Hot melt pressure sensitive adhesive which exhibits minimal staining

• US 6,433,069 B1
• Filed: 06/14/2000
• Issued: 08/13/2002
• Est. Priority Date: 10/23/1997
• Status: Expired due to Fees

• Current Assignee: HB Fuller Company
• Original Assignee: H.B. Fuller Licensing & Financing, Inc.
• Inventors: Oeltjen, Susan T., Kodama, Yoshihiro, Asai, Daisuke, Lindquist, Jeffrey S.
• Primary Examiner(s): Szekely, Peter
• Application Number:
  US09/509,749
• Time in Patent Office: 790 Days
• Field of Search: 524/271, 524/505, 524/474, 524/484, 524/485, 524/486, 525/89, 525/95, 525/98, 525/99, 525/314, 428/355.BL, 156/327, 156/334
• US Class Current: 524/505
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C09J 153/00 Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
• CPC Class Codes: C09J 153/02 Vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: Y10T 428/2883 including addition polymer of diene monomer [e.g., SBR, SIS, etc.]

Abstract

This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.

Claims

1. A hot melt pressure sensitive adhesive comprising:

a. from about 5% to about 30% by weight of the adhesive of at least one block copolymer having styrene end-blocks and ethylene/butylene or ethylene/propylene mid-blocks and having a diblock content of greater than 35%, a coupling efficiency of less than about 50%, a melt index greater than about 20 grams/10 minutes, and a styrene content of from about 10 wt-% to about 30 wt-%,

b. from about 5% to about 50% by weight of the adhesive of at least one block copolymer having styrene end-blocks, a coupling efficiency from about 65% to about 100%;

from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil; and

c. from about 20% to about 60% by weight of the adhesive of a tackifying resin, said adhesive has a 180°

peel to stainless steel of less than about 2.0 pounds per linear inch (about 360 g/cm) and exhibits minimal staining to paper.

2. The adhesive of claim 1 comprising from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%.

5. The adhesive of claim 1 wherein said adhesive has a 180°

peel to stainless steel of less than about 1.5 pounds per linear inch (about 270 g/cm).

6. The adhesive of claim 1 wherein said adhesive exhibits no visible staining to paper.

7. The adhesive of claim 1 wherein b) is a 100% linear styrene-ethylene/butylene-styrene block copolymer.

8. The adhesive of claim 1 wherein a) has a diblock content of about 70% and a styrene content of about 30% by weight of the block copolymer.

9. The adhesive of claim 1 wherein the tackifying resin has a softening point of less than about 100°

C.

26. The adhesive of claim 1 wherein said adhesive has a viscosity of less than 3500 cPs at 175°

C.

27. The adhesive of claim 1 wherein said at least one block copolymer of b) has a melt index greater than 5 grams per 10 minutes, and a styrene content of 10-25 wt-%.

3. A removable label comprising a substrate coated on at least one surface with a hot melt pressure sensitive adhesive comprising

a. from about 5% to about 30% by weight of the adhesive of at least one block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 50% and a melt index greater than about 20 grams/10 minutes;

b. from about 5% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%;

c. from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil; and

d. from about 20% to abut 60% by weight of the adhesive of a tackifying resin;

wherein the resultant adhesive has a 180°

peel to stainless steel of less than about 2.0 pounds per linear inch (about 360 g/cm) and exhibits minimal staining to paper.

16. The label of claim 3 wherein the adhesive has a 180°

adhesion to stainless steel of less than about 1.5 pounds per linear inch (about 270 g/cm).

17. The label of claim 3 wherein the adhesive exhibits no visible staining to paper.

18. The label of claim 3 wherein block copolymer component b) is a 100% linear styrene-ethylene/butylene-styrene block copolymer.

19. The label of claim 3 wherein block copolymer a) has a diblock content of about 70% and a styrene content of about 30% by weight of the block copolymer.

20. The label of claim 3 wherein the tackifying resin has a softening point of less than 100°

C.

4. An article adhered to a magazine page through “

tipping”

with a removable hot melt pressure sensitive adhesive comprising;

a. from about 5% to about 30% by weight of the adhesive of at least one block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 50% and a melt index greater than about 20 grams/10 minutes;

b. from about 5% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%;

c. from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil; and

d. from about 20% to about 60% by weight of the adhesive of a tackifying resin;

wherein the resultant adhesive has a 180°

peel to stainless steel of less than about 2.0 pounds per lineal inch (about 360°

g/cm) and exhibits minimal staining to paper.

21. The adhered article of claim 4 wherein the adhesive has a 180°

adhesion to stainless steel of less than about 1.5 pounds per linear inch (about 270 g/cm).

22. The adhered article of claim 4 wherein the adhesive exhibits no staining to paper.

23. The adhered article of claim 4 wherein block copolymer component b) is a 100% linear styrene-ethylene/butylene-styrene block copolymer.

24. The adhered article of claim 4 wherein block copolymer a) has a diblock content of about 70% and a styrene content of about 30% by weight of the block copolymer.

25. The adhered article of claim 4 wherein the tackifying resin has a softening point of less than 100°

C.

10. A non-staining hot melt adhesive that can be coated on a label or sticker, applied to a substrate, and removed without leaving a residue behind or causing more than acceptable staining, comprising:

a. from about 25% to about 35% by weight of the adhesive of at least one block copolymer having styrene endblocks and isoprene midblocks, a styrene content of 5-16 wt-%, a diblock content of greater than about 40 wt-%, and a molecular weight of greater than 200,000;

b. from about 20% to about 70% by weight of the adhesive of at least one tackifying resin; and

c. from about 5% to about 40% by weight of the adhesive of at least one plasticizing oil.

11. The hot melt adhesive of claim 10 wherein said at least one block copolymer has a styrene content of less than about 16 wt-% of the block copolymer.

12. The adhesive of claim 10 wherein said at least one block copolymer has a diblock content of greater than about 50 wt-% of the block copolymer.

13. A hot melt adhesive characterized by causing minimal staining and having at least acceptable anti-bleeding properties when evaluated in accordance with Staining Tests A and B herein, comprising;

a. from about 10% to about 60% by weight of at least one block copolymer from about 10% to about 60% by weight of at least one block copolymer having midblocks selected from the class consisting of ethylene/butylene and ethylene/propylene, a melt index greater than about 30 g/10 minutes, a coupling efficiency less than about 35% a styrene content of from about 10% to about 30% by weight of the copolymer, and a molecular weight of less than 150,000 g/mole;

b. from about 25% to about 45% by weight of the adhesive of at least one tackifying resin having a softening point less than 100°

C.; and

c. from about 20% to about 30% by weight of the adhesive of at least one plasticizing oil.

14. The adhesive of claim 13 wherein said block copolymer is linear.

15. The adhesive of claim 13 wherein the styrene content is greater than about 25% by weight of the block copolymer.