UV radiation system having materials for selectively attenuating radiation

• US 6,465,799 B1
• Filed: 02/29/2000
• Issued: 10/15/2002
• Est. Priority Date: 03/01/1999
• Status: Expired due to Term

• Current Assignee: Johnson & Johnson Vision Care Incorporated (Johnson & Johnson)
• Original Assignee: Johnson & Johnson Vision Care Incorporated (Johnson & Johnson)
• Inventors: Enns, John B., Ebel, James A., Kimble, Allan W.
• Primary Examiner(s): BERMAN, JACK I
• Application Number:
  US09/515,190
• Time in Patent Office: 959 Days
• Field of Search: 250/504.R, 250/504.H, 250/455.11, 422/24, 252/582, 252/588, 252/589, 501/64, 359/358, 359/361
• US Class Current: 250/504.00R
• CPC Class Codes: A61L 12/063 Ultraviolet radiation
• CPC Class Codes: A61L 2/10 Ultraviolet radiation
• CPC Class Codes: B65B 25/008 packaging of contact lenses
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation

Abstract

This invention provides a high energy radiation system which produces UV radiation comprising a selectively attenuating material which increases the ratio of desired to undesired radiation to reduce the radiation damage to a target by selectively attenuating at least 30 percent of the radiation from greater than 200 up to 240 nm which impinges upon said attenuating material, and directs greater than 50 percent of the radiation from 240 nm to 280 nm which impinges upon said attenuating material.

Claims

1. A high energy radiation system comprising a UV radiation source, wherein said apparatus comprises a selectively attenuating material which increases the ratio of desired to undesired radiation to reduce the radiation damage to a target by selectively attenuating at least 30 percent of the radiation from greater than 200 nm up to 240 nm which impinges upon said attenuating material, and directs greater than 50 percent of the radiation from 240 nm to 280 nm which impinges upon said attenuating material.

2. The system of claim 1, wherein said selectively attenuated radiation is from 100 nm up to 240 nm.

3. The system of claim 1, wherein said selectively attenuated radiation is from 180 nm up to 240 nm.

4. The system of claim 3, wherein said system selectively attenuates at least 60 percent of the radiation from 180 nm up to 240 nm.

5. The system of claim 3, wherein said system selectively attenuates at least 90 percent of the radiation from 180 nm up to 240 nm.

6. The system of claim 1, wherein said system selectively attenuates greater than 90 percent of the radiation, greater than 200 nm up to 240 nm.

7. The system of claim 1, wherein said system directs greater than 75 percent of the radiation from 240 nm to 280 nm.

8. The system of claim 4, wherein said system directs greater than 75 percent of the radiation from 240 nm to 280 nm.

9. The system of claim 4, wherein said system directs greater than 90 percent of the radiation from 240 nm to 280 nm.

10. The system of claim 2, wherein said system directs greater than 90 percent of the radiation from 240 nm to 280 nm, and wherein said system selectively attenuates at least 90 percent of the radiation from 100 nm up to 240 nm.

11. The system of claim 1, wherein said attenuating material has an attenuation ratio of 1.2.

12. The system of claim 3, wherein said attenuating material has an attenuation ratio of 1.8.

13. The system of claim 1, wherein said attenuating material comprises a gas.

14. The system of claim 1, wherein said attenuating material comprises a liquid.

15. The system of claim 14, wherein said liquid is selected from the group consisting of polyols, halogenated carbon compounds, organic carbonates, silicon compounds, mixtures of said liquids, and a solid attenuating material in a liquid carrier.

16. The system of claim 14, wherein said liquid is selected from the group consisting of alkyl alcohols, propylene glycols having a weight average molecular weight from 200 to 1,000, fluorocarbons, chlorocarbons, chloroform, fully halogenated carbon compounds, freon, fluorinerts, fluorinerts having nitrogen within their compositions, aliphatic carbonates, propylene carbonates, sodium silicate, polysiloxane compounds, polydimethylsiloxanes, hydride-terminated silicone oil, and mixtures of said liquids.

