Heat reflecting film with low visible reflectance

• US 6,416,872 B1
• Filed: 08/30/2000
• Issued: 07/09/2002
• Est. Priority Date: 08/30/2000
• Status: Expired due to Term

• Current Assignee: Eastman Performance Films, LLC (Eastman Chemical Company)
• Original Assignee: C P Films Incorporated
• Inventors: Maschwitz, Peter
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): Piziali, Andrew T.
• Application Number:
  US09/651,082
• Time in Patent Office: 678 Days
• Field of Search: 428/426, 428/428, 428/469, 428/472
• US Class Current: 428/469
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3634 one layer at least containing carbon, a carbide or oxycarbide
• CPC Class Codes: C03C 17/3636 one layer at least containing silicon, hydrogenated silicon or a silicide
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3649 made of metals other than silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 17/38 at least one coating being a coating of an organic material
• CPC Class Codes: C03C 17/42 at least one coating of an organic material and at least one non-metal coating
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 1/116 including electrically conducting layers

Abstract

The invention is a heat reflecting transparent window cover having three layers. The composite has a substrate and a unique heat reflective stack disposed upon the substrate. The heat reflective stack has, in series, a first interference layer, an infrared reflecting metal layer, a second interference layer and a first non-infrared reflective layer. The first interference layer has an index of refraction which differs from the index of refraction of the substrate by at least about 0.1. The first non-infrared reflective layer is composed of the material from one of the following groups of materials: (i) metals having an index of refraction greater than about 1.0 and an extinction coefficient greater than about 2.0, and (ii) non-metals having an index of refraction greater than about 0.5 and an extinction coefficient greater than about 0.5.

Claims

1. A heat reflective composite comprising in series:

(a) a first substrate having an index of refraction; and

(b) a heat reflective stack disposed upon the first substrate, the heat reflective stack comprising;

(1) a first interference layer;

(2) an infrared reflecting metal layer deposited onto the first interference layer;

(3) a second interference layer; and

(4) a first non-infrared reflective layer deposited onto the second interference layer, the first non-infrared reflective layer being composed of a material selected from the group of materials consisting of (i) metals having an index of refraction greater than about 1.0 and an extinction coefficient greater than about 2.0 and (ii) non-metals having an index of refraction greater than about 0.5 and an extinction coefficient greater than about 0.5.

2. The heat reflective composite of claim 1 wherein the first non-infrared reflective layer is essentially metallic.

3. The heat reflective composite of claim 1 wherein the index of refraction of the first non-infrared reflective layer is greater than 1.0 in the visible wavelengths.

4. The heat reflective composite of claim 2 wherein the index of refraction of the first non-infrared reflective layer is between about 1.3 and about 3.0.

5. The heat reflective composite of claim 1 wherein the extinction coefficient of the first non-infrared reflective layer is between about 2.1 and about 4.0.

6. The heat reflective composite of claim 1 wherein the first non-infrared reflective layer is chosen from the group of metals consisting of Ti, Ta, Cr, Mo, Ni, stainless steel, mixtures thereof, and tungsten doped titanium nitride.

7. The heat reflective composite of claim 1 wherein the first non-infrared reflective layer is chosen from the group of metals consisting of nickel alloys, stainless steel alloys and titanium alloys.

8. The heat reflective composite of claim 1 wherein the first non-infrared reflective layer is essentially titanium or a titanium alloy.

9. The heat reflective composite of claim 1 wherein the first non-infrared reflective layer is essentially non-metallic.

10. The heat reflective composite of claim 9 wherein the first non-infrared reflective metal layer is chosen from the group of materials consisting of Si, Ge, C and mixtures thereof.

11. The heat reflective composite of claim 1 wherein the index of refraction of the first non-infrared reflective layer increases with wavelength in the visible wavelength.

12. The heat reflective composite of claim 1 wherein the extinction coefficient of the first non-infrared reflective metal layer increases with wavelength in the visible wavelengths.

13. The heat reflective composite of claim 1 wherein the index of refraction and extinction coefficient of the first non-infrared reflective metal layer increases with wavelength in the visible wavelengths.

14. The heat reflective composite of claim 1 wherein a second non-infrared reflective layer is disposed between the first substrate and the first interference layer.

15. The heat reflective composite of claim 1 wherein the heat reflective composite reflects less than about 10% of visible light.

