Thermoplastic sheet with textured surface for use in composite layered product with interlocking interface and method thereof

• US 6,458,446 B1
• Filed: 09/14/1999
• Issued: 10/01/2002
• Est. Priority Date: 09/14/1999
• Status: Active Grant

• Current Assignee: Pureflex Inc.
• Original Assignee: Pureflex Inc.
• Inventors: Andronaco, Ronald V., Beaumont, Joseph H.
• Primary Examiner(s): Thibodeau, Paul
• Assistant Examiner(s): Paulraj, Christopher
• Application Number:
  US09/396,818
• Time in Patent Office: 1,113 Days
• Field of Search: 428/33, 428/161, 428/171, 428/120, 428/156, 428/180, 428/53, 428/54
• US Class Current: 428/161
• CPC Class Codes: B29C 37/0082 Mechanical anchoring B29C66/303 takes precedence
• CPC Class Codes: B29C 59/02 by mechanical means, e.g. pressing B29C59/007 takes precedence; embossing expanded porous articles B29C44/5627
• CPC Class Codes: B29K 2023/0683 UHMWPE, i.e. ultra high molecular weight polyethylene
• CPC Class Codes: B29K 2027/12 containing fluorine
• CPC Class Codes: B32B 2327/18 PTFE, i.e. polytetrafluoroethylene
• CPC Class Codes: B32B 25/08 of synthetic resin
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 3/30 characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs apertured layer B32B3/266; layer with cavities or internal voids B32B3/26
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10T 428/17 Three or more coplanar interfitted sections with securing means
• CPC Class Codes: Y10T 428/24182 Inward from edge of web or sheet
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/24521 with component conforming to contour of nonplanar surface
• CPC Class Codes: Y10T 428/24603 Fiber containing component
• CPC Class Codes: Y10T 428/24678 Waffle-form

Abstract

A process for manufacturing a part includes the steps of molding a thermoplastic material into a generally planar sheet form having a textured surface on at least one side. The textured surface is defined by a plurality of protuberances with at least one side wall extending outwardly from the sheet. The thermoplastic material is molded with a predetermined pressure between a die and within a perforated insert. The molded thermoplastic material sheet and perforated insert are removed from the die after molding. The molded thermoplastic material sheet is sintered at a predetermined temperature for a predetermined period of time. The molded, sintered, thermoplastic material sheet is stripped from the perforated insert. The sheet can be masked for etching if desired. The sheet can be inserted into a molding die, where a dissimilar material is introduced into the die under pressure. The plurality of protuberances on the sheet are deformed during the molding of the dissimilar material, so that at least one side wall of the protuberance is deformed to trap a portion of the molded dissimilar material between the side wall of each protuberance and the thermoplastic sheet material to mechanically interlock the two materials along an interface disposed therebetween.

Claims

1. A part manufactured according to a process comprising the steps of molding a thermoplastic material into a generally planar sheet form having a textured surface on at least one side, the textured surface defined by a plurality of protuberances with at least one side wall extending outwardly from the sheet, the thermoplastic material molded with a predetermined pressure between a die and within a perforated insert, removing the molded thermoplastic material sheet and perforated insert from the die, and sintering the molded thermoplastic material sheet at a predetermined temperature for a predetermined period of time, the part comprising:

a thermoplastic material molded and sintered into a generally planar sheet form having a textured surface on at least one side, the textured surface defined by a plurality of protuberances with at least one side wall extending outwardly from the sheet; and

a dissimilar material layer molded to the textured surface of the sheet and a mechanically locked interface between the dissimilar material layer and the sheet as a result of deformation of the protuberances during the molding process to define a composite layered product, the composite layered product defining a pump diaphragm with the thermoplastic material sheet capable of exposure to a corrosive fluid to be transported mechanically locked to the dissimilar material.

2. The part of claim 1 further comprising:

the protuberances increasing an effective surface area of the thermoplastic material sheet by at least 35% compared with a surface area of the sheet absent the protuberances.

