Energetic plasticizer, and explosive and propellant composition containing same

• US 6,425,966 B1
• Filed: 09/14/2000
• Issued: 07/30/2002
• Est. Priority Date: 09/15/1999
• Status: Expired due to Fees

• Current Assignee: Northrop Grumman Innovation Systems, Inc. (Northrop Grumman Corporation)
• Original Assignee: Alliant Techsystems Incorporated (Northrop Grumman Corporation)
• Inventors: Doll, Daniel W., Cannizzo, Louis F., Highsmith, Thomas K.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US09/661,557
• Time in Patent Office: 684 Days
• Field of Search: 560/264, 149/88, 149/19.1, 149/19.8
• US Class Current: 149/19.1
• CPC Class Codes: C06B 45/105 The resin being a polymer bearing energetic groups or containing a soluble organic explosive

Abstract

2,2-dinitro-1,3-propanediol-diformate is a novel low sensitivity, energetic plasticizer that is useful in explosive and propellant compositions. 2,2-dinitro-1,3-propanediol-diformate can be made by reacting 2,2-dinitro-1,3-propane diol with acetic formic anhydride in the presence of pyridine and at least one solvent.

Claims

1. 2,2-dinitro-1,3-propanediol-diformate.

2. A composition comprising as ingredients 2,2-dinitro-1,3-propanediol-diformate, and one or more additional ingredients effective to form a low sensitivity, high performance explosive or propellant.

3. The composition of claim 2, wherein said composition is a melt cast explosive composition and said additional ingredients comprise at least one energetic material selected from the group consisting of 2,4,6-trinitrotouene (TNT) and 1,3,3-trinitroazetidine (TNAZ).

4. The composition of claim 3, wherein said energetic material is present in an amount of from 40 wt % to 60 wt % based on the total weight of the composition.

5. The composition of claim 4, wherein the 2,2-dinitro-1,3-propanediol-diformate is present in an amount of from 0.5 wt % to 10 wt % based on the total weight of the composition.

6. The composition of claim 2, wherein said composition is a cast cure explosive composition and said additional ingredients comprise 5 wt % to 20 wt % of one or more binders, 0.5 wt % to 3 wt % of one or more curatives, 0.25 wt % to 2 wt % of one or more cure catalysts, and 20 wt % to 80 wt % of one or more oxidizers.

7. The composition of claim 6, wherein a weight ratio of binders to the 2,2-dinitro-1,3-propanediol-diformate and other optional plasticizers is 0.5:

3 to 1;

1.

8. The composition of claim 2, wherein said composition is an extudable explosive composition and said additional ingredients comprise 5 wt % to 35 wt % of one or more thermoplastic elastomers, up to 65 wt % of one or more oxidizers, 0 wt % to 90 wt % of one or more explosive fillers, and 0 wt % to 40 wt % of metals, and wherein both 2,2-dinitro-1,3-propanediol-diformate and other optional plasticizers are present in an amount up to 25 wt %.

9. The composition of claim 8, wherein said explosive fillers comprise one or more nitramines.

10. The composition of claim 2, wherein said composition is an explosive composition comprising as said additional ingredients one or more binders selected from the group consisting of nitrocellulose, poly(glycidyl nitrate), and poly(glycidyl azide).

11. The composition of claim 2, wherein said composition is a composite propellant composition.

12. The composition of claim 11, wherein said additional ingredients comprise 4 wt % to 30 wt % of one or more binders, 0.5 wt % to 3 wt % of one or more curatives, 0.25 wt % to 2 wt % of one or more cure catalysts, 40 wt % to 80 wt % of one or more oxidizers.

13. The composition of claim 12, wherein the 2,2-dinitro-1,3-propanediol-diformate and other optional plasticizers are present in a combined amount of up to 30 wt %.

14. The composition of claim 13, further comprising up to 5 wt % of one or more ballistic modifiers.

15. The composition of claim 2, wherein said composition is a double-base propellant composition.

16. The composition of claim 2, wherein said composition is a triple-base propellant composition.