Nonflammable halogen-free mixture

• US 6,429,246 B1
• Filed: 03/17/1997
• Issued: 08/06/2002
• Est. Priority Date: 03/19/1996
• Status: Expired due to Fees

• Current Assignee: Nexans Incorporated (Nokia Corporation)
• Original Assignee: Alcatel SA (Nokia Corporation)
• Inventors: Rous, Friedemann
• Primary Examiner(s): SZEKELY, PETER A
• Application Number:
  US08/819,239
• Time in Patent Office: 1,968 Days
• Field of Search: 524/261, 524/266, 524/265, 524/267, 524/400, 524/436, 524/437, 524/425, 524/268, 524/505
• US Class Current: 524/268
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/14 Copolymers of propene C08L23/16 takes precedence
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

Abstract

A nonflammable, halogen-free mixture for making thermoplastic polymer materials with increased heat resistance, particularly for manufacturing electrical and optical cables and lines. The mixture comprises: a block or randon block copolymer of polypropylene; a salt of a metal selected from the group consisting of Group II, IIa and IIb metals; a metal hydroxide; a silicone material-selected from the group silicone oil, silicone rubber, and combinations thereof.

Claims

1. A nonflammable halogen-free mixture for manufacturing electrical cables with increased heat resistance, the mixture comprising:

a copolymer selected from the group of copolymers consisting of a polypropylene block copolymer and a polypropylene random block copolymer;

a salt of a metal selected from the group consisting of Group II, IIa and IIb metals of the periodic system, wherein the metal salt in the mixture is in the range of 1 to 15 parts per 100 parts of copolymer;

a metal hydroxide, wherein the metal hydroxide in the mixture is in the range of 30 to 180 parts per 100 parts of copolymer; and

a silicone material selected from the group consisting of silicone oil, silicone rubber, and combinations thereof, wherein the silicon material in the mixture is in the range of 0.3 to 20 parts per 100 parts of copolymer.

2. The mixture as claimed in claim 1, wherein the metal salt is the salt of a carboxylic acid.

3. The mixture as claimed in claim 1, wherein the metal salt of the carboxylic acid is calcium stearate.

4. The mixture as claimed in claim 1, wherein the metal salt of the carboxylic acid is magnesium stearate.

5. The mixture as claimed in claim 1, wherein the metal hydroxide is magnesium hydroxide.

6. The mixture as claimed in claim 1, wherein the metal hydroxide is aluminum hydroxide.

7. The mixture as claimed in claim 1, wherein the mixture further comprises an inorganic filler.

8. The mixture as claimed in claim 7, wherein the inorganic filler is in the range of 10 to 80 parts per 100 parts of polymer.

9. The mixture as claimed in claim 8, wherein the filler is chalk (CaCO₃).

10. The mixture as claimed in claim 1, wherein the mixture further comprises maleic anhydride-grafted polymer.

11. The mixture as claimed in claim 9, wherein the maleic anhydride-grafted polymer is in the range of 0.5 to 5 parts per 100 parts of polymer.

12. The mixture as claimed in claim 1, wherein the polymer is cross-linked.