Color ink composition for graphic art ink jet image printers

• US 6,436,180 B1
• Filed: 03/31/2000
• Issued: 08/20/2002
• Est. Priority Date: 03/31/2000
• Status: Expired due to Term

• Current Assignee: Hewlett-Packard Development Company, L.P. (HP Inc.)
• Original Assignee: Hewlett-Packard Company (HP Inc.)
• Inventors: Iu, Kai-Kong, Chou, Hsin-Chieh, Canfield, Duane G., Ma, Zeying, Stramel, Rodney D., Yue, Shunqiong
• Primary Examiner(s): Klemanski, Helene
• Assistant Examiner(s): Faison, Veronica F.
• Application Number:
  US09/540,102
• Time in Patent Office: 872 Days
• Field of Search: 106/31.89, 106/31.86, 106/31.77, 106/31.75, 106/31.58, 106/31.59, 106/31.47, 106/31.43
• US Class Current: 106/31.59
• CPC Class Codes: C09D 11/38 characterised by non-macromolecular additives other than solvents, pigments or dyes
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing

Abstract

An ink jet ink composition is provided for large format printers for printing on both porous, non-porous, and hybrid glossy media. The ink composition comprises at least one water-soluble dye and a vehicle comprising at least one co-solvent and at least two different surfactants, a non-ionic surfactant and a fluoro-surfactant. The total surfactant concentration ranges from about 0.1 to 5 wt % of the ink composition. The non-ionic surfactant is present in a range of about 0.05 to 3 wt % of the ink composition, while the fluoro-surfactant is present in a range of about 0.001 to 3 wt % of the ink composition. The ink formulation that works well with porous, non-porous, and hybrid glossy media and provides substantially instant ink drying and light fastness of the ink. Further, the ink formulation evidences excellent image quality. The ink can also pass harsh pen material compatibility tests. The ink does not puddle on the surface of the orifice plate in the default pen, yet has low viscosity. The ink is excellent in pen reliability such as long decap time, no decel, no kogation, and good drop directionality.

Claims

1. An ink-jet ink for printing on porous, non-porous, and hybrid glossy print media, said ink-jet ink comprising at least one colorant and a vehicle comprising at least one water-miscible organic co-solvent and water, said ink-jet ink further comprising at least three surfactants, the total surfactant concentration ranging from about 0.1 to 5 wt %, a first surfactant consisting essentially of an anionic surfactant, a second surfactant consisting essentially of a non-ionic surfactant, and a third surfactant consisting essentially of a fluorosurfactant, for reducing dry-time, increasing printer/media throughput, and providing good image quality on said glossy print media, wherein said fluoro-surfactant is selected from the group consisting of (R_FCH₂CH₂O)_xPO(O⁻

NH₄⁺)_y, where R_F is F(CF₂CF₂)_z, where z=1-7 and where x+y=3;

(R_FCH₂CH₂O)_xPO(O⁻

NH₄⁺)_y, where R_F is F(CF₂CF₂)_z, where z=1-7 and where x+y=3+hydrocarbon surfactant;

R_FCH₂CH₂SO₃H, where R_F is F(CF₂CF₂)_z, where z=1-9;

R_FCH₂CH₂SO₃—

NH₄⁺, where R_F is F(CF₂CF₂)_z, where z=1-9;

C₆F₁₃CH₂CH₂SO₃H;

C₆F₁₃CH₂CH₂SO₃⁻

NH₄⁺;

R_FCH₂CH₂S—

CH₂CH₂COO⁻

Li⁺, where R_F is F(CF₂CF₂)_z, where z=1-9;

R_FCH₂CH₂O(CH₂CH₂O)_xH, where R_F is F(CF₂CF₂), where z=1-7;

R_FCH₂CH₂O—

(CH₂CH₂O)_yH, where R_F is F(CF₂CF₂)_z, where z=1-9;

ammonium perfluoroalkyl sulfonates;

potassium fluorinated alkyl carboxylates;

fluorinated alkyl polyoxyethylene ethanols;

fluorinated alkyl alkoxylate; and

fluorinated alkyl ethers.

2. The ink-jet ink of claim 1 wherein said non-ionic surfactant has a concentration within a range of about 0.05 to 3 wt % of said ink and wherein said fluoro-surfactant has a concentration within a range of about 0.001 to 3 wt % of said ink.

3. The inkjet ink of claim 1 wherein said first surfactant has a concentration within a range of about 0.05 to 3 wt % of said ink.

