Alumina trihydrate derived high pore volume, high surface area aluminum oxide composites and methods of their preparation and use

• US 6,403,526 B1
• Filed: 01/13/2000
• Issued: 06/11/2002
• Est. Priority Date: 12/21/1999
• Status: Expired due to Fees

• Current Assignee: W.R. Grace & Co.-Conn. (WR Grace & Company)
• Original Assignee: W R Grace & Company - CONN (WR Grace & Company)
• Inventors: Lussier, Roger Jean, Wallace, Michael David
• Primary Examiner(s): Griffin, Steven P.
• Assistant Examiner(s): JOHNSON, EDWARD M
• Application Number:
  US09/482,735
• Time in Patent Office: 880 Days
• Field of Search: 502/434, 502/355, 502/203, 502/217, 502/208, 502/344, 502/340, 502/628, 502/325, 502/305, 428/402, 428/403, 428/402.24
• US Class Current: 502/439
• CPC Class Codes: B01J 21/04 Alumina
• CPC Class Codes: B01J 21/12 Silica and alumina
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/40 characterised by dimensions, e.g. grain size in a colloidal state B01J35/23; crystallite size B01J35/77
• CPC Class Codes: B01J 35/613 10-100 m2/g
• CPC Class Codes: B01J 35/633 less than 0.5 ml/g
• CPC Class Codes: B01J 35/638 more than 1.0 ml/g
• CPC Class Codes: B01J 35/647 2-50 nm
• CPC Class Codes: B01J 35/651 50-500 nm
• CPC Class Codes: B01J 35/66 Pore distribution
• CPC Class Codes: B01J 35/67 monomodal
• CPC Class Codes: C01F 7/02 Aluminium oxide; Aluminium hydroxide; Aluminates
• CPC Class Codes: C01F 7/448 using superatmospheric pressure, e.g. hydrothermal conversion of gibbsite into boehmite
• CPC Class Codes: C01P 2002/60 Compounds characterised by their crystallite size
• CPC Class Codes: C01P 2004/50 Agglomerated particles
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C01P 2006/12 Surface area
• CPC Class Codes: C01P 2006/14 Pore volume
• CPC Class Codes: C01P 2006/16 Pore diameter
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/2991 : Coated

Abstract

Porous composite particles are provided which comprise an aluminum oxide component, e.g., crystalline boehmite having a crystallite size of from about 20 to about 200 Angstroms and additive component residue, e.g., silicate, phosphate, of a crystal size growth inhibitor, intimately dispersed within the aluminum oxide component. The aluminum oxide component of the composite particles are derived from a mixture of alumina trihydrate (e.g., gibbsite) and an alumina seed component, i.e., active alumina, which are both converted to crystalline boehmite in the presence of the additive component. Also provided is a method for making the composite particles, agglomerate particles derived therefrom, and a process for hydroprocessing petroleum feedstock using the agglomerates.

Claims

1. Porous composite particles comprising an aluminum oxide component and at least one additive component residue of a crystal size growth inhibitor dispersed within the aluminum oxide component, wherein said composite particles have:

(A) a specific surface area of at least about 80 m²/g;

(B) an average nitrogen pore diameter of from about 60 to about 1,000 Angstroms;

(C) a total nitrogen pore volume of from about 0.2 to about 2.5 cc/g; and

(D) an average particle diameter of from about 1 to about 15 microns.

 

and wherein in said composite particles;

(i) the alumina oxide component comprises at least 70 wt. % (a) crystalline boehmite having an average crystallite size of from about 20 to about 200 Angstroms;

(b) gamma alumina derived from said crystalline boehmite;

or (c) mixtures thereof;

(ii) the additive component residue is derived from at least one ionic compound having a cation and an anion wherein the cation is selected from the group of ammonium, alkali metal cation, and alkaline earth metal cation and mixtures thereof and the anion is selected from the group of hydroxyl, silicate, phosphate, sulfate and mixtures thereof, and is present in the composite particles at an amount of from about 0.5 to about 10 wt. %, based on the combined weight of the aluminum oxide component, and additive component residue.

2. The porous composite particles of claim 1 wherein the aluminum oxide component is derived from a mixture of gibbsite and active alumina.

3. The porous composite particles of claim 1 wherein the additive component residue is derived from a mixture of at least one silicate and at least one hydroxide.

4. The porous composite particles of claim 2 wherein the added component residue is derived from a mixture of at least one silicate and at least one phosphate.

5. The porous composite particles of claim 1 wherein the nitrogen pore volume is characterized as having:

(i) a macropore content of not greater than about 75% of the total pore volume;

(ii) a mesopore content of from about 15 to about 90% of the total nitrogen pore volume and wherein at least about 20% of the pores in the mesopore region have a diameter of from about 100 to about 400 Angstroms; and

(iii) a micropore content of not greater than about 80% of the total nitrogen pore volume.

