Multilayer composite material and method for evaporative cooling

• US 6,464,672 B1
• Filed: 10/26/1999
• Issued: 10/15/2002
• Est. Priority Date: 07/14/1992
• Status: Expired due to Fees

• Current Assignee: Theresa M. Buckley
• Original Assignee: Theresa M. Buckley
• Inventors: Buckley, Theresa M.
• Primary Examiner(s): Lewis, Kim M.
• Application Number:
  US09/428,137
• Time in Patent Office: 1,085 Days
• Field of Search: 604/385.08, 604/304, 604/289, 604/897, 604/307, 604/308, 604/358, 604/290, 428/242, 428/304.4, 428/308.4, 428/311.1, 428/317.9, 428/309.9, 428/321.5, 128/849, 128/850, 602/41, 602/42, 165/10, 165/46, 216/7, 216/8, 215/8, 215/9
• US Class Current: 604/304
• CPC Class Codes: A41D 13/0056 using evaporative effect
• CPC Class Codes: A41D 31/065 using layered materials
• CPC Class Codes: A61F 2007/0098 ways of manufacturing heating or cooling devices for therapy
• CPC Class Codes: A61F 2007/0214 Polymers, e.g. water absorbing
• CPC Class Codes: A61F 2007/0244 with layers
• CPC Class Codes: A61F 2007/0246 with a layer having high heat transfer capability
• CPC Class Codes: A61F 2007/0249 with a layer having low heat transfer capability
• CPC Class Codes: A61F 2007/026 with a fluid absorbing layer
• CPC Class Codes: A61F 2007/0292 using latent heat produced or absorbed during phase change of materials, e.g. of super-cooled solutions
• CPC Class Codes: A61F 7/02 Compresses or poultices for effecting heating or cooling
• CPC Class Codes: A61F 7/034 Flameless
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
• CPC Class Codes: C09K 5/063 Materials absorbing or liberating heat during crystallisation; Heat storage materials
• CPC Class Codes: F24V 30/00 Apparatus or devices using heat produced by exothermal chemical reactions other than combustion
• CPC Class Codes: F28D 20/023 the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
• CPC Class Codes: Y02E 60/14 Thermal energy storage
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249958 Void-containing component is synthetic resin or natural rubbers
• CPC Class Codes: Y10T 428/249962 Void-containing component has a continuous matrix of fibers only [e.g., porous paper, etc.]
• CPC Class Codes: Y10T 428/249964 : Fibers of defined composition
• CPC Class Codes: Y10T 428/249972 : Resin or rubber element
• CPC Class Codes: Y10T 428/249981 : Plural void-containing components
• CPC Class Codes: Y10T 428/249986 : Void-containing component contains also a solid fiber or solid particle
• CPC Class Codes: Y10T 428/249987 : With nonvoid component of specified composition
• CPC Class Codes: Y10T 428/249994 : Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
• CPC Class Codes: Y10T 428/249995 : Constituent is in liquid form
• CPC Class Codes: Y10T 428/249997 : Encapsulated liquid
• CPC Class Codes: Y10T 428/31504 : Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31544 : Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31971 : Of carbohydrate

Abstract

A multilayer composite material and method for evaporative cooling of a person employs an evaporative cooling liquid that changes phase from a liquid to a gaseous state to absorb thermal energy. The evaporative cooling liquid is absorbed into a superabsorbent material enclosed within the multilayer composite material. The multilayer composite material has a high percentage of the evaporative cooling liquid in the matrix. The cooling effect can be sustained for an extended period of time because of the high percentage of phase change liquid that can be absorbed into the superabsorbent. Such a composite can be used for cooling febrile patients by evaporative cooling as the evaporative cooling liquid in the matrix changes from a liquid to a gaseous state to absorb thermal energy. The composite can be made with a perforated barrier material around the outside to regulate the evaporation rate of the phase change liquid. Alternatively, the composite can be made with an imperveous barrier material or semipermeable membrane on one side to prevent the liquid from contacting the person'"'"'s skin. The evaporative cooling liquid in the matrix can be recharged by soaking the material in the liquid. The multilayer composite material can be fashioned into blankets, garments and other articles.

