Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal

• US 6,436,893 B1
• Filed: 10/18/2000
• Issued: 08/20/2002
• Est. Priority Date: 01/13/1997
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Man, Victor F., Olson, Keith E., Lentsch, Steven E.
• Primary Examiner(s): Green, Anthony J.
• Application Number:
  US09/691,012
• Time in Patent Office: 671 Days
• Field of Search: 510/222, 510/224, 510/225, 510/228, 510/236, 510/298, 510/299, 510/346, 510/445, 510/446
• US Class Current: 510/446
• CPC Class Codes: C11D 17/0047 Detergents in the form of bars or tablets
• CPC Class Codes: C11D 17/0052 Cast detergent compositions
• CPC Class Codes: C11D 17/0065 Solid detergents containing builders C11D17/06 takes precedence
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/06 Phosphates, including polyphosphates
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/361 Phosphonates, phosphinates or phosphonites
• CPC Class Codes: C11D 3/364 containing nitrogen

Abstract

Solid block alkaline detergent compositions are disclosed comprising a source of alkalinity, and other detergent additives including sequestrants. The solid block detergents of the invention used a mixed inorganic and organic sequestrant composition that successfully softens service water used in manufacturing aqueous detergents from the composition, but also obtains substantially improved organic soil removal on dishware or flatware. The solid block detergents of the invention comprise large masses of the chemical ingredients having a weight of greater than about 500 grams in a solid block product format that is typically dispensed using a spray on water dispenser that creates an aqueous concentrate that is used in a washing machine.

Claims

1. An alkaline detergent composition having improved organic soil removal capacity, said detergent comprising:

(a) about 0.1 to 70 wt. % of an alkali metal carbonate;

(b) about 1 to about 20 wt. % of a surfactant; and

(c) a sequestrant comprising an organic phosphonate present in an amount of about 0.1 to 15 wt. % of the composition and an inorganic condensed phosphate present in an amount of about 5 to 40 wt. % of the composition, the sequestrant comprising at least about 1 part by weight of organic phosphonate composition per each one hundred parts by weight of the inorganic condensed phosphate;

wherein there is less than about 9 wt % total phosphorus in the composition; and

the combination of the inorganic condensed phosphate and the organic phosphonate in the sequestrant provides for improved organic soil removal.

2. The composition of claim 1, wherein the surfactant comprises a nonionic surfactant.

3. The composition of claim 1, wherein the inorganic condensed phosphate comprises sodium tripolyphosphate.

4. The composition of claim 1, wherein the organic phosphonate comprises amino trimethylene phosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, 1-(hydroxy ethylidene)-1,1-diphosphonic acid, or mixtures thereof.

5. The composition of claim 1, wherein the alkali metal carbonate comprises sodium carbonate that is present in an amount of about 0.1 to about 60 wt % of the composition.

6. The composition of claim 1, comprising about 5 to about 35 wt % of an inorganic condensed phosphate.

7. The composition of claim 1, comprising about 10 to about 35 wt % of sodium tripolyphosphate and about 1 to about 5 wt % of amino trimethylene phosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, 1-(hydroxy ethylidene)-1,1-diphosphonic acid or mixtures thereof.

8. The composition of claim 1, wherein the composition is provided in a form of powder, agglomeration, liquid, pellet, solid block, or combinations thereof.

9. The composition of claim 1, wherein the composition is provided in the form of a solid block.

10. An alkaline detergent composition having improved organic soil removal capacity, said detergent composition comprising:

(a) about 25 to 65 wt % of sodium carbonate;

(b) about 0.1 to about 10 wt % of a nonionic surfactant;

(c) a sequestrant comprising;

(i) an inorganic condensed phosphate present in the amount of about 10 to about 40 wt % of the composition; and

(ii) an organic phosphonate present in the amount of about 0.1 to 15 wt % of the composition; and

(d) about 0.01 to about 1.3 moles of water per each mole of sodium carbonate;

wherein there is less than about 9 wt % of total phosphorus in the detergent composition, and the combination of the inorganic condensed phosphate and the organic phosphonate in the sequestrant provides for improved organic soil removal.

11. The composition of claim 10, wherein the organic phosphonate comprises aminotrimethylene phosphonic acid or sodium salts thereof, 2-phosphonobutane-1,2,4-tricarboxylic acid or salts thereof, 4,1-(hydroxy ethylidene)-1,1-diphosphonic acid or salts thereof, or mixtures thereof.

12. The composition of claim 11, wherein the composition comprises about 25 to about 35 wt % of sodium tripolyphosphate and about 1 to 5 wt % of the organic phosphonate.

13. The composition of claim 11, wherein the composition is provided in a form of powder, agglomeration, liquid, pellet, solid block, or combinations thereof.

14. The composition of claim 11, wherein the composition is provided in the form of a solid block.