Diesel fuel composition

• US 6,447,558 B1
• Filed: 12/07/2000
• Issued: 09/10/2002
• Est. Priority Date: 12/21/1999
• Status: Expired due to Term

• Current Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Inventors: Miller, Richard C., Schlosberg, Richard Henry, Yeh, Lisa I-Ching, Caers, Raf F.
• Primary Examiner(s): Medley, Margaret
• Application Number:
  US09/732,455
• Publication Number:
  US 20020108299A1
• Time in Patent Office: 642 Days
• Field of Search: 444/37, 444/38, 444/39, 444/51, 444/52
• US Class Current: 44/437
• CPC Class Codes: C10L 1/026 for compression ignition
• CPC Class Codes: C10L 10/02 for reducing smoke development

Abstract

This invention is a method of reducing particulate matter emission from internal combustion engines which use a diesel fuel composition comprising a major amount of a diesel fuel having a base fuel which contains no more than 10% by weight of olefins and no more than 10% by weight of esters, by admixing said fuel with greater than 5% by weight based on the total composition of a saturated, aliphatic monohydric alcohol having on an average from 4 to 20 carbon atoms, one or more ketones having on an average 5 to 25 carbons and mixture of said alcohol(s) and ketone(s). The amount of the oxygenate in the fuel composition is sufficient to provide the fuel with at least 0.5% by weight of oxygen. The oxygenate significantly reduce particulate emissions from the exhausts of diesel powered engines.

Claims

1. A method of reducing particulate emissions from a vehicle powered by a diesel fuel composition comprising a major amount of a diesel fuel having a base distillate fuel which contains no more than 10% by weight of olefins and no more than 10% by weight of esters, said method comprising blending with the composition at least 5% by weight based on the total composition of an additive for reducing particulate emissions consisting essentially of at least one oxygenate selected from the group consisting of saturated, aliphatic monohydric primary, secondary or tertiary alcohol and mixtures thereof having on an average from 4 to 20 carbon atoms, one or more mono- or poly-ketones or keto-monohydric aliphatic alcohols having on an average 5 to 25 carbons, and mixtures of the aforesaid alcohol(s) and ketone(s) said oxygenate containing no other oxygen in its structure, the amount of the oxygenate in the composition being sufficient to provide the fuel composition with at least 2% by weight of oxygen.

2. The method according to claim 1 wherein the fuel is a distillate fuel comprising a major amount of diesel fuel which is ashless.

3. The method according to claim 1 wherein the alcohol has on an average from 6-20 carbon atoms.

4. The method according to claim 1 wherein the alcohol has on an average from 8-20 carbon atoms.

5. The method according to claim 1 wherein the ketone is an aliphatic ketone.

6. The method according to claim 1 or 5 wherein the ketone has on average from 5 to 21 carbon atoms.

7. The method according to claim 1 or 5 wherein the ketone has an average from 7 to 15 carbon atoms.

8. The method according to claim 1 wherein the alcohol is selected from hexanol, methyl hexanol, 2-ethyl hexanol, octanol, isooctanol, nonanol, iso-nonanol, 2-propyl heptanol, 2,4-dimethyl heptanol, decanol, isodecanol, undecanol, isoundecanol, dodecanol, isododecanol, tridecanol, iso-tridecanol, tetradecanol, iso-tetradecanol, myristyl alcohol, hexadecanol, octadecanol, stearyl alcohol, isostearyl alcohol, eicosanol, di-isobutyl carbinol, tetrahydrolinalool, and mixtures thereof.

9. The method according to claim 1 wherein the amount of oxygenate used to provide the composition with at least 2% by weight of oxygen is in the range from 7 to 60% by weight based on the total fuel composition.

10. The method according to claim 1 wherein the diesel composition comprises at least 80% by weight of the base fuel.

11. A method for reducing CO emissions without any substantial increase in NO_x from a vehicle powered under high load conditions by a diesel fuel composition comprising a major amount of the diesel fuel having a base distillate fuel which contain no more than 10% by weight of olefins as base stock and no more than 10% by weight of an ester, said method comprising blending with the composition at least 5% by weight based on the total composition of an additive consisting essentially of at least one oxygenate selected from the group consisting of saturated, aliphatic monohydric primary, secondary, tertiary alcohol and mixtures thereof having on an average from 4 to 20 carbon atoms, one or more mono- or poly-ketones or keta-monohydric aliphatic alcohol having on an average 5 to 25 carbons, and mixtures of the aforesaid alcohol(s) and ketone(s), said oxygenate containing no other oxygen in its structure, the amount of the oxygenate in the composition being sufficient to provide the fuel composition with at least 2% by weight of oxygen.