes: B01D 2239/1233 Fibre diameter
• CPC Class Codes: B01D 2239/1258 Permeability
• CPC Class Codes: B01D 39/2065 the material being fibrous
• CPC Class Codes: B01D 39/2082 the material being filamentary or fibrous
• CPC Class Codes: Y10T 428/249978 Voids specified as micro
• CPC Class Codes: Y10T 428/2904 Staple length fiber
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 442/30 Woven fabric [i.e., woven strand or strip material]
• CPC Class Codes: Y10T 442/50 FELT FABRIC
• CPC Class Codes: Y10T 442/60 Nonwoven fabric [i.e., nonwoven strand or fiber material]

Abstract

A filter media structure, which is capable of operating in the micro- and nanofiltration regime, offers: low cost, durability, high temperature and chemical resistance, high permeability, high flow rate, low pressure drop across the filter media, high mechanical strength, separation efficiency, and biocompatibility. The filter media structure is comprised of mixture of carbon or ceramic fibers and inorganic fiber whiskers generally having a diameter of from about 0.03 to about 5 microns. The present invention further provides a method of preparing a filter media structure comprising mixing together a) inorganic fibers; b) inorganic fiber whiskers; c) a water soluble binder, and optionally depositing a thin layer of pyrolytic carbon on the surface of the inorganic fibers and inorganic fiber whiskers comprising the filter media structure. The filter media structure is selected from the group consisting of a paper, felt and fabric. The present invention provides a further method for preparing a filter media structure comprising a) mixing together inorganic fiber whiskers and a resin selected from the group consisting of thermosetting and thermoplastic resins; b) impregnating inorganic fibers with said inorganic fiber whisker/resin mixture to form a paper.

Claims

1. A method for preparing a filter media structure comprising inorganic fibers, inorganic fiber whiskers and a binder comprising:

a) mixing together inorganic fibers;

inorganic fiber whiskers;

a binder and water to form a slurry;

b) removing the excess water from the slurry;

c) drying said slurry at a temperature sufficient to fuse the binder to form said filter media structure; and

d) carbonizing said filter media structure.

2. The method according to claim 1, wherein the filter media structure is selected from the group consisting of papers, felts, needled felts, non-woven fabrics and woven fabrics.

3. The method according to claim 1, further comprising the step of depositing a thin layer of pyrolytic carbon on the surface of the inorganic fibers and inorganic fiber whiskers in the formed filter media structure.

4. The method according to claim 1, wherein the inorganic fibers are selected from the group consisting of carbon and ceramic fibers.

5. The method according to claim 4, wherein the carbon fibers are derived from a precursor selected from the group consisting of PAN, pitch or rayon.

6. The method according to claim 4, wherein the ceramic fibers are selected from the group consisting of silicon carbide, silicon nitride, aluminosilicate, glass, silica, alumina, ceria, zirconia and mixtures thereof.

7. The method according to claim 1, wherein the inorganic fiber whiskers are selected from the group consisting of carbon, silicon carbide, silicon nitride, titanium carbide, titanium nitride, alumina, silica, zirconia, ceria, glass and mixtures thereof.

8. The method according to claim 1, wherein the filter media comprises from about 5 to about 95 volume percent inorganic fibers and from about 5 to about 95 volume percent inorganic fiber whiskers, based on the total volume of the inorganic fibers and the inorganic fiber whiskers.

9. The method according to claim 1, wherein the inorganic fiber whiskers are about 3 to about 5000 microns in length.

10. The method according to claim 1, wherein the diameter of the inorganic fiber whiskers is from about 0.03 to about 5 microns.

11. The method according to claim 1, wherein the diameter of the inorganic fibers is from about 3 to about 100 microns.

12. The method according to claim 1, wherein said binder is water soluble.

13. The method according to claim 12, wherein said water soluble binder is selected from the group consisting of polyvinyl alcohol, sodium alginate, water soluble phenolics.

14. The method according to claim 1, wherein said filter media has a pore size distribution sufficiently small to capture particles in the size range of about 0.05 to about 100 microns.

15. The method according to claim 1, wherein, said filter media provides a pore size distribution sufficiently small to trap particles in the size range of about 0.1 to about 10 microns.

16. A method for preparing a filter media structure comprising inorganic fibers, inorganic fiber whiskers and a binder comprising:

a) mixing together inorganic fiber whiskers and a resin binder to form a mixture;

b) impregnating said inorganic fibers with said inorganic fiber whisker/resin binder mixture to form a filter media structure having a random assemblage of impregnated fibers and fiber whiskers;

c) carbonizing said inorganic fiber whisker/resin binder impregnated inorganic fiber filter media structure; and

optionally

d) depositing pyrolytic carbon on the surface of the fibers in said inorganic fiber whisker/resin binder impregnated inorganic fiber filter media structure.

17. The method according to claim 16, wherein said resin is selected the group consisting of acrylic, polyester and phenolic resins.

18. The method according to claim 16, wherein said carbon is derived from a chemical vapor deposition process.

19. The method according to claim 16, wherein said inorganic fiber whiskers and said resin are mixed in a high shear mixer.

20. The method according to claim 16, wherein the inorganic fibers are selected from the group consisting of carbon fibers and ceramic fibers.

21. The method according to claim 20, wherein the carbon fibers are derived from a precursor selected from the group consisting of PAN, pitch or rayon.

22. The method according to claim 20, wherein the ceramic fibers are selected from the group consisting of silicon carbide, silicon nitride, aluminosilicate glass, silica alumina, ceria, zirconia and mixtures thereof.

