Apparatus and method for fabricating a microbattery

• US 6,432,577 B1
• Filed: 06/29/2000
• Issued: 08/13/2002
• Est. Priority Date: 06/29/2000
• Status: Expired due to Term

• Current Assignee: National Technology & Engineering Solutions Of Sandia LLC (Honeywell International Inc.)
• Original Assignee: Sandia Corporation (Martin Marietta Corporation)
• Inventors: Kravitz, Stanley H., Ingersoll, David, Zipperian, Thomas E., Christenson, Todd R., Shul, Randy J.
• Primary Examiner(s): Ryan, Patrick
• Assistant Examiner(s): YUAN, DAH WEI D
• Application Number:
  US09/607,587
• Time in Patent Office: 775 Days
• Field of Search: 429/162, 429/218.1, 429/223, 429/247, 429/251, 429/252
• US Class Current: 429/162
• CPC Class Codes: H01M 10/0436 Small-sized flat cells or batteries for portable equipment
• CPC Class Codes: H01M 50/528 Fixed electrical connections, i.e. not intended for disconnection
• CPC Class Codes: H01M 6/12 with flat electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

An apparatus and method for fabricating a microbattery that uses silicon as the structural component, packaging component, and semiconductor to reduce the weight, size, and cost of thin film battery technology is described. When combined with advanced semiconductor packaging techniques, such a silicon-based microbattery enables the fabrication of autonomous, highly functional, integrated microsystems having broad applicability.

Claims

1. A microbattery, comprising:

a) a dielectric porous membrane;

b) a first electrode containing anodic material mounted on one side of the porous membrane;

c) a second electrode containing cathodic material mounted on the opposite side of the porous membrane;

d) a first silicon frame mounted with the first electrode and on the side opposite the porous membrane;

e) a second silicon frame mounted with the second electrode and on the side opposite the porous membrane; and

f) electrical connectors passing through each frame for providing electrical connectivity from the first and second electrodes to external circuitry.

2. The microbattery of claim 1, further comprising a first dielectric layer on the side of the first silicon frame facing the porous membrane and a second dielectric layer on the side of the second silicon frame facing the porous membrane.

3. The microbattery of claim 2, wherein the first and second dielectric layers comprise silicon dioxide or silicon nitride.

4. The microbattery of claim 2, further comprising a first current collector layer on the side of the first dielectric layer facing the porous membrane and a second current collector layer on the side of the second dielectric layer facing the porous membrane, and wherein the electric connectors make electrical connectivity from the first and second current collector layers to external circuitry.

5. The microbattery of claim 4, wherein the first and second current collector layers comprise aluminum, copper, nickel, carbon, or silver.

6. A microbattery, comprising:

a) a dielectric porous membrane;

b) a first electrode containing anodic material mounted on one side of the porous membrane;

c) a second electrode containing cathodic material mounted on the opposite side of the porous membrane;

d) a first frame mounted with the first electrode and on the side opposite the porous membrane, and wherein the first frame is conducting or semiconducting;

e) a first dielectric layer on the side of the first frame facing the porous membrane; and

f) a second frame mounted with the second electrode and on the side opposite the porous membrane, and wherein the second frame is conducting or semiconducting;

g) a second dielectric layer on the side of the second frame facing the porous membrane; and

h) electrical connectors passing through each frame for providing electrical connectivity from the first and second electrodes to external circuitry.

7. The microbattery of claim 6, wherein the first and second dielectric layers comprise silicon dioxide or silicon nitride.

8. The microbattery of claim 7, wherein the first and second dielectric layers are made by steam oxidation of silicon.

9. The microbattery of claim 6, further comprising a first current collector layer on the side of the first dielectric layer facing the porous membrane and a second current collector layer on the side of the second dielectric layer facing the porous membrane, and wherein the electric connectors make electrical connectivity from the first and second current collector layers to external circuitry.

10. The microbattery of claim 9, wherein the first and second current collector layers comprise aluminum, copper, nickel, carbon, or silver.

11. A microbattery, comprising:

a) a dielectric porous membrane;

b) a first electrode comprising a honeycomb cell structure in silicon containing anodic material mounted on one side of the porous membrane;

c) a second electrode comprising a honeycomb cell structure in silicon containing cathodic material mounted on the opposite side of the porous membrane;

d) a first frame mounted with the first electrode and on the side opposite the porous membrane;

e) a second frame mounted with the second electrode and on the side opposite the porous membrane; and

f) electrical connectors passing through each frame for providing electrical connectivity from the first and second electrodes to external circuitry.

12. The microbattery of claim 11, wherein the honeycomb structure is patterned into silicon using a deep reactive ion etching process.

13. A microbattery, comprising:

a) a dielectric porous membrane;

b) a first electrode containing anodic material mounted on one side of the porous membrane;

c) a second electrode containing cathodic material mounted on the opposite side of the porous membrane;

d) a first frame mounted with the first electrode and on the side opposite the porous membrane;

e) a second frame mounted with the second electrode and on the side opposite the porous membrane; and

f) electrical connectors comprising a plurality of through-frame plated vias passing through each frame for providing electrical connectivity from the first and second electrodes to external circuitry.

14. The microbattery of claim 13, wherein the through-frame plated vias are fabricated by forming through-frame via holes by deep reactive ion etching in silicon, steam oxidation of the via holes, and electroplating to form metal via plugs that are electrically isolated from the frames.

15. The microbattery of claim 14, wherein the metal via plugs are gold, nickel, copper, or nickel-iron.