17. The system of claim 14, wherein said liquid comprises chloroform and propylene carbonate.

18. The system of claim 15, wherein the location of said liquid attenuating material is selected from the group consisting of between a lamp envelope and a flow tube, between a flow tube and a protective window, and within a passageway adjacent to a reflector, within a passageway adjacent a protective window, and within a passageway located between a target and said radiation source.

19. The system of claim 1, wherein said attenuating material comprises a solid.

20. The system of claim 19, wherein said solid is selected from the group consisting of alkaline metal compounds, heavy metal oxides, divalent metal oxides, and polyvalent metal oxides, rare earth metal oxides, rare earth metal halides, and metallic combination oxides.

21. The system of claim 19, wherein said solid comprises M_aO_bX_cH_d wherein M is a single metal or a mix of metals, O is oxygen, X is a heteroatom, and H is a halide, a is 1 to 20, b is 0 to 20, c is 0 to 20, and d is 0 to 20, with the proviso that at least b, c or d is at least 1.

22. The system of claim 19, wherein said solid material is more than 99.9% pure.

23. The system of claim 19, wherein said solid material is selected from the group consisting of calcium oxide, hafnium oxide, lanthanum oxide, iron oxide, terbium oxide, praseodymium oxide, barium titanate. magnesium fluoride, magnesium oxide, aluminum oxide, barium oxide, barium titanate, holmium oxide, calcium oxide, lanthanum oxide, germanium oxide, tellurium oxide, europium oxide, erbium oxide, neodymium oxide, samarium oxide, ytterbium oxide, yttrium oxide, and dysprosium oxide.

24. The system of claim 19, wherein said solid material is selected from the group consisting of magnesium oxide, erbium oxide, holmium oxide, samarium oxide, tellurium oxide, lanthanum oxide, yttrium oxide, and ytterbium oxide.

25. The system of claim 19, wherein said solid material is selected from the group consisting of lanthanum oxide, yttrium oxide, and ytterbium oxide.

26. The system of claim 3, wherein said attenuating material is a solid attenuating material incorporated as a dopant into said system in a lamp envelope, protective window, flow tube, reflector, passageway, transparent support, blocking element or removable solid material.

27. The system of claim 3, wherein said attenuating material is a solid attenuating material incorporated as a coating into said system on a lamp envelope, protective window, flow tube, reflector, passageway, transparent support, blocking element or removable solid material.

28. The system of claim 27, wherein said coating can be applied by painting, spraying, plasma coating, dipping, casting, conversion coating, gel coating, etching, chemical vapor depositing, sputtering, or chemical or mechanical bonding.

29. The system of claim 19, wherein said solid attenuating materials comprise materials selected from the group consisting of polyvinyl alcohols, cyanoacrylates, acrylics, silicones.

30. The system of claim 29, wherein said solid attenuating materials comprise materials selected from the group consisting of sodium silicate, low-temperature sintered glasses, alkali oxide silicates, sodium, potassium and lithium silicates, sol gel binder precursors, aluminum tert butoxide, sodium silicate, tetraethylorthosilicate (TEOS), metal isopropoxides, dysprosium ethylhexano-diisopropoxide in isopropanol, dysprosium 2-ethylhexanoate in hexane, dysprosium isopropoxide in toluene-isopropanol, dysprosium 2-methoxyethoxide in 2-methoxyethanol, erbium ethylhexano-diisopropoxide in isopropanol, erbium 2-ethylhexanoate in hexane, erbium isopropoxide in toluene-isopropanol, holmium ethylhexano-diisopropoxide in isopropanol, holmium isopropoxide in toluene-isopropanol, holmium 2-methoxyethoxide in 2-methoxyethanol, lanthanum acetate, lanthanum 2-ethylhexanoate in hexane, lanthanum isopropoxide, lanthanum 2-methoxyethoxide in 2-methoxyethanol, magnesium ethoxide in ethanol, magnesium methoxide in methanol, magnesium 2-methoxyethoxide in 2-methoxyethanol, neodymium ethylhexano-diisopropoxide in isopropanol, neodymium 2-ethylhexanoate in hexane, neodymium isopropoxide in toluene-isopropanol, neodymium 2-methoxyethoxide in 2-methoxyethanol, samarium ethylhexano-monoisopropoxide in toluene isopropanol, samarium 2-ethylhexanoate in hexane, samarium isopropoxide in toluene-isopropanol, samarium 2-methoxyethoxide in 2-methoxyethanol, ytterbium isopropoxide in toluene-isopropanol, ytterbium 2-methoxyethoxide in 2-methoxyethanol, yttrium ethylhexano-diisopropoxide in toluene-isopropanol, and yttrium ethylhexano-monoisopropoxide in toluene-isopropanol.

