Method for forming high performance surface coatings and compositions of same

• US 6,410,086 B1
• Filed: 11/26/1999
• Issued: 06/25/2002
• Est. Priority Date: 11/26/1999
• Status: Expired due to Fees

• Current Assignee: Iscar Limited (Berkshire Hathaway Incorporated), Cerel (Ceramics Technologies) Ltd.
• Original Assignee: Iscar Limited (Berkshire Hathaway Incorporated), Cerel (Ceramics Technologies) Ltd.
• Inventors: Layyous, Albir A., Cherniak, Ludmilla, Barsky, Alex, Brandon, David G., Gal-Or, Leah, Goldner, Ron, Gilboa, Shay, Lanir, Ronen
• Primary Examiner(s): CHEN, BRET P
• Application Number:
  US09/449,958
• Time in Patent Office: 942 Days
• Field of Search: 427/249.2, 427/248.1, 427/569, 427/596, 427/255.12, 427/586, 204/489, 204/491, 204/471, 204/484
• US Class Current: 427/248.1
• CPC Class Codes: C23C 16/045 Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
• CPC Class Codes: C23C 26/00 Coating not provided for in groups C23C2/00 - C23C24/00
• CPC Class Codes: C23C 28/04 only coatings of inorganic non-metallic material
• CPC Class Codes: C25D 13/22 Servicing or operating apparatus or multistep processes

Abstract

A method of forming on an object a surface coating having a high mechanical strength and chemical and physical stability above 700° C. is disclosed. The method comprises (a) electrophoretically depositing at least one surface coating material on a surface of the object for obtaining a green coating on the surface; and (b) infiltrating into and depositing onto the green coating at least one additional surface coating material by a gas-phase infiltration/deposition method, thereby forming a high performance surface coating, wherein, the at least one surface coating material and the at least one additional surface coating material are chemically and physically stable above 700° C.

Claims

1. A method for forming on an object a high performance surface coating having high mechanical strength exhibiting hardness and wear resistance, and, high thermal and chemical durabilities, the method comprising the steps of:

(a) electrophoretically depositing at least one surface coating material on a surface of the object for obtaining a green coating on said surface of the object; and

(b) infiltrating into and depositing onto said green coating at least one additional surface coating material by a gas-phase infiltration/deposition method, thereby forming the high performance surface coating;

wherein, at least one of said at least one surface coating material and said at least one additional surface coating material is chemically and physically stable above 700°

C.

2. The method of claim 1, wherein said step of infiltrating into and depositing onto said green coating said at least one additional surface coating material by said gas-phase infiltration/deposition method is performed in a temperature range of between about 350°

C. to about 1200°

C.

3. The method of claim 1, wherein said gas-phase infiltration/deposition method includes chemical vapor infiltration/deposition (CVI/D).

4. The method of claim 3, wherein said method of chemical vapor infiltration/deposition (CVI/D) is selected from the group consisting of non-plasma CVD, plasma assisted CVD (PACVD), and plasma CVD (PCVD).

5. The method of claim 4, wherein said non-plasma CVD is selected from the group consisting of hot wall reactor CVD and laser enhanced CVD.

6. The method of claim 4, wherein said plasma assisted CVD (PACVD) is selected from the group consisting of induction heating PACVD and hot filament PACVD.

7. The method of claim 4, wherein said plasma CVD (PCVD) is selected from the group consisting of DC PCVD, RF induction PCVD and microwave PCVD.

8. The method of claim 1, wherein said step of electrophoretically depositing said at least one surface coating material on said surface of the object includes the step of preparing an EPD suspension including said at least one surface coating material in powdered form, a polar organic liquid, and optionally, at least one additive.

9. The method of claim 8, wherein said at least one additive is selected from the group consisting of a ceramic powder, a pH and conductivity adjusting agent, a charging and surface active dispersing agent, and a binding agent.

10. The method of claim 9, wherein said pH and conductivity adjusting agent is selected from the group consisting of a phosphate ester, acetic acid, and hydrochloric acid.

11. The method of claim 9, wherein said charging and surface active dispersing agent is selected from the group consisting of acetylacetone, phosphate ester, and polyacrylic acid.

12. The method of claim 9, wherein said binding agent is selected from the group consisting of menhaden (fish) oil, polyvinyl butyral, polyvinyl alcohol, polyvinyl acid, nitrocellulose, and shellac.

13. The method of claim 8, wherein said polar organic liquid is an alcohol.

14. The method of claim 13, wherein said alcohol is selected from the group consisting of ethanol, methanol, and isopropanol.

15. The method of claim 1, wherein said step of electrophoretically depositing said at least one surface coating material on said surface of the object is performed by passing direct electrical current between electrodes of an electrophoretic cell including an EPD suspension featuring said at least one surface coating material, said step of passing said direct electrical current is effected according to a mode selected from the group consisting of constant current and constant voltage.

16. The method of claim 1, wherein each of said at least one surface coating material and each of said at least one additional surface coating material is selected from the group consisting of a high performance base material, a high performance base material strengthening agent, and diamond.

17. The method of claim 1 wherein said surface of the object is selected from the group consisting of a high performance base material and a high performance base material strengthening agent.

18. The method of claim 17, wherein said high performance base material is selected from the group consisting of a metal alloy, a metal carbide, a metal nitride, a metal boride, a cemented carbide, a ceramic, a cermet, and a semiconductor material.

19. The method of claim 17, wherein said high performance base material strengthening agent is selected from the group consisting of a said high performance base material, a non-metal carbide, a non-metal nitride, and a metal carbide/nitride mixture.

20. The method of claim 19, wherein said non-metal nitride includes boron nitride of a specific morphologic and crystallographic form, said crystallographic form includes cubic.