Low temperature hydrocarbon gas separation process

• US 6,425,266 B1
• Filed: 09/24/2001
• Issued: 07/30/2002
• Est. Priority Date: 09/24/2001
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Roberts, Mark Julian
• Primary Examiner(s): Esquivel, Denise L.
• Assistant Examiner(s): Drake, Malik N.
• Application Number:
  US09/962,755
• Time in Patent Office: 309 Days
• Field of Search: 626/17, 626/18, 626/19, 626/20, 626/21, 629/01
• US Class Current: 62/621
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2200/76 Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
• CPC Class Codes: F25J 2200/90 Details relating to column internals, e.g. structured packing, gas or liquid distribution
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2230/08 Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2240/40 Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/02 Internal refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/04 Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/08 Internal refrigeration by flash gas recovery loop
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more

Abstract

Method for separating a pressurized hydrocarbon mixture containing at least a more volatile component and a less volatile component. The method comprises (a) cooling and partially condensing the hydrocarbon mixture to yield a first hydrocarbon vapor and a first hydrocarbon liquid; (b) work expanding at least a portion of the first hydrocarbon vapor and introducing it into a distillation column at a first column location; (c) reducing the pressure of the first hydrocarbon liquid and introducing it into the distillation column at a second column location; and (d) withdrawing an overhead vapor enriched in the more volatile component from the distillation column; cooling, partially condensing, and separating the overhead vapor to provide a condensed overhead liquid and an uncondensed vapor overhead, introducing the condensed overhead liquid into the distillation column as reflux, and withdrawing from the bottom of the distillation column a stream enriched in the less volatile component. Cooling and partial condensing of the overhead vapor in (d) may be effected by (1) further cooling a second portion of the two-phase hydrocarbon mixture, (2) reducing the pressure of the further cooled hydrocarbon mixture to provide a reduced-pressure hydrocarbon mixture; and (3) cooling and partially condensing the overhead vapor by indirect heat exchange with the reduced-pressure hydrocarbon mixture to provide reflux to the distillation column. Cooling and partial condensing of the overhead vapor provides a warmed, two-phase hydrocarbon mixture, the warmed, two-phase hydrocarbon mixture may be separated into a second hydrocarbon liquid and a second hydrocarbon vapor, the second hydrocarbon liquid may be introduced into the distillation column, and the second hydrocarbon vapor may be warmed and introduced in to the distillation column at a second location below the first column location of (b).

Claims

1. A method for the separation of a pressurized hydrocarbon mixture containing at least one more volatile component and at least one less volatile component, which method comprises

(a) cooling and partially condensing the hydrocarbon mixture to form a two-phase hydrocarbon mixture, and separating a first portion of the two-phase hydrocarbon mixture into a first hydrocarbon vapor and a first hydrocarbon liquid;

(b) work expanding at least a portion of the first hydrocarbon vapor to provide a cooled, expanded hydrocarbon vapor and introducing the cooled, expanded hydrocarbon vapor into a distillation column at a first column location;

(c) reducing the pressure of the first hydrocarbon liquid to provide a reduced-pressure hydrocarbon liquid and introducing the reduced-pressure hydrocarbon liquid into the distillation column at a second column location; and

(d) withdrawing an overhead vapor enriched in the more volatile component from the distillation column;

cooling, partially condensing, and separating the overhead vapor to provide a condensed overhead liquid and an uncondensed vapor overhead, introducing the condensed overhead liquid into the distillation column as reflux, and withdrawing from the bottom of the distillation column a stream enriched in the less volatile component;

wherein cooling and partial condensing of the overhead vapor in (d) is effected by

(1) further cooling a second portion of the two-phase hydrocarbon mixture to provide a further cooled hydrocarbon mixture;

(2) reducing the pressure of the further cooled hydrocarbon mixture to provide a reduced-pressure hydrocarbon mixture; and

(3) utilizing the reduced-pressure hydrocarbon mixture to provide by indirect heat exchange the cooling and partial condensing of the overhead vapor; and

wherein cooling and partial condensing of the overhead vapor by indirect heat exchange with the reduced-pressure hydrocarbon mixture in (3) provides a warmed, two-phase hydrocarbon mixture, the warmed, two-phase hydrocarbon mixture is separated into a second hydrocarbon liquid and a second hydrocarbon vapor, the second hydrocarbon liquid is introduced into the distillation column, and the second hydrocarbon vapor is warmed and introduced into the distillation column at a third column location below the first column location of (b).