23. The method according to claim 16, wherein the inorganic fiber whiskers are selected from the group consisting of carbon, silicon carbide, silicon nitride, titanium carbide, titanium nitride, alumina, ceria, silica, zirconia and mixtures thereof.

24. The method according to claim 16, wherein the filter media comprises about 5 to about 95 volume percent inorganic fibers and from about 5 to about 95 volume percent inorganic fiber whiskers based on the total volume of the inorganic fibers and the fiber whiskers.

25. The method according to claim 16, wherein the inorganic fiber whiskers are about 3 to about 5000 microns in length.

26. The method according to claim 16, wherein the diameter of the inorganic fiber whiskers is from about 0.03 to about 5 microns.

27. The method according to claim 16, wherein the diameter of the inorganic fibers is about 3 to about 100 microns.

28. A composition of matter comprising a blend of inorganic fibers, inorganic fiber whiskers and one of (i) a fused binder or (ii) a fused and carbonized binder.

29. The composition of matter of claim 28, wherein the inorganic fibers are selected from the group consisting of carbon fiber and ceramic fibers.

30. The composition of matter of claim 29, wherein the carbon fibers are derived from a precursor fiber selected from the group consisting of PAN, pitch or rayon.

31. The composition of matter of claim 29, wherein the ceramic fibers are selected from the group consisting of silicon carbide, silicon nitride, aluminosilicate, glass, silica, alumina, zirconia, ceria and mixtures thereof.

32. The composition of matter of claim 28, wherein the inorganic fiber whiskers are selected from the group consisting of carbon, silicon carbide, silicon nitride, titanium carbide, titanium nitride, alumina, zirconia, ceria, silica, glass and mixtures thereof.

33. The composition of matter of claim 28, wherein the composition comprises about 5 to about 95 weight percent inorganic fibers and wherein the composition comprises about 5 to about 95 weight percent inorganic fiber whiskers, based on the total volume of the inorganic fibers and the fiber whiskers.

34. The composition of matter of claim 28, wherein the fiber whiskers are from about 3 to about 5000 microns in length.

35. The composition of matter of claim 28, the fiber whiskers have a range of about 5 to about 300 microns in length.

36. The composition of matter of claim 28, wherein the average diameter of the inorganic fiber whiskers is from about 0.03 to about 5 microns.

37. The composition of matter of claim 36, wherein the average diameter of the inorganic fiber whiskers is from about 0.03 to about 0.2 microns.

38. The composition of claim 36, wherein the average length of the inorganic fibers is from about 1 to about 15 millimeters.

39. The composition of matter of claim 28, wherein the average diameter of the inorganic fibers is from about 3 to about 100 microns.

40. The composition of matter of claim 28, wherein the composition is provided as a structure is selected from the group consisting of paper, felt, needled felt, woven fabric and non-woven fabric.

41. The composition of matter of claim 28, wherein said composition has a permeability as measured by a pressure drop across the composition from about 0.1 millibar to about 500 millibar.

42. The composition of matter of claim 28, wherein said composition has a permeability as measured by a pressure drop across the composition from about 15 millibar to about 500 millibar.

43. The composition of matter of claim 28, having a flow rate through the composition from about 10 liters/m²/h to about 25,000 liters/m²/h.

44. The composition of matter of claim 28, wherein said composition has strength sufficient to resist loads imparted by fluctuating pressures.

45. The composition of matter of claim 28, wherein said composition comprises carbon fibers and carbon whiskers, and wherein said composition is operable at temperatures of from the freezing point of the first condensing gas to about 500°

C. in air and up to about 3000°

C. in a non-oxidizing atmosphere.

46. The composition of matter of claim 28, wherein said composition comprises ceramic fibers and ceramic whiskers, and wherein said composition is operable at temperatures of up to about two-thirds of the lowest melting temperature of the ceramic fibers and whiskers comprising said composition.

47. The composition of claim 28, wherein the binder is fused and carbonized.

48. The composition of claim 47, wherein said wherein the inorganic fibers are selected from the group consisting of carbon fibers and ceramic fibers.

49. The composition of claim 47, wherein the carbon fibers are derived from a precursor fiber selected from the group consisting of PAN, pitch or rayon, and wherein the ceramic fibers are selected from the group consisting of silicon carbide, silicon nitride, aluminosilicate, glass, silica, alumina, zirconia, ceria and mixtures thereof.

50. The composition of claim 47, wherein the inorganic fiber whiskers are selected from the group consisting of carbon, silicon carbide, silicon nitride, titanium carbide, titanium nitride, alumina, zirconia, ceria, silica, glass and mixtures thereof.

51. The composition of claim 47, wherein the composition comprises about 5 to about 95 weight percent inorganic fibers and wherein the composition comprises about 5 to about 95 weight percent inorganic fiber whiskers, based on the total volume of the inorganic fibers and the fiber whiskers.

52. The composition of claim 47, wherein the fiber whiskers are from about 3 to about 5000 microns in length, and wherein the average diameter of the inorganic fiber whiskers is from about 0.03 to about 5 microns.

53. The composition of claim 47, wherein the fibers are from about 1 to about 15 millimeters in length, and wherein the average diameter of the fibers is from about 3 to about 100 microns.

54. The composition of claim 47, having an average pore size and pore size distribution sufficiently small to capture particles in the size range of about 0.05 to about 100 microns.

55. The composition of claim 47, wherein the composition is selected from the group consisting of paper, felt, needled felt, woven fabric and non-woven fabric.

56. The composition of claim 47, wherein said composition has a permeability as measured by a pressure drop across the composition from about 0.1 millibar to about 500 millibar, and a flow rate through the composition from about 10 liters/m²h to about 25,000 liters/m²/h.