Method and apparatus for managing fuel cell performance

• US 6,423,434 B1
• Filed: 08/09/1999
• Issued: 07/23/2002
• Est. Priority Date: 08/09/1999
• Status: Expired due to Term

• Current Assignee: Google Technology Holdings LLC (Alphabet Inc.), Neubourg Skin Care GmbH & Co. KG
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Pratt, Steven D., Kelley, Ronald J., Muthuswamy, Sivakumar, Pennisi, Robert W.
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): WILLS, MONIQUE M
• Application Number:
  US09/370,157
• Time in Patent Office: 1,079 Days
• Field of Search: 429/12, 429/13, 429/22, 429/14, 429/15, 429/16, 429/17, 429/23, 429/24, 429/28
• US Class Current: 429/431
• CPC Class Codes: H01M 8/04 Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
• CPC Class Codes: H01M 8/04225 during start-up
• CPC Class Codes: H01M 8/04302 applied during start-up
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A method and apparatus for managing the performance of a fuel cell system (100) using an agitation means (150). The method of managing the performance involves, monitoring operational parameters (110) of individual fuel cells and the overall fuel cell system, comparing performance parameters (120) of the system against target values, selecting a control method (130) from a set of available control methods based on the result of comparison of the performance parameters against the target values and using that control method to initiate and control an agitation process, and actuating (140) an agitation means using the selected control method so as alter the monitored operational parameters (160).

Claims

1. A method for managing performance of a fuel cell system having a plurality of fuel cells, each fuel cell having an anode side, a cathode side, and a plurality of operational parameters characterizing its operational state, the method comprising:

comparing performance parameters of the system against target values to produce a result, said performance parameters being a function of at least one of the plurality of operational parameters of at least one of the plurality of fuel cells in the system, wherein one or more of the operational parameters degrade in response to the settling of a plurality of contaminants on at least one portion of the at least one of the plurality of fuel cells;

selecting at least one control method from a plurality of control methods based on the value of said result;

initiating an actuation cycle to actuate an agitation means using the selected control method; and

agitating the at least one of the plurality of fuel cells using the agitation means, wherein the agitation causes mixing of vapor, liquid, particulates and gaseous components on at least one portion of the fuel cell, and further wherein the agitation causes the plurality of contaminants to be dislodged from the at least one portion of the at least one of the plurality of fuel cells thereby reducing the degradation of the one or more operational parameters.

2. The method of claim 1, wherein the control method comprises amplitude, frequency and length of the agitation cycle, sequence of agitation cycles, target fuel cells and target fuel cell sides on which to initiate the agitation.

3. The method of claim 1, wherein the step of initiating further comprises controlled discharge of fuel, water, particulates or contaminant gas components from the fuel cell system.

4. The method of claim 1, wherein the step of initiating further comprises controlled discharge of oxidant, water, particulates or contaminant gas components from the fuel cell system.

5. The method of claim 1, wherein the agitation means is selected from the group consisting of ultrasonic waves, acoustic excitation, mechanical vibration, thermal excitation, electromechanical excitation, pulsation of fuel cell fuel and pulsation of fuel cell oxidant.

6. The method of claim 1, wherein the monitored operating parameters are selected from the group consisting of fuel cell current output, fuel cell voltage output, fuel cell internal resistance, and temperature and humidity of the fuel cells.

7. The method of claim 1, wherein the compared performance parameters are selected from the group consisting of fuel cell system power output, fuel cell system current-voltage (IV curve) characteristics, fuel cell system load factor, fuel cell system electrical efficiency, and fuel and oxidant utilization efficiency.

8. A method for managing performance of a fuel cell system having a plurality of fuel cells, each fuel cell having an anode side, a cathode side, and a plurality of operational parameters characterizing its operational state, the method comprising:

comparing performance parameters of the system, selected from the group consisting of fuel cell system power output, fuel cell system current-voltage (IV curve) characteristics, fuel cell system load factor, fuel cell system electrical efficiency, and fuel and oxidant utilization efficiency of the system against target values to produce a result, said performance parameters being a function of at least one of a plurality of operational parameters selected from the group consisting of fuel cell current output, fuel cell voltage output, fuel cell internal resistance, and temperature and humidity at different locations in the fuel cell, of at least one of the plurality of fuel cells in the system, wherein one or more of the operational parameters degrade in response to the settling of a plurality of contaminants on at least one portion of the at least one of the plurality of fuel cells;

selecting at least one control method from a plurality of control methods based on the value of said result;

initiating an actuation cycle to actuate an agitation means selected from the group consisting of ultrasonic waves, acoustic excitation, mechanical vibration, thermal excitation, electromechanical excitation, pulsation of fuel cell fuel and pulsation of fuel cell oxidant using the selected control method; and

agitating the at least one of the plurality of fuel cells using the agitation means, wherein the agitation causes mixing of vapor, liquid;

particulates and gaseous components on at least one portion of the fuel cell, and further wherein the agitation causes the plurality of contaminants to be dislodged from the at least one portion of the at least one of the plurality of fuel cells thereby reducing the degradation of the one or more operational parameters.

9. The method of claim 8, wherein the control method comprises amplitude, frequency and length of the agitation cycle, sequence of agitation cycles, target fuel cells and target fuel cell sides on which to initiate the agitation.