Claims

1. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin during use, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the inner layer of barrier material comprises a semipermeable membrane that allows passage of the evaporative cooling liquid in vapor form, but does not allow passage of the evaporative cooling liquid in liquid form.

2. The multilayer composite material of claim 1, wherein the middle layer, the inner layer and the outer layer are bonded to one another.

3. The multilayer composite material of claim 1, wherein the middle layer, the inner layer and the outer layer are bonded to one another to enclose internal spaces within the middle layer containing the superabsorbent material.

4. The multilayer composite material of claim 1, wherein the middle layer, the inner layer and the outer layer are bonded to one another to enclose internal spaces within the middle layer containing particles of the superabsorbent material, which are then swelled in place by allowing them to absorb the evaporative cooling liquid.

5. The multilayer composite material of claim 1, wherein the superabsorbent material absorbs more than twenty times its weight of the evaporative cooling liquid.

6. The multilayer composite material of claim 1, wherein the inner layer comprises a fabric.

7. The multilayer composite material of claim 1, wherein the inner layer comprises a perforated barrier material.

8. The multilayer composite material of claim 1, wherein the inner layer comprises a porous barrier material.

9. The multilayer composite material of claim 1, wherein the semipermeable membrane allows passage of alcohol vapor, but does not allow passage of liquid alcohol.

10. The multilayer composite material of claim 1, wherein the semipermeable membrane allows passage of water vapor, but does not allow passage of liquid water.

11. The multilayer composite material of claim 1, wherein the semipermeable membrane comprises expanded polytetrafluoroethylene.

12. The multilayer composite material of claim 1, wherein the semipermeable membrane comprises cellulose acetate.

13. The multilayer composite material of claim 1, wherein the outer layer comprises a semipermeable membrane that allows passage of the evaporative cooling liquid in vapor form, but does not allow passage of the evaporative cooling liquid in liquid form.

14. The multilayer composite material of claim 1, wherein the outer layer comprises a semipermeable membrane that allows passage of water vapor, but does not allow passage of liquid water.

15. The multilayer composite material of claim 1, wherein the outer layer comprises a fabric.

16. The multilayer composite material of claim 1, wherein the outer layer comprises a perforated material.

17. The multilayer composite material of claim 1, wherein the outer layer comprises a porous material.

18. The multilayer composite material of claim 1, wherein the superabsorbent material comprises polyacrylamide.

19. The multilayer composite material of claim 1, wherein the superabsorbent material comprises methyl cellulose.

20. The multilayer composite material of claim 1, wherein the superabsorbent material comprises carboxymethyl cellulose.

21. The multilayer composite material of claim 1, wherein the superabsorbent material comprises starch grafted polyacrylate polymers.

22. The multilayer composite material of claim 1, wherein the superabsorbent material comprises polyethylene oxide.

23. The multilayer composite material of claim 1, wherein the superabsorbent material comprises crosslinked polyethylene oxide.

24. The multilayer composite material of claim 1, wherein the superabsorbent material comprises polyethylene oxide reinforced with a webbing material.

25. The multilayer composite material of claim 1, wherein the superabsorbent material is a crosslinked material.

26. The multilayer composite material of claim 1, wherein the superabsorbent material is reinforced with a webbing material.

27. The multilayer composite material of claim 1, wherein the middle layer contains particles of the superabsorbent material.

28. The multilayer composite material of claim 1, wherein the middle layer contains fibers of the superabsorbent material.

29. The multilayer composite material of claim 1, wherein the middle layer contains particles of the superabsorbent material placed into internal spaces within the middle layer.

30. The multilayer composite material of claim 1, wherein the middle layer contains particles of the superabsorbent material placed into internal spaces within the middle layer and then swelled in place by allowing them to absorb the evaporative cooling liquid.