2. The method of claim 1 wherein the cooling of the second portion of the two-phase hydrocarbon mixture of (1) is effected in part by indirect heat exchange with the second hydrocarbon vapor to provide a warmed second hydrocarbon vapor.

3. The method of claim 2 wherein the cooling and partial condensing of the hydrocarbon mixture in (a) is effected in part by indirect heat exchange with the warmed second hydrocarbon vapor to yield a further warmed second hydrocarbon vapor which is introduced into the distillation column at the third column location which is below the first column location of (b).

4. The method of claim 3 wherein the third column location is below the second column location.

5. The method of claim 1 which further comprises combining a portion of the first hydrocarbon vapor of (a) with the second portion of the two-phase hydrocarbon mixture of prior to further cooling.

6. The method of claim 1 wherein the cooling of the second portion of the two-phase hydrocarbon mixture of (1) is effected in part by indirect heat exchange with the uncondensed vapor overhead of (d) to provide a warmed uncondensed vapor overhead.

7. The method of claim 6 wherein the cooling and partially condensing of the hydrocarbon mixture in (a) is effected in part by indirect heat exchange with the warmed uncondensed vapor overhead.

8. The method of claim 1 wherein the overhead vapor enriched in the more volatile component withdrawn from the distillation column in (d) is compressed prior to cooling and partially condensing, and the partially-condensed overhead is reduced in pressure prior to introduction into the distillation column as reflux.

9. The method of claim 1 wherein the second hydrocarbon vapor is work expanded after warming and prior to introduction into the distillation column.

10. The method of claim 1 wherein the pressure of the reduced-pressure hydrocarbon mixture of (2) is lower than the pressure in the distillation column.

11. The method of claim 10 wherein the second hydrocarbon liquid is pumped and pressurized prior to introduction into the distillation column.

12. The method of claim 11 wherein the second hydrocarbon vapor is compressed prior to being introduced into the distillation column.

13. The method of claim 1 wherein the hydrocarbon mixture comprises methane and one or more hydrocarbons containing two or more carbon atoms.

14. The method of claim 13 wherein the hydrocarbon mixture also contains nitrogen.

15. The method of claim 13 wherein the hydrocarbon mixture is natural gas.

16. A method for the separation of a pressurized hydrocarbon mixture containing at least one more volatile component and at least one less volatile component, which method comprises

(a) cooling and partially condensing the hydrocarbon mixture to form a two-phase hydrocarbon mixture, and separating a first portion of the two-phase hydrocarbon mixture into a first hydrocarbon vapor and a first hydrocarbon liquid;

(b) work expanding at least a portion of the first hydrocarbon vapor to provide a cooled, expanded hydrocarbon vapor and introducing the cooled, expanded hydrocarbon vapor into a distillation column at a first column location;

(c) reducing the pressure of the first hydrocarbon liquid to provide a reduced-pressure hydrocarbon liquid and introducing the reduced-pressure hydrocarbon liquid into the distillation column at a second column location; and

(d) withdrawing an overhead vapor enriched in the more volatile component from the distillation column, compressing a portion of the overhead vapor to yield a compressed overhead vapor, cooling the compressed overhead vapor to provide a cooled and at least partially condensed overhead stream, reducing the pressure of the cooled and at least partially condensed overhead stream to provide a reduced-pressure overhead stream, introducing the reduced-pressure overhead stream into the distillation column as reflux, and withdrawing from the bottom of the distillation column a stream enriched in the less volatile component;

wherein cooling of the compressed overhead vapor in (d) is effected by

(1) further cooling a second portion of the two-phase hydrocarbon mixture to provide a further cooled hydrocarbon mixture;

(2) reducing the pressure of the further cooled hydrocarbon mixture to provide a reduced-pressure hydrocarbon mixture; and

(3) utilizing the reduced-pressure hydrocarbon mixture to provide by indirect heat exchange the cooling of the compressed overhead vapor;

and wherein cooling of the compressed overhead vapor by indirect heat exchange with the reduced-pressure hydrocarbon mixture in (3) provides a warmed, two-phase hydrocarbon mixture, the warmed, two-phase hydrocarbon mixture is separated into a second hydrocarbon liquid and a second hydrocarbon vapor, the second hydrocarbon liquid is introduced into the distillation column, and the second hydrocarbon vapor is warmed and introduced into the distillation column at a third column location below the first column location of (b).