4. The ink-jet ink of claim 1 wherein said first surfactant is a diphenyl sulfonate derivative, a sulfonate, or a dioctyl sodium sulfosuccinate, said second surfactant is an acetylenic ethoxylated diol or a polyethylene oxide ether or a polypropylene oxide ether, and said third surfactant is said fluoro-surfactant.

5. The ink-jet ink of claim 1 wherein said colorant is a water-soluble dye.

6. The ink-jet ink of claim 5 wherein said water-soluble dye comprises at least one dye selected from the group consisting of yellow, cyan, and magenta dyes.

7. The ink-jet ink of claim 6 wherein said yellow dye consists essentially of Direct Yellow 132, wherein said cyan dye consists essentially of Direct Blue 199, and wherein said magenta dye is selected from the group consisting of Magenta 377 and a mixture consisting essentially of Magenta 377 and Acid Red 52.

8. The ink-jet ink of claim 1 wherein said at least one water-miscible cosolvent is selected from the group consisting of nitrogen-containing ketones;

diols selected from the group consisting of ethanediols, propanediols, butanediols, pentanediols, hexanediols, heptanediols, and octanediols;

C₃-C₆ alcohols and isomers thereof;

glycol ethers selected from the group consisting of polyalkylene glycols, and polymeric glycols;

thioglycol ethers;

glycol ureas; and

polyalkoxylated triols.

9. The ink-jet ink of claim 8, wherein said at least one water-miscible organic co-solvent is selected from the group consisting of 2-pyrrolidone, N-methylpyrrolid-2-one (NMP), 1,3-dimethylimidazolid-2-one, octyl-pyrrolidone, 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, ²-ethyl-2-hydroxymethyl- 1,3-propanediol, ethylhydroxy-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol, 2,5-hexanediol, 1,2-heptanediol, 1,7-heptanediol, 1,2-octanediol, 1,8-octanediol, propanol, butanol, pentanol, and hexanol, diethylene glycol, tri-ethylene glycol, tetraethylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene 92 glycol, Polyethylene Glycol 200, Polyethylene Glycol 300, Polyethylene Glycol 400, Polypropylene Glycol 400, and thiodiglycol.

10. The ink-jet ink of claim 9 wherein said at least one water-miscible or-ganic co-solvent comprises a mixture of 2-pyrrolidone and 1,6-hexanediol.

11. The ink-jet ink of claim 1 further comprising at least one component independently selected from the group consisting of buffers, biocides, and metal chelators.

12. An ink-jet ink for printing on porous, non-porous, and hybrid glossy print media, said ink-jet ink comprising (a) 0.5 to 5 wt % of at least one water-soluble dye selected from the group consisting of yellow, cyan, and magenta dyes and (b) a vehicle comprising 5 to 20 wt % of at least one water-miscible organic co-solvent, about 0.1 to 5 wt % of a surfactant mixture comprising an anionic surfactant, a non-ionic surfactant, and an anionic fluoro-surfactant selected from the group consisting of (R_FCH₂CH₂O)_xPO(O⁻

NH₄⁺)_y, where R_F is F(CF₂CF₂)_z, where z=1-7 and where x+y=3;

(R_FCH₂CH₂O)_xPO(O⁻

NH₄⁺)_y, where R_F is F(CF₂CF₂)_z, where z=1-7 and where x+y=3+hydrocarbon surfactant;

R_FCH₂CH₂SO₃H, where R_F is F(CF₂CF₂)_z, where z=1-9;

R_FCH₂CH₂SO₃⁻

NH₄⁺, where R_F is F(CF₂CF₂)_z, where z=1-9;

C₆F₁₃CH₂CH₂SO₃H;

C₆F₁₃CH₂CH₂SO₃⁻

NH₄⁺;

R_FCH₂CH₂S—

CH₂CH₂COO⁻

Li⁺, where R_F is F(CF₂CF₂)_z, where z=1-9;

R_FCH₂CH₂O(CH₂CH₂O)_xH, where R_F is F(CF₂CF₂)_z, where z=1-7;

R_FCH₂CH₂O(CH₂CH₂O)_yH, where R_F is F(CF₂CF₂)_z, where z=1-9;

ammonium perfluoroalkyl sulfonates;

potassium fluorinated alkyl carboxylates;

fluorinated alkyl polyoxyethylene ethanols;

fluorinated alkyl alkoxylate; and

fluorinated alkyl ethers;

0 to about 1.5 wt % of at least one component independently selected from the group consisting of buffers, biocides, and metal chelators; and

the balance water.

13. The ink-jet ink of claim 12 wherein said first surfactant is a diphenyl sulfonate derivative, a sulfonate, or a dioctyl sodium sulfosuccinate, said second surfactant is an acetylenic ethoxylated diol or a polyethylene oxide ether or a polypropylene oxide ether, and said third surfactant is said fluoro-surfactant.

