Adhesive for battery, battery using the same and method of fabricating the same

• US 6,444,355 B1
• Filed: 02/23/1998
• Issued: 09/03/2002
• Est. Priority Date: 02/28/1997
• Status: Expired due to Fees

• Current Assignee: Mitsubishi Denki Kabushiki Kaisha (Mitsubishi Electric Corporation)
• Original Assignee: Mitsubishi Denki Kabushiki Kaisha (Mitsubishi Electric Corporation)
• Inventors: Yoshida, Yasuhiro, Shiota, Hisashi, Murai, Michio, Inuzuka, Takayuki, Aihara, Shigeru, Hamano, Kouji, Shiraga, Syo
• Primary Examiner(s): EINSMANN, MARGARET V
• Application Number:
  US09/028,097
• Time in Patent Office: 1,653 Days
• Field of Search: 429/144, 429/192, 429/194, 429/208, 429/249, 429/253, 429/254, 525/302, 525/304, 525/305, 525/309
• US Class Current: 429/144
• CPC Class Codes: H01M 10/0431 Cells with wound or folded electrodes H01M10/045 takes precedence
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 50/449 having a layered structure
• CPC Class Codes: H01M 50/457 comprising three or more layers
• CPC Class Codes: H01M 50/46 Separators, membranes or diaphragms characterised by their combination with electrodes
• CPC Class Codes: H01M 50/461 with adhesive layers between electrodes and separators
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: H01M 6/188 Processes of manufacture
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A lithium ion battery comprising a positive electrode 1, a negative electrode 4 and a separator 7 for retaining an electrolyte, characterized in that as an adhesive 8 for bonding said positive electrode 1 to said separator 7 and said negative electrode 4 to said separator 7 there is used a thermosetting adhesive comprising a mixture of at least one organic vinyl compound containing two or more vinyl groups per molecule, a reaction catalyst and a volatile organic solvent.

Claims

1. An adhesive for battery used for adhering an electrode to a separator, comprising a mixture of

(1) at least one organic vinyl monomer having two or more vinyl groups per molecule,

(2) a volatile organic solvent,

(3) a reaction catalyst, selected from azobisisobutyronitrile, benzoyl peroxide and lauroyl peroxide,

(4) a thermoplastic resin selected from the group consisting of polyacrylic esters and polymethacrylic esters, and

(5) at least one organic vinyl monomer containing one vinyl group per molecule selected from the group consisting of methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, i-butyl methacrylate, t-butyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, isobornyl methacrylate, tetrahydrofurfuryl methacrylate, styrene, vinyl chloride and acrylonitrile,

wherein said adhesive has a property that it becomes porous when heated, whereby said at least one organic vinyl monomer having two or more vinyl groups per molecule undergoes crosslinked polymerization, and said volatile organic solvent is evaporated off, and wherein said thermoplastic resin is present in an adhesive-strength increasing amount.

2. The adhesive for battery as claimed in claim 1, wherein said organic vinyl compound having two or more vinyl groups per molecule is selected from the group consisting of an acrylic ester and methacrylic ester.

3. The adhesive for battery as claimed in claim 1, wherein the volatile organic solvent is at least one selected from the group consisting of N-methylpyrrolidone, propylene carbonate, ethylene carbonate, tetrahydrofuran, 1,3-dioxolan, diethyl carbonate, dimethyl carbonate, sulfolane, tert-butylether, iso-butylether, 1,2-dimethoxyethane, 1,2-ethoxymethoxyethane, acetone, methyl ethyl ketone, ethyl acetate, acetonitrile, diethylether, dimethylformamide and dimethyl sulfoxide.

4. The adhesive for battery as claimed in claim 3, wherein the volatile organic solvent is N-methylpyrrolidone.

5. The adhesive for battery as claimed in claim 1, wherein the reaction catalyst is azobisisobutyronitrile.

6. The adhesive for battery as claimed in claim 2, wherein the at least one organic vinyl monomer having two or more vinyl groups per molecule is ethylene glycol dimethacrylate or trimethylolpropane trimethacrylate.

7. The adhesive for battery as claimed in claim 1, wherein the thermoplastic resin is poly (methyl methacrylate).

8. The adhesive for battery as claimed in claim 1, wherein the volatile organic solvent is N-methylpyrrolidone, the reaction catalyst is azobisisobutyronitrile, the at least one organic vinyl monomer having two or more vinyl groups per molecule is ethylene glycol dimethacrylate or trimethylolpropane trimethacrylate, and the thermoplastic resin is poly (methyl methacrylate).

9. A battery comprising an electrode laminate having:

a positive electrode;

a negative electrode;

a separator which is arranged between said positive electrode and negative electrode and keeps an electrolytic solution; and

an adhesive resin layer which bonds said positive electrode and said negative electrode to said separator,

wherein said adhesive resin layer is an adhesive according to claim 1.

10. The battery as claimed in claim 9, wherein each of said positive electrode and negative electrode comprises a collector and an electrode active material layer formed on the collector, and

adhesive strength between the active material layer and the separator is not smaller than that between the active material layer and the collector.

11. The battery as claimed in claim 9, wherein said battery has a plurality of electrode laminates.

12. The battery as claimed in claim 11, wherein said plurality of electrode laminates are arranged by alternately interposing positive electrodes and negative electrodes between a plurality of cut separators one by one.

13. The battery as claimed in claim 11, wherein said plurality of electrode laminates are arranged by alternately interposing positive electrodes and negative electrodes between the gap of a wound separator one by one.

14. The battery as claimed in claim 11, wherein said plurality of electrode laminates are arranged by alternately interposing positive electrodes and negative electrodes between the gap of a pair of folded separators.

15. A method of fabricating a battery, comprising the steps of:

coating an adhesive according to claim 1 on at least one of a separator and each of negative and positive electrodes to be adhered each other;

laminating a positive electrode and a negative electrode on the both surfaces of the separator respectively to form a electrode laminate;

curing the adhesive by heating the electrode laminate so that said volatile organic solvent is distilled off said adhesive.