31. The multilayer composite material of claim 1, wherein the middle layer contains particles of the superabsorbent material within a foam matrix.

32. The multilayer composite material of claim 1, wherein the middle layer contains particles of the superabsorbent material within a fibrous matrix.

33. The multilayer composite material of claim 1, wherein the middle layer comprises a foam matrix.

34. The multilayer composite material of claim 1, wherein the middle layer comprises a fibrous matrix.

35. The multilayer composite material of claim 1, wherein at least one layer of the multilayer composite material comprises a polyamide material.

36. The multilayer composite material of claim 1, wherein at least one layer of the multilayer composite material comprises a nylon material.

37. The multilayer composite material of claim 1, wherein at least one layer of the multilayer composite material comprises a kevlar material.

38. The multilayer composite material of claim 1, wherein at least one layer of the multilayer composite material comprises an aramide material.

39. The multilayer composite material of claim 1, wherein at least one layer of the multilayer composite material comprises an aromatic polyamide material.

40. The multilayer composite material of claim 1, wherein at least one layer of the multilayer composite material comprises a breathable material.

41. The multilayer composite material of claim 1, wherein the multilayer composite material is flexible.

42. The multilayer composite material of claim 1, wherein the multilayer composite material is fashioned into a garment.

43. The multilayer composite material of claim 1, wherein the multilayer composite material is fashioned into a hat.

44. The multilayer composite material of claim 1, wherein the multilayer composite material is fashioned into a glove or mitten.

45. The multilayer composite material of claim 1, wherein the multilayer composite material is fashioned into a sock or boot liner.

46. The multilayer composite material of claim 1, wherein the multilayer composite material is fashioned into a blanket.

47. The multilayer composite material of claim 1, wherein the multilayer composite material is fashioned into a medical treatment apparatus for evaporative cooling of febrile patients.

49. The multilayer composite material of claim 41, wherein the middle layer, the inner layer and the outer layer are bonded to one another to enclose internal spaces within the middle layer containing the particles of the superabsorbent material.

48. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer containing particles of a superabsorbent material for absorption of an evaporative cooling liquid within a fibrous matrix,

an inner layer of barrier material that does not allow passage of the evaporative cooling liquid in liquid form,

a porous outer layer allowing evaporation of the evaporative cooling liquid from the particles of superabsorbent material through the outer layer.

50. A multilayer composite material comprising:

middle layer containing particles of a superabsorbent material within a fibrous matrix,

an inner layer of barrier material that allows passage of water vapor, but does not allow passage of liquid water, and

a porous outer layer.

51. The multilayer composite material of claim 50, wherein the superabsorbent material is superabsorbent for water.

52. A multilayer composite material comprising:

a middle layer containing particles of a superabsorbent material,

an inner layer of barrier material, and

an outer layer,

wherein the middle layer, inner layer and outer layer are bonded to one another to enclose internal spaces within the middle layer containing the particles of superabsorbent material, and

wherein the inner layer of barrier material comprises a semipermeable membrane that allows passage of the evaporative cooling liquid in vapor form, but does not allow passage of the evaporative cooling liquid in liquid form.

53. The multilayer composite material of claim 52, wherein the superabsorbent material is superabsorbent for water.

54. A method of evaporative cooling of a person comprising:

providing a multilayer composite material comprising a middle layer containing particles of a superabsorbent material for absorption of an evaporative cooling liquid, the particles of superabsorbent material being contained within a fibrous matrix, an inner layer of barrier material between the middle layer and the person'"'"'s skin that allows passage of the evaporative cooling liquid in vapor form, but does not allow passage of the evaporative cooling liquid in liquid form, and a porous outer layer allowing evaporation of the evaporative cooling liquid from the particles of superabsorbent material through the outer layer;

absorbing an evaporative cooling liquid into the particles of superabsorbent material within the multilayer composite material;

placing the multilayer composite material containing the evaporative cooling liquid in thermal contact with the person'"'"'s skin; and

cooling the person by evaporation of the evaporative cooling liquid from the particles of superabsorbent material through the outer layer.