16. The heat reflective composite of claim 1 wherein the heat reflective composite reflects less than about 8% of visible light.

17. The heat reflective composite of claim 1 wherein light transmitted through the heat reflective composite is of a color which is neutral to blue.

18. The heat reflective composite of claim 1 wherein reflective light from the heat reflective composite is a color which is neutral to blue-green.

19. The heat reflective composite of claim 1 wherein light transmitted through and light reflected from the heat reflective composite are both of a color which is neutral to blue-green.

20. The heat reflective composite of claim 1 wherein the heat reflective composite reflects at least about 70% of electromagnetic radiation having a wavelength greater than about 1200 nm.

21. The heat reflective composite of claim 1 wherein a second substrate is disposed immediately adjacent to the first non-infrared reflective layer.

22. The heat reflective composite of claim 1 wherein the heat reflective composite transmits between about 40% and about 60% of light within the visible light range.

23. A heat reflective product comprising in series:

(a) a first layer of glass;

(b) a first substrate having an index of refraction;

(c) a heat reflective stack, the heat reflective stack comprising;

(1) a first interference layer having an index of refraction which differs from the index of refraction of the substrate by at least about 0.1;

(2) an infrared reflecting metal layer deposited onto the first interference layer;

(3) a second interference layer; and

(4) a first non-infrared reflective layer deposited onto the second interference layer, the first non-infrared reflective layer being composed of a material selected from the group of materials consisting of (i) metals having an index of refraction greater than about 1.0 and an extinction coefficient greater than about 2.0 and (ii) non-metals having an index of refraction greater than about 0.5 and an extinction coefficient greater than about 0.5; and

(d) a second substrate.

24. A solar reflective product comprising in series:

(a) a first layer of glass;

(b) a first layer of polyvinylbutyral;

(c) a first substrate having an index of refraction;

(d) a heat reflective stack disposed upon the first substrate, the heat reflective stack comprising;

(1) a first interference layer having an index of refraction which differs from the index of refraction of the substrate by at least about 0.1;

(2) an infrared reflecting metal layer deposited onto the first interference layer;

(3) a second interference layer; and

(4) a first non-infrared reflective layer deposited onto the second interference layer, the first non-infrared reflective layer being composed of a material selected from the group of materials consisting of (i) metals having an index of refraction greater than about 1.0 and an extinction coefficient greater than about 2.0 and (ii) non-metals having an index of refraction greater than about 0.5 and an extinction coefficient greater than about 0.5;

(e) a second layer of polyvinylbutyral; and

(f) a second layer of glass.

25. A heat reflective product comprising in series:

(a) a first layer of glass;

(b) a first substrate having an index of refraction;

(c) a heat reflective stack disposed upon the first substrate, the heat reflective stack comprising;

(1) a first interference layer having an index of refraction which differs from the index of refraction of the substrate by at least about 0.1;

(2) an infrared reflecting metal layer deposited onto the first interference layer;

(3) a second interference layer; and

(4) a first non-infrared reflective layer deposited onto the second interference layer, the first non-infrared reflective layer being composed of a material selected from the group of materials consisting of (i) metals having an index of refraction greater than about 1.0 and an extinction coefficient greater than about 2.0 and (ii) non-metals having an index of refraction greater than about 0.5 and an extinction coefficient greater than about 0.5; and

(d) a second layer of glass;

wherein the first layer of glass is spaced apart from the first substrate and the second layer of glass is spaced apart from the first non-infrared reflective layer.

26. A heat reflective product comprising in series:

(a) a first layer of glass;

(b) a heat reflective stack disposed upon the first substrate, the heat reflective stack comprising;

(1) a first interference layer having an index of refraction which differs from the index of refraction of the substrate by at least about 0.1;

(2) an infrared reflecting metal layer deposited onto the first interference layer;

(3) a second interference layer; and

(4) a first non-infrared reflective layer deposited onto the second interference layer, the first non-infrared reflective layer being composed of a material selected from the group of materials consisting of (i) metals having an index of refraction greater than about 1.0 and an extinction coefficient greater than about 2.0 and (ii) non-metals having an index of refraction greater than about 0.5 and an extinction coefficient greater than about 0.5; and

(c) a second layer of glass;

wherein the second layer of glass is spaced-apart from the first non-infrared reflective layer.