31. The system of claim 29, wherein said solid attenuating materials comprise materials selected from the group consisting of lanthanum acetate, lanthanum 2-ethylhexanoate in hexane, lanthanum isopropoxide, lanthanum 2-methoxyethoxide in 2-methoxyethanol, ytterbium isopropoxide in toluene-isopropanol, ytterbium 2-methoxyethhoxide in 2-methoxyethanol, ytterbium ethylhexano-diisopropoxide in toluene-isopropanol, and yttrium ethylhexano-monoisopropoxide in toluene-isopropanol.

32. The system of claim 27, wherein the thickness of the attenuating coatings is between from 0.1 to 2500 microns.

33. The system of claim 1, wherein said reflector further comprises a reflective material selected from the group consisting of polished aluminum, barium sulfate, aluminum oxide, magnesium fluoride, and magnesium oxide.

34. The system of claim 1, wherein said reflector comprises barium sulfate and lanthanum oxide.

35. The system of claim 1, wherein the reflector 14 can be machined out of the formed solid which comprises the reflector materials, and attenuating materials.

36. The system of claim 34, wherein said attenuating material is selected from the group consisting of lanthanum oxide, yttrium oxide and ytterbium oxide.

37. The system of claim 1 further comprising a blocking element.

38. The system of claim 37, wherein said blocking element comprises said attenuating material, and has a diffuse reflective surface.

39. The system of claim 1, wherein no direct radiation from said radiation source impinges a target.

40. The system of claim 1 further comprising at least one reflector for said radiation source, wherein said reflector is a diffuse reflector having an elliptical shape.

41. The system of claim 1 further comprising a removable solid material comprising said selectively attenuated material, said solid material being located between the radiation source and the target.

42. The system of claim 41, wherein said removable solid material has the form selected from the group consisting of a film, block, plate, and powder packed into a support.

43. The system of claim 42, wherein said film comprises a polymeric material selected from the group consisting of polyamides and polyolefins.

44. The system of claim 1, wherein said system further comprises a target wherein said target comprises said attenuating materials.

45. The system of claim 44, wherein said target comprises a material selected from the group consisting of nylon, lanthanum oxide, adipic acid, barium adipate, calcium adipate, magnesium adipate, disodium adipate, carboxylic acids, and sol gels precursors.

46. The system of claim 44, wherein said target further comprises a container and a product, wherein said container comprises a material selected from the group consisting of Barium hexafluoroacetylacetonate, Barium (2,2,6,6-tetramethyl-3,5-heptanedionate, Lanthanum acetylacetonate hydrate, Lanthanum (2,2,6,6-tetramethyl-3,5-heptanedionate, Magnesium acetylacetonate dihydrate, Magnesium (2,2,6,6-tetramethyl-3,5-heptanedionate), Ytterbium acetylacetonate, Ytterbium hexafluoroacetylacetonate, Ytterbium (2,2,6,6-tetramethyl-3,5-heptanedionate, Yttrium acetylacetonate, Yttrium hexafluoroacetylacetonate, and Yttrium (2,2,6,6-tetramethyl-3,5-heptanedionate.

47. The system of claim 1, wherein said attenuating material undergoes a change in % reflectivity/nm greater than 2, between from 230 to 250 nm.

48. The system of claim 1, wherein said attenuating material undergoes a change in % reflectivity/nm greater than 3, between from 235 to 245 nm.

49. A high energy radiation system comprising a UV radiation source, wherein said apparatus comprises a selectively attenuating material which increases the ratio of desired to undesired radiation to reduce the radiation damage to a target by selectively attenuating at least 30 percent of the radiation from greater than 200 nm up to 250 nm which impinges upon said attenuating material, and directs greater than 50 percent of the radiation from 250 nm to 280 nm which impinges upon said attenuating material.