55. A method of evaporative cooling of a person comprising:

providing a multilayer composite material comprising a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid, an inner layer of barrier material between the middle layer and the person'"'"'s skin, wherein the inner layer of barrier material comprises a semipermeable membrane that allows passage of the evaporative cooling liquid in vapor form, but does not allow passage of the evaporative cooling liquid in liquid form, and an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer;

absorbing an evaporative cooling liquid into the superabsorbent material within the multilayer composite material;

placing the multilayer composite material containing the evaporative cooling liquid in thermal contact with the person'"'"'s skin; and

cooling the person by evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer.

56. A method of evaporativve cooling of a person comprising;

providing a multilayer composite material comprising a middle layer including a superabsorbent material for absorbtion of an evaporative coling liquid, an inner layer of barrier material between the middle layer and the person'"'"'s skin, and an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbant material through the outer layer;

absorbing an evaporative cooling liquid into the superabsorbent material within the multilayer composite material;

placing the multilayer composite material containing the evaporative cooling liquid in thermal contact with the person'"'"'s skin; and

cooling the person by evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer.

57. A method of evaporative cooling of a person comprising:

providing a multilayer composite material comprising a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid, an inner layer of barrier material between the middle layer and the person'"'"'s skin, and an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer;

absorbing an evaporative cooling liquid into the superabsorbent material within the multilayer composite material;

placing the multilayer composite material containing the evaporative cooling liquid in thermal contact with the person'"'"'s skin; and

cooling the person by evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer;

wherein the absorbing step comprises absorbing alcohol into the superabsorbent material within the multilayer composite material.

58. The method of claim 57, wherein the multilayer composite material is utilized for evaporative cooling of a febrile patient.

59. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the middle layer, the inner layer and the outer layer are bonded to one another to enclose internal spaces within the middle layer containing the superabsorbent material.

60. The multilayer composite material of claim 59, wherein the particles of the superabsorbent material within the middle layer are swelled in place by allowing them to absorb the evaporative cooling liquid.

61. The multilayer composite material of claim 59, wherein the particles of the superabsorbent material within the middle layer are swelled in place by allowing them to absorb the evaporative cooling liquid.

62. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the inner layer of barrier material is impermeable to the evaporative cooling liquid.

63. The multilayer composite material of claim 62, wherein the semipermeable membrane allows passage of water vapor, but does not allow passage of liquid water.

64. The multilayer composite material of claim 62, wherein the semipermeable membrane allows passage of alcohol vapor, but does not allow passage of liquid alcohol.

65. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the outer layer comprises a semipermeable membrane that allows passage of the evaporative cooling liquid in vapor form, but does not allow passage of the evaporative cooling liquid in liquid form.

66. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the middle layer contains particles of the superabsorbent material placed into internal spaces within the middle layer.

67. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the middle layer contains particles of the superabsorbent material within a foam matrix.

68. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the middle layer contains particles of the superabsorbent material within a fibrous matrix.

69. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the middle layer comprises a fibrous matrix.

70. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the multilayer composite material is fashioned into a garment.

71. The multilayer composite material of claim 70, wherein the multilayer composite material is fashioned into a hat.

72. The multilayer composite material of claim 70, wherein the multilayer composite material is fashioned into a glove or mitten.

73. The multilayer composite material of claim 70, wherein the multilayer composite material is fashioned into a sock or boot liner.

74. A multilayer composite material for evaporative cooling of a person comprising:

a middle layer including a superabsorbent material for absorption of an evaporative cooling liquid,

an inner layer of barrier material between the middle layer and the person'"'"'s skin, and

an outer layer allowing evaporation of the evaporative cooling liquid from the superabsorbent material through the outer layer,

wherein the multilayer composite material is fashioned into a blanket.