3. The part of claim 1 further comprising:

the protuberances increasing an effective surface area of the thermoplastic material sheet by between 35% and 40%, inclusive compared with a surface area of the sheet absent the protuberances.

4. The part of claim 1 further comprising:

the at least one side wall extending outwardly in a direction generally perpendicular to the sheet.

5. The part of claim 1 further comprising:

the protuberances spaced from one another on the at least one side of the sheet.

6. The part of claim 1 further comprising:

the protuberances disposed in a geometric pattern.

7. The part of claim 1 wherein the thermoplastic material is selected from the group consisting of fluoroplastic polymers, polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP) copolymers, perfluoroalkoxy (PFA) resins, polychlorotrifluoroethylene (PCTFE), ethylene-chlorotrifluoroethylene (ECTFE) copolymers, ethylene-tetrafluoroethylene (ETFE) copolymers, polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), ultrahigh-molecular-weight polyethylene (UHMWPE), and mixtures thereof.

8. The part of claim 1 wherein the thermoplastic material contains as a major constituent a material selected from the group consisting of fluoroplastic polymers, polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP) copolymers, perfluoroalkoxy (PFA) resins, polychlorotrifluoroethylene (PCTFE), ethylene-chlorotrifluoroethylene (ECTFE) copolymers, ethylene-tetrafluoroethylene (ETFE) copolymers, polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), ultrahigh-molecular-weight polyethylene (UHMWPE), and mixtures thereof.

9. The part of claim 1 wherein the dissimilar material is selected from the group consisting of natural rubbers, vulcanized rubbers, butadiene-styrene copolymers, chloroprene polymers, nitrile rubbers, butadiene-acrylonitrile copolymers, isobutylene copolymers, butyl rubbers, polysulfide rubbers, ethylene-propylene rubbers, polyurethane elastomers, silicone rubbers, fluorocarbon elastomers, polyester elastomers, chlorinated rubbers, rubber hydrochloride, cyclized rubbers, chlorosulphonated polyethylene, and mixtures thereof.

10. The part of claim 1 wherein the dissimilar material contains as a major constituent an elastomer material selected from the group consisting of natural rubbers, vulcanized rubbers, butadiene-styrene copolymers, chloroprene polymers, nitrile rubbers, butadiene-acrylonitrile copolymers, isobutylene copolymers, butyl rubbers, polysulfide rubbers, ethylene-propylene rubbers, polyurethane elastomers, silicone rubbers, fluorocarbon elastomers, polyester elastomers, chlorinated rubbers, rubber hydrochloride, cyclized rubbers, chlorosulphonated polyethylene, and mixtures thereof.

11. The part of claim 1 further comprising:

the thermoplastic material sheet composed at least primarily of polytetrafluoroethylene (PTFE) and the dissimilar material composed at least primarily of rubber.

12. The part of claim 1 further comprising:

the plurality of protuberances distributed over the at least one surface of the sheet.

13. The part of claim 12 further comprising:

the plurality of protuberances evenly distributed over the at least one surface of the sheet.

14. The part of claim 12 further comprising:

the plurality of protuberances uniformly distributed over the at least one surface of the sheet.

15. The part of claim 1 further comprising:

the plurality of protuberances deformable under pressure so that at least one side wall of the protuberance moves into an angled orientation with respect to the at least one surface of the sheet to define a plurality of individual mechanical locking members along an interface between the sheet and the dissimilar material layer to be introduced during pressurized molding.

16. The part of claim 15 further comprising:

a portion of the dissimilar material layer being trapped between the angled side wall of each protuberance mechanically interlocking the sheet along the interface with the dissimilar material layer.

17. A part comprising:

a thermoplastic material molded and sintered into a generally planar sheet form having a textured surface on at least one side, the textured surface defined by a plurality of protuberances with at least one side wall extending outwardly from the sheet; and

a dissimilar material layer molded to the textured surface of the sheet and a mechanically locked interface between the dissimilar material layer and the sheet as a result of deformation of the protuberances during the molding process to define a composite layered product, the composite layered product defining a pump diaphragm with the thermoplastic material sheet capable of exposure to a corrosive fluid to be transported mechanically locked to the dissimilar material.

