Method for manufacturing a structural part by deposition technique

• US 6,423,255 B1
• Filed: 08/14/2000
• Issued: 07/23/2002
• Est. Priority Date: 03/24/2000
• Status: Expired due to Term

• Current Assignee: Exone GMBH (Desktop Metal, Inc.)
• Original Assignee: Generis GmbH (Voxeljet AG)
• Inventors: Hoechsmann, Rainer, Ederer, Ingo
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US09/529,721
• Time in Patent Office: 708 Days
• Field of Search: 264/113, 425/81.1, 425/91, 425/145, 347/1
• US Class Current: 264/113
• CPC Class Codes: B22C 1/224 Furan polymers B22C1/2273 takes precedence
• CPC Class Codes: B22C 9/02 Sand moulds or like moulds for shaped castings
• CPC Class Codes: B22C 9/10 Cores; Manufacture or installation of cores breaker cores B22C9/084
• CPC Class Codes: B22F 10/14 by jetting of binder onto a bed of metal powder
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B29C 64/165 using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 30/00 Apparatus for additive manufacturing; Details thereof or accessories therefor
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: Y02P 10/25 Process efficiency

Abstract

A method for manufacturing a structural part by a multi-layer deposition technique, in particular a part in the form of a casting mold or a casting core, a porous first layer of bulk particulate material consisting of particles of a predetermined particle size being deposited to form a layer of a predetermined layer thickness, a predetermined dose of liquid binder material being applied onto the layer, so that the liquid binder material penetrates the layer and becomes distributed within the layer and wets the particles of the layer and a predetermined residual porosity of the layer remains after distribution, a predetermined dose of liquid curing agent being selectively applied to a predetermined sub-area of the layer containing the binder material, a second layer being deposited on the first layer containing the binder material and the curing agent and being treated with a binder material and selectively with a liquid curing agent, the curing agent being applied to the second layer before the binder material of the first layer has cured.

Claims

1. A method for manufacturing a structural part by a multi-layer deposition technique, by depositing bulk particulate material in several stacked adjacent layers which are bonded to each other at predetermined sub-areas of the respective adjacent layers, said method comprising

a) depositing a porous first layer of bulk particulate material consisting of particles of a predetermined particle size to form a layer of a predetermined layer thickness;

b) applying a predetermined dose of liquid binder material onto at least the sub-area of the first layer, so that the liquid binder material penetrates the sub-area and becomes distributed in the sub-area and wets the particles of the sub-area and a predetermined residual porosity of the sub-area remains after distribution of the liquid binder material;

c) applying selectively a predetermined dose of liquid curing agent, which causes the binder material to cure within a predetermined period of time, to the sub-area of the first layer containing the binder material, so that the curing agent becomes distributed in the sub-area of the first layer; and

d) depositing a second layer in accordance with step a) onto the first layer containing the binder material and the curing agent treating the second layer with a binder material in accordance with step b), and treating the second layer, in the sub-area of the second layer overlapping at least part of the sub-area of the first layer, with a liquid curing agent in accordance with step c), wherein the curing agent is applied to the sub-area of the second layer within the predetermined period of time, during which the binder material of the first layer cures selectively in the sub-area of the first layer, so that the binder material in the sub-area of the second layer is bonded to the curing binder material in the sub-area of the first layer before the curing binder material in the sub-area of the first layer has finally cured.

2. The method as set forth in claim 1, wherein the predetermined particle size ranges from 100 to 200 μ

m.

3. The method as set forth in claim 1, wherein the predetermined layer thickness ranges from 0.15 to 0.3 mm.

4. The method as set forth in claim 1, wherein the liquid binder material is applied in the form of droplets of liquid binder material.

5. The method as set forth in claim 4 wherein the droplets have a predetermined diameter, and wherein the predetermined droplet diameter of the droplets ranges from 5-50 μ

m.

6. The method as set forth in claim 1, wherein the liquid curing agent is applied in the form of droplets of liquid curing agent of a predetermined droplet diameter.

7. The method as set forth in claim 6, wherein the predetermined droplet diameter of the droplets of curing agent ranges from 5 to 50 μ

m.

8. The method as set forth in claim 6, wherein a drop-on-demand print head using bubble-jet or piezoelectric systems is used for applying the droplets of curing agent.

9. The method as set forth in claim 1, wherein a sand selected from the group consisting of quartz sand, silicate sand, chromite sand, olivine sand, and zircon sand is used as the particulate material.

10. The method as set forth in claim 1, wherein the predetermined dose of binder material is selected such that the ratio of weight of the binder material relative to particle material ranges from 2 to 3 percent.

11. The method as set forth in claim 1, wherein a material selected from the group consisting of furane resin, resol ester and phenolic resin is used as binder material.

12. The method as set forth in claim 11, wherein furane resin with furfuryl alcohol is used in a proportion of at least 50 percent and ethane diol is used in a proportion of approximately 4 percent.

13. The method as set forth in claim 1, wherein an organic acid is used as curing agent.

14. The method as set forth in claim 1, wherein

the curing agent comprises toluene sulfonic acid in a proportion of 45 to 55 percent, diethylene glycol in a proportion of 5 to 15 percent, and sulphuric acid in a proportion of at most 1 percent.

15. The method as set forth in claim 12, wherein

the curing agent comprises toluene sulfonic acid in a proportion of 45 to 55 percent, diethylene glycol in a proportion of 5 to 15 percent, and sulphuric acid in a proportion of at most 1 percent, and

the binder material and the curing agent are used in a ratio of weight of 2:

1.

16. The method as set forth in claim 1, wherein the curing agent is diluted with alcohol in a ratio of approximately 2:

1.

17. The method as set forth in claim 1, wherein the binder material and/or the curing agent are applied in corresponding step b) and c), respectively, with a droplet line density ranging from 300 to 600 dpi.

18. The method as set forth in claim 1, wherein in step b), the liquid binder material is exclusively applied to said sub-area.

19. The method of claim 1 wherein the structural part is a mold or a core for a lost-form method.

23. The method as set forth in claim 1, wherein the predetermined particle size ranges from 110 to 160 μ

m.

24. The method as set forth in claim 1, wherein the predetermined particle average size is 140 μ

m.

20. An apparatus for manufacturing parts by a deposition technique, comprising:

a base being vertically movable in a z-direction;

a control unit;

an application device being horizontally movable in a y-direction and being controllable by means of the control unit and by which layers of a bulk particulate material is deposited to form a layer of a predetermined thickness;

a binder dosing device being controllable by means of the control unit and being mounted on a carriage being, above the base, horizontally movable in the y-direction, the binder dosing device further comprising a nozzle arrangement by means of which a liquid binder material is applied in a dosed quantity in form of droplets of a predetermined diameter onto the layer; and

a curing agent dosing device being horizontally movable in an x-direction and being controllable by means of the control unit and being mounted on the carriage and by means of which a liquid curing agent is applied in form of droplets of a predetermined diameter to selected sub-areas of the layer.

21. The apparatus as set forth in claim 20, wherein the curing agent dosing device is a drop-on-demand print head using a bubble jet or piezoelectric system.

22. The apparatus as set forth in claim 20, wherein the binder dosing device is a drop-on-demand print head using a bubble-jet or piezoelectric system.