10. The method of claim 8, wherein the step of initiating further comprises controlled discharge of fuel, water, particulates or contaminant gas components from the fuel cell system.

11. The method of claim 8, wherein the step of initiating further comprises controlled discharge of oxidant, water, particulates or contaminant gas components from the fuel cell system.

12. A method for controlling performance of a fuel cell system, having a plurality of fuel cells, each fuel cell having a plurality of operational parameters characterizing its operational state, wherein one or more of the operational parameters degrade in response to the settling of a plurality of contaminants on at least one portion of the fuel cell, the method comprising selecting and using a control method, initiating an agitation cycle to actuate an agitation means using the selected control method, and agitating at least one of the plurality of fuel cells sufficient to cause mixing of vapor, liquid, particulates and gaseous components and further to cause the plurality of contaminants to be dislodged from the at least one portion of the at least one of the plurality of fuel cells thereby reducing the degradation of the one or more operational parameters in the fuel cell system.

13. The method of claim 12, wherein the control method comprises amplitude, frequency and length of the agitation cycle, sequence of agitation cycles, target fuel cells and target fuel cell sides on which to initiate the agitation.

14. The method of claim 12 further comprising controlled discharge of fuel, water, particulates or contaminant gas components from the fuel cell system.

15. The method of claim 12 further comprising controlled discharge of oxidant, water, particulates and contaminant gas components from the fuel cell system.

16. A method for managing performance of a fuel cell system having a plurality of fuel cells, each fuel cell having an anode side, a cathode side, and a plurality of operational parameters characterizing its operational state, the method comprising the following steps in the order named:

a) monitoring operational parameters of at least one of the plurality of fuel cells in the system, wherein one or more of the operational parameters degrade in response to the settling of a plurality of contaminants on at least one portion of the at least one of the plurality of fuel cells;

b) comparing performance parameters of the system against target values to produce a result;

c) selecting at least one control method from a plurality of control methods based on the value of said result; and

d) initiating an actuation cycle to actuate an agitation means using the selected control method so as alter the operational parameters; and

e) agitating the at least one of the plurality of fuel cells using the agitation means, wherein the agitation causes mixing of vapor, liquid, particulates and gaseous components on at least one portion of the fuel cell, and further wherein the agitation causes the plurality of contaminants to be dislodged from the at least one portion of the at least one of the plurality of fuel cells thereby reducing the degradation of the one or more operational parameters.

17. The method of claim 16, wherein the control method comprises amplitude, frequency and length of the agitation cycle, sequence of agitation cycles, target fuel cells and target fuel cell sides on which to initiate the agitation.

18. The method of claim 16, wherein the step of initiating further comprises controlled discharge of fuel, water, particulates or contaminant gas components from the fuel cell system.

19. The method of claim 16, wherein the step of initiating further comprises controlled discharge of oxidant, water, particulates or contaminant gas components from the fuel cell system.

20. The method of claim 16, wherein the agitation means is selected from the group consisting of ultrasonic waves, acoustic excitation, mechanical vibration, thermal excitation, electromechanical excitation, pulsation of fuel cell fuel and pulsation of fuel cell oxidant.

21. The method of claim 16, wherein the monitored operating parameters are selected from the group consisting of fuel cell current output, fuel cell voltage output, fuel cell internal resistance, and temperature and humidity of the fuel cells.

22. The method of claim 16, wherein the compared performance parameters are selected from the group consisting of fuel cell system power output, fuel cell system current-voltage (IV curve) characteristics, fuel cell system load factor, fuel cell system electrical efficiency, and fuel and oxidant utilization efficiency.

23. A fuel cell having a plurality of operational parameters characterizing the operational state of the fuel cell, comprising:

at least one membrane electrode assembly, having two major sides, comprising a solid electrolyte disposed between and in intimate contact with an anode forming first major side of the membrane electrode assembly and a cathode forming second major side of the membrane electrode assembly, wherein a plurality of contaminants settle on at least one side of the membrane electrode assembly during operation of the fuel cell, and further wherein the contaminants cause a degradation in one or more of the operational parameters; and

an agitation means to provide agitation to at least one portion of the fuel cell, wherein the agitation means operates in response to the degradation in the one or more operational parameters;

wherein the agitation produces mixing of vapor, liquid, particulates and gaseous components at least on one major side of the membrane electrode assembly, and further wherein the agitation causes the plurality of contaminants to be dislodged from at least one portion of the fuel cell thereby reducing the degradation of the one or more operational parameters.

24. The fuel cell as described in claim 23, wherein the agitation means is disposed on the first major side, the second major side or both sides of the membrane electrode assembly.

25. The fuel cell as described in claim 23, wherein the agitation means is selected from the group consisting of ultrasonic waves, acoustic excitation, mechanical vibration, thermal excitation, electromechanical excitation, pulsation of fuel cell fuel and pulsation of fuel cell oxidant.

26. The fuel cell as described in claim 23, wherein the membrane electrode assemblies are disposed in a stacked arrangement.

27. The fuel cell as described in claim 23, wherein the membrane electrode assemblies are disposed in a planar arrangement.

28. The fuel cell as described in claim 23, wherein the agitation means further comprises a release valve for selective, controlled release of the agitated components from the fuel cell.