14. The ink-jet ink of claim 12 wherein said yellow dye consists essentially of Direct Yellow 132, wherein said cyan dye consists essentially of Direct Blue 199, and wherein said magenta dye comprises a mixture consisting essentially of Magenta 377 and Acid Red 52.

15. The ink-jet ink of claim 12 wherein said at least one water-miscible cosolvent is selected from the group consisting of nitrogen-containing ketones;

diols selected from the group consisting of ethanediols, propanediols, butanediols, pentanediols, hexanediols, heptanediols, and octanediols;

C₃-C₆ alcohols and isomers thereof;

glycol ethers selected from the group consisting of polyalkylene glycols, and polymeric glycols;

thioglycol ethers;

glycol ureas; and

polyalkoxylated triols.

16. The ink-jet ink of claim 15 wherein said at least one water-miscible organic co-solvent is selected from the group consisting of 2-pyrrolidone, N-methyl-pyrrolid-2-one (NMP), 1,3-dimethylimidazolid-2-one, octyl-pyrrolidone, 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 2-ethyl-2-hydroxymethyl- 1,3-propanediol, ethylhydroxypropanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol, 2,5-hexanediol, 1,2-heptanediol, 1,7-heptanediol, 1,2-octanediol, 1,8-octanediol, propanol, butanol, pentanol, and hexanol, diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, Polyethylene Glycol 200, Polyethylene Glycol 300, Polyethylene Glycol 400, Polypropylene Glycol 400, and thiodiglycol.

17. The ink-jet ink of claim 16 wherein said at least one water-miscible organic co-solvent comprises a mixture of 2-pyrrolidone and 1,6-hexanediol.

18. A method of printing an ink-jet ink on porous, non-porous, and hybrid glossy print media, said method comprising:

(a) providing an ink-jet ink composition, said ink-jet ink comprising at least one colorant and a vehicle comprising at least one water-miscible organic co-solvent and water, said ink-jet ink further comprising at least three surfactants, the total surfactant concentration ranging from about 0.1 to 5 wt %, a first surfactant consisting essentially of an anionic surfactant, a second surfactant consisting essentiaily of a non-ionic surfactant, and a third surfactant consisting essentially of a fluoro-surfactant, wherein said fluoro-surfactant is selected from the group consisting of (R_FCH₂CH₂O)_xPO(O⁻

NH₄⁺)_y, where R_F is F(CF₂CF₂)_z, where z=1-7 and where x+y=3;

(R_FCH₂CH₂O)_xPO(O⁻

NH₄⁺)_y, where R_F is F(CF₂CF₂)_z, where z=1-7 and where x+y=3+hydrocarbon surfactant;

R_FCH₂CH₂SO₃H, where R_F is F(CF₂CF₂)_z, where z=1-9;

R_FCH₂CH₂SO₃⁻

NH₄⁺, where R_F is F(CF₂CF₂)_z, where z=1-9;

C₆F₁₃CH₂CH₂SO₃H;

C₆F₁₃CH₂CH₂SO₃⁻

NH₄⁺;

R_FCH₂CH₂S—

CH₂CH₂COO⁻

Li⁺, where R_F is F(CF₂CF₂)_z, where z=1-9;

R_FCH₂CH₂O(CH₂CH₂O)_xH, where R_F is F(CF₂CF₂)_z, where z=1-7;

R_FCH₂CH₂O(CH₂CH₂O)_yH, where R_F is F(CF₂CF₂)_z, where z=1-9;

ammonium perfluoroalkyl sulfonates;

potassium fluorinated alkyl carboxylates;

fluorinated alkyl polyoxyethylene ethanols;

fluorinated alkyl alkoxylate; and

fluorinated alkyl ethers; and

(b) causing droplets of said ink-jet ink composition to be jetted through an orifice plate onto said print media.

19. The method of claim 18 wherein said non-ionic surfactant has a concentration within a range of about 0.05 to 3 wt % of said ink and wherein said fluoro-surfactant has a concentration within a range of about 0.001 to 3 wt % of said ink.

20. The method of claim 18 wherein said first surfactant has a concentration within a range of about 0.05 to 3 wt % of said ink.

21. The method of claim 18 wherein said first surfactant is a diphenyl sulfonate derivative, a sulfonate, or a dioctyl sodium sulfosuccinate, said second surfactant is an acetylenic ethoxylated diol or a polyethylene oxide ether or a polypropylene oxide ether, and said third surfactant is said fluoro-surfactant.