Particulate fluorescent substance

• US 6,436,314 B1
• Filed: 05/16/2001
• Issued: 08/20/2002
• Est. Priority Date: 03/17/1994
• Status: Expired due to Fees

• Current Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Original Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Inventors: Yamada, Yukinori, Kamoto, Takanori, Saibara, Shoji, Oshima, Toshio, Nabeshima, Tomio
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US09/855,647
• Publication Number:
  US 20020043647A1
• Time in Patent Office: 461 Days
• Field of Search: 252/301.16, 252/301.4 R, 252/301.65
• US Class Current: 252/301.40R
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: C09K 11/7701 Chalogenides
• CPC Class Codes: C09K 11/7706 Aluminates
• CPC Class Codes: C09K 11/7708 Vanadates; Chromates; Molybdates; Tungstates
• CPC Class Codes: C09K 11/7709 Phosphates
• CPC Class Codes: C09K 11/7756 containing neodynium
• CPC Class Codes: C09K 11/7769 Oxides C09K11/7768 takes precedence
• CPC Class Codes: C09K 11/7774 Aluminates
• CPC Class Codes: C09K 11/7776 Vanadates; Chromates; Molybdates; Tungstates
• CPC Class Codes: C09K 11/7777 Phosphates

Abstract

A fluorescent substance of the following general formula:

Ln_XA_1−XPO₄

wherein Ln represents at least one element selected from the group consisting of Nd, Yb and Er; A represents at least one element selected from the group consisting of Y, La, Gd, Bi, Ce, LU, In and Tb; and X represents a value within the range of 0.01 to 0.99.

Claims

1. A fluorescent substance of a kind capable of emitting, in response to irradiation of exciting light, a fluorescent light of a wavelength different from that of the exciting light, characterized in that the average particle size of the fluorescent substance is smaller than the wavelength of the fluorescent light at the maximum intensity of such fluorescent light emitted by such fluorescent substance, and wherein the fluorescent substance is an organic metallic compound containing at least Nd as an optical active element.

7. The fluorescent substance as defined in claim 1 or 4, characterized in that the organic metallic compound contains at least one organic group selected from the group consisting of carboxylic acid, ketone, ether and amine.

8. The fluorescent substance as defined in claim 1 or 4, characterized in that the organic metallic compound is at least one organic group selected from the group consisting of neodymium cinnamate, complex salt of cinnamic acid with neodymium and ytterbium, complex salt of benzoic acid with neodymium and ytterbium, neodymium naphthoate, and complex salt of naphthoic acid with neodymium and ytterbium.

9. The fluorescent substance as defined in claim 1 or 4, characterized in that the fluorescent substance contains Nd and Yb, the molar ratio of Nd relative to Yb (Nd:

Yb) being within the range of 9;

1 to 5;

5.

2. A fluorescent substance of a kind capable of emitting, in response to irradiation of exciting light, a fluorescent light of a wavelength different from that of the exciting light, characterized in that the average particle size of the fluorescent substance is smaller than the wavelength of the fluorescent light at the maximum intensity of such fluorescent light emitted by such fluorescent substance, wherein the rise time required for the intensity of the fluorescent substance to reach 90% of the maximum intensity thereof subsequent to irradiation of the exciting light is within 200μ

sec, and wherein the fluorescent substance is comprised of an organic metallic compound containing as an optically active element, at least Nd.

3. A fluorescent substance of a kind capable of emitting, in response to irradiation of exciting light, a fluorescent light of a wavelength different from that of the exciting light, characterized in that the average particle size of the fluorescent substance is smaller than the wavelength of the fluorescent light at the maximum intensity of such fluorescent light emitted by such fluorescent substance, and wherein the fall time required for the intensity of the fluorescent light to attenuate 80% of the maximum intensity thereof subsequent to interruption of the irradiation is within 200μ

sec, and wherein the fluorescent substance is comprised of an organic metallic compound containing as an optically active element, at least Nd.

4. A fluorescent substance of a kind capable of emitting, in response to irradiation of exciting light, a fluorescent light of a wavelength different from that of the exciting light, characterized in that the average particle size of the fluorescent substance is smaller than the wavelength of the fluorescent light at the maximum intensity of the exciting light, wherein the fluorescent substance is an organic metallic compound containing at least Nd as an optical active element.

5. A fluorescent substance of a kind capable of emitting, in response to irradiation of exciting light, a fluorescent light of a wavelength different from that of the exciting light, characterized in that the average particle size of the fluorescent substance is smaller than the wavelength of the fluorescent light at the maximum intensity of the exciting light, wherein the rise time required for the intensity of the fluorescent substance to reach 90% of the maximum intensity thereof subsequent to irradiation of the exciting light is within 200μ

sec, and wherein the fluorescent substance is comprised of an organic metallic compound containing as an optically active element, at least Nd.

6. A fluorescent substance of a kind capable of emitting, in response to irradiation of exciting light, a fluorescent light of a wavelength different from that of the exciting light, characterized in that the average particle size of the fluorescent substance is smaller than the wavelength of the fluorescent light at the maximum intensity of the exciting light, and wherein the fall time required for the intensity of the fluorescent light to attenuate 80% of the maximum intensity thereof subsequent to interruption of the irradiation is within 200μ

sec, wherein the fluorescent substance is comprised of an organic metallic compound containing as an optically active element, at least Nd.