18. The part of claim 17 further comprising:

the protuberances increasing an effective surface area of the thermoplastic material sheet by at least 35% compared with a surface area of the sheet absent the protuberances.

19. The part of claim 17 further comprising:

the protuberances increasing an effective surface area of the thermoplastic material sheet by between 35% and 40%, inclusive compared with a surface area of the sheet absent the protuberances.

20. The part of claim 17 further comprising:

the at least one side wall extending outwardly in a direction generally perpendicular to the sheet.

21. The part of claim 17 further comprising:

the protuberances spaced from one another on the at least one side of the sheet.

22. The part of claim 17 further comprising:

the protuberances disposed in a geometric pattern.

23. The part of claim 17 wherein the thermoplastic material is selected from the group consisting of fluoroplastic polymers, polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP) copolymers, perfluoroalkoxy (PFA) resins, polychlorotrifluoroethylene (PCTFE), ethylene-chlorotrifluoroethylene (ECTFE) copolymers, ethylene-tetrafluoroethylene (ETFE) copolymers, polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), ultrahigh-molecular-weight polyethylene (UHMWPE), and mixtures thereof.

24. The part of claim 17 wherein the thermoplastic material contains as a major constituent a material selected from the group consisting of fluoroplastic polymers, polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP) copolymers, perfluoroalkoxy (PFA) resins, polychlorotrifluoroethylene (PCTFE), ethylene-chlorotrifluoroethylene (ECTFE) copolymers, ethylene-tetrafluoroethylene (ETFE) copolymers, polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), ultrahigh-molecular-weight polyethylene (UHMWPE), and mixtures thereof.

25. The part of claim 17 wherein the dissimilar material is selected from the group consisting of natural rubbers, vulcanized rubbers, butadiene-styrene copolymers, chloroprene polymers, nitrile rubbers, butadiene-acrylonitrile copolymers, isobutylene copolymers, butyl rubbers, polysulfide rubbers, ethylene-propylene rubbers, polyurethane elastomers, silicone rubbers, fluorocarbon elastomers, polyester elastomers, chlorinated rubbers, rubber hydrochloride, cyclized rubbers, chlorosulphonated polyethylene, and mixtures thereof.

26. The part of claim 17 wherein the dissimilar material contains as a major constituent an elastomer material selected from the group consisting of natural rubbers, vulcanized rubbers, butadiene-styrene copolymers, chloroprene polymers, nitrile rubbers, butadiene-acrylonitrile copolymers, isobutylene copolymers, butyl rubbers, polysulfide rubbers, ethylene-propylene rubbers, polyurethane elastomers, silicone rubbers, fluorocarbon elastomers, polyester elastomers, chlorinated rubbers, rubber hydrochloride, cyclized rubbers, chlorosulphonated polyethylene, and mixtures thereof.

27. The part of claim 17 further comprising:

the thermoplastic material sheet composed at least primarily of polytetrafluoroethylene (PTFE) and the dissimilar material composed at least primarily of rubber.

28. The part of claim 17 further comprising:

the plurality of protuberances distributed over the at least one surface of the sheet.

29. The part of claim 28 further comprising:

the plurality of protuberances evenly distributed over the at least one surface of the sheet.

30. The part of claim 28 further comprising:

the plurality of protuberances uniformly distributed over the at least one surface of the sheet.

31. The part of claim 17 further comprising:

the plurality of protuberances deformable under pressure so that at least one side wall of the protuberance moves into an angled orientation with respect to the at least one surface of the sheet to define a plurality of individual mechanical locking members along an interface between the sheet and the dissimilar material layer to be introduced during pressurized molding.

32. The part of claim 31 further comprising:

a portion of the dissimilar material layer being trapped between the angled side wall of each protuberance mechanically interlocking the sheet along the interface with the dissimilar material layer.