Method for the gas-inflation articles

• US 6,435,552 B1
• Filed: 12/20/1999
• Issued: 08/20/2002
• Est. Priority Date: 12/18/1997
• Status: Expired due to Fees

• Current Assignee: Atlantic Research Corporation (L3Harris Technologies, Inc.)
• Original Assignee: Atlantic Research Corporation (L3Harris Technologies, Inc.)
• Inventors: Lundstrom, Norman H., Greso, Aaron J., Scheffee, Robert S.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US09/466,776
• Time in Patent Office: 974 Days
• Field of Search: 280/741, 149/36
• US Class Current: 280/741
• CPC Class Codes: A62D 1/06 containing gas-producing, chemically-reactive components
• CPC Class Codes: C06B 25/34 the compound being a nitrated acyclic, alicyclic or heterocyclic amine
• CPC Class Codes: C06D 5/06 by reaction of two or more solids
• CPC Class Codes: C07C 281/16 Compounds containing any of the groups , e.g. aminoguanidine

Abstract

A pyrotechnic gas generant composition includes a high oxygen balance compound or fuel, preferably, azodiformamidine dinitrate, which is the resulting reaction product of an aminoguanidine salt and nitric acid. Specifically, the high oxygen balance compound or fuel of the present invention is the resulting reaction product of aminoguanidine salts, such as aminoguanidine nitrate, aminoguanidine bicarbonate, or aminoguanidine sulfate with nitric acid. Preferably, the aminoguanidine salt is aminoguanidine bicarbonate. The resulting reaction product is a yellow precipitate that can be used alone, with or without oxidizers or other additives, for very rapid self-deflagration or in combination with oxidizers and additives. In each instance, the gas generant composition provides both high gas output and low production of solid combustion products. Further, the precipitant is relatively non-hygroscopic and has a high burn rate. The gas generating composition is useful as a gas generator for an air bag of an occupant restraint system for an automobile, gun propellants, inflation and expulsion devices, flotation devices, pyrotechnics, fire suppression devices and smokeless, reduced smoke and smokey rocket propellants.

Claims

1. A method for inflating an inflatable article comprising the steps of:

(a) igniting and combusting a pyrotechnic gas generant composition which includes azodiformamidine dinitrate as a high oxygen balance fuel;

(b) generating gaseous reaction products by combustion of said pyrotechnic gas generant composition according to step (a);

(c) passing said gaseous reaction products generated according to step (b) through a filter and allowing filtered gas to exit; and

then

(d) introducing the filtered gas into an inflatable article thereby inflating the same.

2. The method of claim 1, wherein said pyrotechnic gas generant composition includes 2-100% by weight of said high oxygen balance fuel.

3. The method of claim 2, wherein said pyrotechnic gas generant composition includes 40-100% by weight of said high oxygen balance fuel.

4. The method of claim 1, wherein the pyrotechnic gas generant composition further includes at least one oxidizer which is present in said pyrotechnic gas generant composition in an amount up to 98% by weight.

5. The method of claim 4, wherein said at least one oxidizer is present in an amount up to 60% by weight of said pyrotechnic gas generant composition.

6. The method of claim 4, wherein said at least one oxidizer is substantially non-hygroscopic.

7. The method of claim 1, wherein said pyrotechnic gas generant composition further includes at least one additive selected from the group consisting of a scavenger, ignition aid, ignition initiator, gas conversion catalyst, ballistic modifier, slag formers, binders, plasticizers, fuels, stabilizers, curing agents, cure catalysts, cross linkers, inorganic coolants, organic coolants and compounding aids and mixtures thereof.

8. The method of claim 4, wherein said at least one oxidizer is selected from the group consisting of alkali metal, alkaline earth metal, transition metal and transition metal complex nitrates, nitrites, chlorates, chlorites, perchlorates, chromates, or mixtures thereof.

9. The method of claim 8, wherein said oxidizer comprises sodium nitrate.

10. The method of claim 9, wherein said oxidizer further comprises ammonium perchlorate.

11. The method of claim 4, wherein said oxidizer comprises phase stabilized ammonium nitrate.

12. The method of claim 4, wherein said oxidizer is at least one selected from the group consisting of ammonium perchlorate, ammonium nitrate, potassium perchlorate, strontium nitrate, potassium nitrate, lithium nitrate, lithium carbonate and mixtures thereof.

13. The method of claim 1, wherein said azodiformamidine dinitrate is crystallized or recrystallized.

14. The method of claim 1, wherein said pyrotechnic gas generant composition includes at least one other fuel.

15. The method of claim 14, wherein said at least one other fuel is selected from the group consisting of hydrazodicarbonamidine, diazoguanidine, formamidine, bisformamidine, azobisformamidine, guanyl azide and mixtures thereof.

16. The method of claim 14, wherein said at least one other fuel is at least one selected from the group consisting of guanyl azide nitrate, diazoguanidine nitrate, azobisnitroformamidine, 1,1′

-azodiformamidine dipicrate, and mixtures thereof.