6. The porous composite particles of claim 2 wherein the additive component residue is derived from a mixture of at least one silicate, at least one phosphate and at least one swellable clay.

7. The porous composite particles of any one of claims 2 to 6 wherein the additive component residue is present therein at from about 0.5 to about 5 wt. % based on the weight of the aluminum oxide component and additive component residue in the composite particles.

8. The porous composite particles of claim 2 wherein the average crystallite size of the boehmite present therein is from about 30 to about 150 Angstroms.

9. The porous composite particles of claim 8 wherein the surface area is from about 150 to about 450 m²/g, the total nitrogen pore volume is from about 0.5 to about 2.4 cc/g, and the average pore diameter is from about 80 to about 500 Angstroms.

10. Porous composite of claim 2 wherein the additive component residue comprises at least one member derived from the group of ammonium sulfate, ammonium phosphate, alkali metal silicate, dialkali metal silicate, tetra alkali metal silicate, dialkali metal phosphate, alkali metal polyphosphate, and alkali metal sulfate.

11. A process for making porous composite particles having a surface area of at least 80 m²/g, a total nitrogen pore volume of from about 0.2 to about 2.5 cc/g, and an average pore diameter of from about 60 to about 1,000 Angstroms comprising:

(A) admixing (i) alumina trihydrate, (ii) liquid medium capable of solubilizing at least a portion of the alumina trihydrate under hydrothermal treatment conditions, (iii) at least one active alumina seed component, and (iv) at least one additive component selected from the group of (a) at least one alkali or alkaline earth metal hydroxide or ammonium;

silicate, phosphate or sulfate and (b) swellable clay, and (c) mixtures thereof in a manner and under conditions sufficient to disperse the alumina trihydrate and alumina seed component as particles in the liquid medium;

(B) hydrothermally treating a dispersion provided in accordance with step A at a temperature and for a time sufficient to convert the active alumina and alumina trihydrate to crystalline boehmite having an average crystallite size of from about 20 to about 200 Angstroms and to form composite particles comprising residue of said additive component dispersed within said crystalline boehmite slurried in the liquid medium;

(C) removing the liquid medium from the composite particles provided in accordance with step B.

12. The process of claim 11 wherein the aluminum trihydrate is gibbsite.

13. The process of claim 12 wherein the gibbsite is separately milled to an average particle size of from about 5 to about 20 microns prior to contact with the active alumina and the additive component.

14. The process of claim 12 wherein the gibbsite, active alumina and additive component are co-milled prior to hydrothermal treatment to impart an average particle size to the gibbsite and active alumina of from about 0.1 to about 15.0 microns.

15. The process of claim 12 wherein the resulting composite particles are washed with an ammonium sulfate solution.

16. The process of claim 12 wherein the additive component comprises a mixture of at least one silicate and at least one hydroxide.

17. The process of claim 12 wherein the additive component comprises a mixture of at least one silicate and at least one phosphate.

18. The process of claim 12 wherein the additive component comprises a mixture of at least one silicate and at least one swellable clay.

19. The process of claim 12 wherein the additive component comprises a mixture of at least one silicate, at least one phosphate, and at least one swellable clay.

20. The process of claim 19 wherein the swellable clay is selected from the group consisting of montmorillonite, hectorite and saponite.

21. The process of claim 19 wherein the additive component comprises at least one member selected from the group of ammonium sulfate, ammonium phosphate, alkali metal silicate, dialkali metal silicate, tetra alkali metal silicate, dialkali metal phosphate, alkali metal polyphosphate, alkali metal sulfate, montmorillonite clay, hectorite clay and saponite clay.

22. Porous agglomerate particles comprising constituent composite particles of an additive component residue dispersed within an aluminum oxide component, wherein:

(A) the agglomerate particle size is from about 0.5 to about 5 mm;

(B) the aluminum oxide component comprises at least 70 wt. % (a) crystallite boehmite having a crystallite size of from about 20 to about 200 Angstroms; and

(b) gamma alumina derived from said crystalline boehmite;

or (c) mixtures thereof;

(C) the additive component residue is (i) present within the aluminum oxide component at an amount of from about 0.5 to about 10 wt. %, based on the combined weight of the aluminum oxide component and additive, component residue, and (ii) derived from at least one ionic compound having a cation and an anion wherein the cation is selected from the group consisting of ammonium, alkali metal cation, and alkaline earth metal cation and mixtures thereof and the anion is selected from the group consisting of hydroxyl, silicate, phosphate, sulfate and mixtures thereof.

