Refrigerant and heat transfer fluid additive

• US 6,432,320 B1
• Filed: 11/22/2000
• Issued: 08/13/2002
• Est. Priority Date: 11/02/1998
• Status: Expired due to Fees

• Current Assignee: Michael H. Gurin, Patrick Bonsignore
• Original Assignee: Michael H. Gurin, Patrick Bonsignore
• Inventors: Gurin, Michael H., Bonsignore, Patrick
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US09/721,074
• Time in Patent Office: 629 Days
• Field of Search: 252/70, 252/71, 165/10, 165/104.15, 165/104.19
• US Class Current: 252/70
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C09K 5/10 Liquid materials

Abstract

An additive suited to use in combination with heat transfer media comprises a chemically stabilized nano-particle size powder. Suitable powders include those of copper, beryllium, titanium, nickel, iron, alloys or blends thereof, and carbon. The surface of the powder is modified by surface complexation or physical adsorption with a chemical agent. The additive, when mixed with a heat transfer medium, forms a colloidal dispersion which exhibits enhanced heat transfer capacity and thermal conductivity, stable chemical composition, faster heat transfer rates, dispersion maintenance which are beneficial to most heat transfer systems.

Claims

1. A heat transfer composition comprising:

a heat transfer medium; and

an additive comprising;

a powder selected from the group consisting of metals, metal oxides, alloys, and combinations thereof, the powder having an average particle size of from about 1 nanometer to about 100 microns, and

a coating on the powder, the coating including at least one chemical agent selected from the group consisting of organic corrosion inhibitors, inorganic corrosion inhibitors, ethylene oxide/polypropylene oxide block copolymers, and combinations thereof.

2. The heat transfer composition of claim 1, wherein the coating is one which does at least one of the following:

a) increases settling time of the additive in the heat transfer medium;

b) passivates the additive;

c) inhibits corrosion of the additive; and

d) increases long term stability of the additive.

3. The heat transfer composition of claim 1, wherein the powder comprises particles having an average size of less than 10 microns.

4. The heat transfer composition of claim 3, wherein the powder particles have an average size of from about 10 nanometers to 2000 nanometers.

5. The heat transfer composition of claim 4, wherein the powder particles have an average size of from about 25 nanometers to 1000 nanometers.

6. The heat transfer composition of claim 1, wherein the powder is formed from at least one material selected from the group consisting of copper, aluminum, titanium, nickel, beryllium, silver, gold, and iron, alloys thereof, blends thereof, and compounds thereof.

7. The heat transfer composition of claim 6, wherein the powder comprises copper or beryllium.

8. The heat transfer composition of claim 1 wherein the coating includes a corrosion inhibitor.

9. The heat transfer composition of claim 8, wherein the corrosion inhibitor is selected from the group consisting of azoles, substituted azole derivatives, and combinations thereof.

10. The heat transfer composition of claim 9, wherein the azole or substituted azole derivative is selected from the group consisting of benzotriazole, tolyltriazole, 2,5-(aminopentyl)benzimidazole, alkoxybenzotriazole, imidazoles, thiazoles, 1-phenyl-5-mercaptotetrazole, thiodiazoles, halogen-resistant azoles, and combinations thereof.

11. The heat transfer composition of claim 10, wherein the substituted azole includes an alkyl-substituted aromatic triazole.

12. The heat transfer composition of claim 11, wherein the alkyl-substituted aromatic triazole includes tolyltriazole.

13. The heat transfer composition of claim 8, wherein the coating comprises an inorganic corrosion inhibitor selected from the group consisting of water-soluble amine salts, phosphates, salts of transition elements, and combinations thereof.

14. The heat transfer composition of claim 1, wherein the coating includes at least one of the group consisting of ethylene oxide/propylene oxide block copolymers, anionic surfactants, and nonionic surfactants.

15. The heat transfer composition of claim 1, wherein the heat transfer medium is selected from the group consisting of water;

aqueous brines;

mixtures of water with at least one of the group consisting of alcohols, glycols, and ammonia;

hydrocarbons;

mineral oils;

natural oils;

synthetic oils;

fats;

waxes;

ethers;

esters;

glycols;

halogen derivatives of at least one of the group consisting of hydrocarbons, mineral oils, natural oils, synthetic oils, fats, waxes, ethers, esters, and glycols;

silicate esters;

biphenyl;

polyaromatic compounds;

salt-hydrates, organic eutectics, clathrate-hydrates;

paraffins;

inorganic and organic eutectic mixtures; and

combinations thereof.

16. The heat transfer composition of claim 1, further including at least one additional additive selected from the group consisting of functionalizing agents, dispersants, surfactants, antioxidants, and combinations thereof.

18. The heat transfer composition of claim 1, wherein the powder is formed from at least one carbon material selected from the group consisting of graphite, carbon nanotubes, diamond, and fullerene carbons of the general formula C_2n, where n is an integer of at least 30.

17. A heat transfer composition for transferring heat between a heat source and a heat sink, the composition comprising:

a heat transfer medium; and

an additive comprising;

a powder which includes carbon, the powder having an average particle size of from about 1 nanometer to about 100 microns, and

a coating on the powder, the coating including at least one chemical agent selected from the group consisting of ethylene oxide/polypropylene oxide block copolymers, surfactants, lignin, lignin derivatives, alkali metal salts, alkali earth metal salts, ammonium salts, alkyl ether phosphates, and combinations thereof.

19. The heat transfer composition of claim 17, wherein the coating includes at least one of the group consisting of lignin and lignin derivatives.

20. An additive for a heat transfer medium comprising:

a nano-particle size powder having an average particle size of from about 1 nanometer to about 2000 nanometers and being formed from a material selected from the group consisting of metals, alloys, metal compounds, carbon, and combinations thereof, the powder being chemically stabilized with an azole.

21. A process for transferring heat between a heat source and a heat sink, the method comprising:

transferring heat between the heat source and the heat sink with a heat transfer composition which includes a powder having a particle size of, the powder being selected from the group consisting of metals, metal alloys, metal blends, metal compounds, carbon, and combinations thereof, the powder having an average particle size of from about 1 nanometer to about 2000 nanometers and having a surface thereof coated with a chemical agent which provides the powder with improved corrosion resistance or dispersion characteristics as compared with an uncoated powder, the chemical agent being selected from the group consisting of organic corrosion inhibitors, inorganic corrosion inhibitors, ethylene oxide/polypropylene oxide block copolymers, surfactants, lignin, lignin derivatives, and combinations thereof.

22. The process of claim 21, further including, prior to the step of transferring heat:

treating a powder with the chemical agent; and

combining the treated powder with a heat transfer medium.

23. The process of claim 22, wherein the step of treating includes

dispersing the chemical agent in a solvent to form a mixture;

and

contacting the powder with the mixture.

24. The process of claim 22, wherein the step of treating includes at least one of:

a) complexing the chemical agent with accessible surfaces of particles of the powder; and

b) physically adsorbing the chemical agent on accessible surfaces of particles of the powder.

25. The process of claim 22, wherein the chemical additive is in sufficient amount to form at least a monolayer of the chemical additive on the accessible surfaces of the powder particles.

26. The process of claim 21, wherein the powder includes at least one of the group consisting of metals, metal alloys, metal blends, metal compounds and the chemical agent includes a corrosion inhibitor.

27. The process of claim 26, wherein the powder includes copper and the chemical agent includes an azole.