Corn oil and protein extraction method

• US 6,433,146 B1
• Filed: 05/18/1999
• Issued: 08/13/2002
• Est. Priority Date: 05/18/1999
• Status: Active Grant

• Current Assignee: Board of Trustees of The University of Illinois
• Original Assignee: Board of Trustees of The University of Illinois
• Inventors: Cheryan, Munir
• Primary Examiner(s): Low, Christopher S. F.
• Assistant Examiner(s): Gupta, Anish
• Application Number:
  US09/313,690
• Time in Patent Office: 1,183 Days
• Field of Search: 530/412, 530/414, 530/418, 530/422, 530/424, 530/370, 530/373
• US Class Current: 530/373
• CPC Class Codes: A23J 1/142 by extracting with organic solvents
• CPC Class Codes: A23V 2002/00 Food compositions, function of food ingredients or processes for food or foodstuffs
• CPC Class Codes: A23V 2300/34 Membrane process
• CPC Class Codes: C11B 1/10 by extracting
• CPC Class Codes: C11B 1/108 after-treatment, e.g. of miscellae

Abstract

The invention is a corn product removal process that successfully extracts oil and zein from dry-milled corn. Oils and zein are extracted from corn using ethanol. Corn solids are separated from the ethanol, oil and zein mixture produced in the step of extracting. Thereafter, the ethanol, oil and zein mixture are membrane filtered to restrain zein from the mixture and pass an oil and ethanol mixture. At least one of zein or oil is then selected to be separated for an output corn product.

Claims

1. A corn product removal process, the process comprising steps of:

extracting oils and proteins from corn by subjecting the corn to an ethanol solution to thereby produce and extraction solution containing oils, corn solids, and zein protein;

separating said corn solids from said extraction solution;

membrane filtering said extraction solution after said step of separating said corn solids to restrain zein concentrate from said mixture and pass an oil and ethanol mixture;

membrane filtering said oil and ethanol mixture to restrain oil concentrate and pass ethanol;

selecting at least one of zein concentrate or oil separated in said membrane filtering steps for an output corn product,

wherein said step of membrane filtering said extraction solution uses at least one ultrafiltration membrane,

wherein said step of membrane filtering said oil and ethanol mixture uses at least one nanofiltration membrane, and

wherein said step of extraction uses an ethanol solution having an ethanol concentration of between 60-100%.

2. The process of claim 1, wherein said step of selecting comprises selecting zein for output and further comprising a step of purifying said zein concentrate to obtain zein.

3. The process of claim 2, wherein said step of purifying comprises evaporating any ethanol and water from said zein concentrate.

4. The process of claim 2, wherein said step of purifying comprises precipitating zein.

5. The process of claim 4, wherein said precipitating comprises adding cold water to said zein concentrate to lower ethanol concentration below approximately 40 percent.

6. The process of claim 1, wherein said step of selecting comprises selecting oil for output and further comprising a step of purifying oil concentrate obtained in said step of membrane filtering said oil and ethanol mixture.

7. The process of claim 6, wherein said step of purifying comprises evaporating any ethanol and water from said oil concentrate.

9. The process of claim 1, wherein said separating step comprises centrifugation.

10. The process of claim 1, further comprising a step of removing the ethanol solvent from the corn solids by application of heat.

11. The process of claim 10, further comprising a step of recycling ethanol passed in said step of membrane filtering said oil and ethanol mixture into said step of extracting.

12. The process of claim 1, further comprising a step of recycling ethanol produced in any step back into said step of extracting.

13. The process of claim 1, wherein said corn is dry grind corn.

8. The process 1, wherein said separating step comprises filtration.