23. The porous agglomerate particles of claim 22 wherein the support agglomerate particles possess:

(i) a specific surface area of at least about 100 m²/g;

(ii) an average pore diameter of from about 50 to 500 Angstroms; and

(iii) a total mercury pore volume of from about 0.2 to about 2.5 cc/g.

24. The porous agglomerate particles of claim 22 wherein the aluminum oxide component is derived from a mixture of gibbsite and active alumina.

25. The porous agglomerate particles of claim 22 wherein the additive component residue is derived from a mixture of at least one silicate and at least one hydroxide.

26. The porous agglomerate particles of claim 22 wherein the additive component residue is derived from a mixture of at least one silicate and at least one phosphate.

27. The porous agglomerate particles of claim 22 wherein the additive component residue is derived from a mixture of at least one silicate, at least one phosphate, and at least one hydroxide.

28. The porous agglomerate particles of claim 22 wherein the additive component residue is derived from a mixture of at least one silicate, at least one phosphate and at least one swellable clay.

29. The porous agglomerate particles of claim 22 wherein the additive component residue comprises at least one member selected from the group consisting of ammonium sulfate, ammonium phosphate, alkali metal silicate, dialkali metal silicate, tetra alkali metal silicate, dialkali metal phosphate, alkali metal polyphosphate, alkali metal sulfate, montmorillonite clay, hectorite clay and saponite clay.

30. The porous agglomerate particles of claim 22 wherein the additive component residue is present therein at from about 0.5 to about 5 wt. % based on the combined weight of the aluminum oxide and additive component residue.

31. The agglomerate particles of any one of claims 22 to 30 impregnated with an amount of at least one catalyst component effective to hydroprocess petroleum feedstock.

32. The agglomerate particles of any one of claims 22 to 30 impregnated with at least one hydrogenation component of a metal having hydrogenation activity selected from the group consisting of Group VIII and Group VIA metals of the Periodic Table.

33. The agglomerate particles of claim 22 which have been calcined at a temperature of from about 300 to about 900°

C. for a period of from about 0.1 to about 4 hours.

34. In a process for the hydroprocessing of petroleum feedstock wherein said feedstock is contacted with hydrogen under pressure in the presence of a supported hydroprocessing catalyst, the improvement comprising utilizing porous agglomerate particles as the support for the supported catalyst wherein said porous agglomerate particles comprise constituent composite particles of an additive component residue dispersed within an aluminum oxide component wherein:

(A) the agglomerate particle size is from about 0.5 to about 5 mm;

(B) the aluminum oxide component comprises at least 70 wt. % crystalline boehmite having a crystallite size of from about 20 to about 200 Angstroms; and

(b) gamma alumina derived from said crystalline boehmite;

or (c) mixtures thereof;

(C) the additive component residue is (i) present within the aluminum oxide component at an amount of from about 0.5 to about 10 wt. % based on the combined weight of the aluminum oxide component and additive component residue and (ii) derived from at least one ionic compound having a cation and an anion wherein the cation is selected from the group consisting of ammonium, alkali metal cation, alkaline earth metal cation, and mixtures thereof and the anion is selected from the group of hydroxyl, silicate, phosphate, sulfate and mixtures thereof.

35. The process of claim 34 wherein the support agglomerate particles possess:

(i) a specific surface area of at least about 100 m²/g;

(ii) an average pore diameter of from about 50 to 500 Angstroms; and

(iii) a total mercury pore volume of from about 0.2 to about 2.5 cc/g.

36. Porous composite particles comprising an aluminum oxide component and additive component residue dispersed within the aluminum oxide component, and having:

(A) a specific surface area of at least about 80 m²/g;

(B) an average nitrogen pore diameter of from about 60 to 1,000 Angstroms; and

(C) a total nitrogen pore volume of from about 0.2 to about 2.5 cc/g; and

 

prepared by the process comprising;

(A) admixing (i) alumina trihydrate, (ii) liquid medium capable of solubilizing at least a portion of the alumina trihydrate under hydrothermal treatment conditions, (iii) at least one active alumina seed component, and (iv) at least one additive component selected from the group consisting of (a) alkali or alkaline earth metal hydroxide, silicate, phosphate or sulfate and (b) swellable clay, in a manner and under conditions sufficient to disperse the alumina trihydrate and alumina seed component as particles having an average particle size of from about 1 to about 15 microns in the liquid medium;

(B) hydrothermally treating a dispersion provided in accordance with step A at a temperature and for a time sufficient to convert the active alumina and alumina trihydrate to crystalline boehmite having an average crystallite size of from about 20 to about 200 Angstroms and to form composite particles comprising residue of said additive component dispersed within said crystalline boehmite slurried in the liquid medium;

(C) removing the liquid medium from the composite particles provided in accordance with step B.