Method for handling waste oil

• US 6,414,183 B1
• Filed: 04/05/2000
• Issued: 07/02/2002
• Est. Priority Date: 04/05/1999
• Status: Expired due to Term

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Sakamoto, Kazuhiko, Nakahara, Sei, Ueoka, Masatoshi
• Primary Examiner(s): Killos, Paul J.
• Assistant Examiner(s): Deemie, Robert W.
• Application Number:
  US09/543,743
• Time in Patent Office: 818 Days
• Field of Search: 560/218, 560/205, 560/210, 560/211, 560/212, 562/523, 562/531-535, 562/544, 562/546, 562/547, 562/600
• US Class Current: 560/218
• CPC Class Codes: C07C 51/252 of propene, butenes, acrolein or methacrolein
• CPC Class Codes: C07C 51/42 Separation; Purification; Stabilisation; Use of additives
• CPC Class Codes: C07C 57/04 Acrylic acid; Methacrylic acid
• CPC Class Codes: C07C 67/39 by oxidation of groups which are precursors for the acid moiety of the ester
• CPC Class Codes: C07C 69/54 Acrylic acid esters; Methacrylic acid esters

Abstract

The present invention provides a method for stabilizing waste oil which is taken of each chemical apparatus of the manufacturing line of (meth)acryl acid and/or ester thereof, and treating the waste oil such as draining it out of the production apparatus, for example, a distillation tower from its bottom, sending and transporting it by a pump through a pipeline, and storing it in a storage tank in a simple manner while keeping the waste oil in a stable state. The waste oil can be stabilized by coexisting with solvent.

The solvent used in the present invention is typically at least one selected from the group consisting of water, alcohol, ether, carboxylic acid, ketone, aromatic hydrocarbons, and aliphatic hydrocarbons.

Claims

1. A method for producing (meth)acrylic acid or ester thereof comprising:

providing a reaction gas generated by oxidizing propylene and/or acrolein in contact with a gas containing molecular state oxygen, or a reaction gas generated by oxidizing at least one member selected from isobutylene, t-butyl alcohol and methacrolein in contact with a gas containing molecular state oxygen;

treating the reaction gas to produce a (meth)acrylic acid solution; and

purifying the (meth)acrylic acid solution to produce (meth)acrylic acid,

wherein waste oil produced during the method and which contains (meth)acrylic acid or ester thereof is coexisted with a solvent.

2. A method according to claim 1, wherein the solvent is at least one selected from a group consisting of water, alcohol, ether, carboxylic acid, ketone, aromatic hydrocarbons and aliphatic hydrocarbons.

3. A method according to claim 2, wherein the water is industrial water and/or waste water discharged from various plants.

4. A method according to claim 2, wherein the alcohol is an alcohol having 1 to 8 carbons.

5. A method according to claim 2, wherein the ether is an ether having 2 to 16 carbon atoms.

6. A method according to claim 2, wherein the carboxylic acid is acetic acid and/or propionic acid.

7. A method according to claim 2, wherein the ketone is acetone and/or methyl isobutyl ketone.

8. A method according to claim 2, wherein the aromatic hydrocarbons and the aliphatic hydrocarbons is at least one selected from a group consisting of hexane, heptane, toluene, xylene, diphenyl, and kerosene.

9. A method according to claim 1, wherein the solvent is acetic acid and/or methanol.

10. A method according to claim 9, wherein the acetic acid is an acetic acid which is separated and recovered from the process stream of (meth)acrylic acid and/or ester thereof as impurities.

11. A method according to claim 1, wherein the mass amount of the solvent is from 0.05 to 10 times larger than the mass amount of the waste oil.

12. A method according to claim 1, wherein the solvent is added to the waste oil after the waste oil is taken out of a process stream.

13. A method according to claim 1, wherein the waste oil which coexisted with the solvent has a viscosity of 200 cP or less at 100°

C.

14. A method according to claim 1, wherein the mixture of solvent and waste oil is processed in a chemical apparatus.

15. A method according to claim 14, wherein the boiling point of the solvent is higher by at least 30°

C. than that of (meth)acrylic acid and/or ester thereof.

16. A method according to claim 15, wherein the solvent is diphenyl and/or diphenyl ether.

17. A method according to claim 1, wherein the reaction gas is treated with water to produce the (meth)acrylic acid solution.

18. A method according to claim 1, wherein the (meth)acrylic ester is a methyl ester, ethyl ester, n-butyl ester or 2-ethyl hexyl ester of (meth)acrylic acid produced by reacting (meth)acrylic acid and alcohol.