NOx reduction sensor coating

• US 6,468,407 B2
• Filed: 12/19/2000
• Issued: 10/22/2002
• Est. Priority Date: 12/19/2000
• Status: Expired due to Fees

• Current Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Original Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Inventors: Clyde, Eric P., Beckmeyer, Richard F., LaBarge, William J., Kikuchi, Paul
• Primary Examiner(s): Warden, Jill
• Assistant Examiner(s): SINES, BRIAN J
• Application Number:
  US09/741,763
• Publication Number:
  US 20020106307A1
• Time in Patent Office: 672 Days
• Field of Search: 422/98, 422/90, 422/88, 422/83, 422/82.07, 422/95, 73/232, 204/421-429, 123/697, 438/49, 436/139, 338/34
• US Class Current: 204/429
• CPC Class Codes: G01N 27/4077 Means for protecting the electrolyte or the electrodes
• CPC Class Codes: G01N 33/5438 Electrodes
• CPC Class Codes: G01N 33/54393 Improving reaction conditions or stability, e.g. by coating or irradiation of surface, by reduction of non-specific binding, by promotion of specific binding
• CPC Class Codes: G01N 33/553 Metal or metal coated
• CPC Class Codes: Y10T 436/177692 Oxides of nitrogen

Abstract

A sensor is disclosed that comprises an electrolyte disposed between and in intimate contact with a sensing electrode and a reference electrode. A protective coating is disposed on the protective layer adjacent to the sensing electrode. The protective coating comprises a mixture of a metal oxide, a zeolite, and an alumina. A method for making the sensor is also disclosed.

Claims

1. A sensor, comprising:

an electrolyte disposed between and in intimate contact with a sensing electrode and a reference electrode; and

a protective layer disposed adjacent to said sensing electrode, wherein said protective layer has a protective coating comprising a mixture of a metal oxide, a zeolite, and alumina.

2. The sensor of claim 1, wherein said protective coating comprises about 1 wt. % to about 28 wt. % metal oxide, about 50 wt. % to about 98 wt. % zeolite, and about 1 wt. % to about 48 wt. % alumina.

3. The sensor of claim 2, wherein said protective coating comprises about 10 wt. % to about 20 wt. % metal oxide, about 50 wt. % to about 75 wt. % zeolite, and about 15 wt. % to about 40 wt. % alumina.

4. The sensor of claim 3, wherein said protective coating comprises about 13 wt. % to about 15 wt. % metal oxide, about 51 wt. % to about 61 wt. % zeolite, and about 24 wt. % to about 36 wt. % alumina.

5. The sensor of claim 1, wherein said metal oxide comprises calcium oxide, strontium oxide, barium oxide, manganese oxide, tin oxide, copper oxide, cobalt oxide, lead oxide, aluminum oxide, silicon oxide, titanium oxide, zeolites, zirconium oxide, lanthanum oxide, as well as alloys and combinations comprising at least one of the foregoing metal oxides.

6. The sensor of claim 1, wherein said metal oxide is barium oxide.

7. The sensor of claim 1, wherein said zeolite is a Y-type zeolite, whose molecules enclose cations of strontium, barium, or a corresponding synthetic compound, as well as combinations comprising at least one of the foregoing cations.

8. The sensor of claim 1, wherein said protective coating has a thickness of up to about 200 μ

m.

9. The sensor of claim 8, wherein said protective coating has a thickness of about 120 μ

m to about 160 μ

m.

19. The sensor of claim 5, wherein said metal oxide comprises calcium oxide, strontium oxide, barium oxide, manganese oxide, tin oxide, copper oxide, cobalt oxide, lead oxide, silicon oxide, titanium oxide, zeolites, zirconium oxide, lanthanum oxide, as well as alloys and combinations comprising at least one of the foregoing metal oxides.

10. A method for manufacturing a sensor, comprising:

disposing an electrolyte between a sensing electrode and a reference electrode;

disposing a protective layer adjacent to said sensing electrode; and

disposing a protective coating comprising a mixture of a metal oxide, a zeolite, and alumina in physical contact with said protective layer.

11. The method of claim 10, wherein said protective coating comprises about 1 wt. % to about 28 wt. % metal oxide, about 50 wt. % to about 98 wt. % zeolite, and about 1 wt. % to about 48 wt. % alumina.

12. The method of claim 11, wherein said protective coating comprises about 10 wt. % to about 20 wt. % metal oxide, about 50 wt. % to about 75 wt. % zeolite, and about 15 wt. % to about 40 wt. % alumina.

13. The method of claim 12, wherein said protective coating comprises about 13 wt. % to about 15 wt. % metal oxide, about 51 wt. % to about 61 wt. % zeolite, and about 24 wt. % to about 36 wt. % alumina.

14. The method of claim 10, wherein said metal oxide comprises calcium oxide, strontium oxide, barium oxide, manganese oxide, tin oxide, copper oxide, cobalt oxide, lead oxide, aluminum oxide, silicon oxide, titanium oxide, zeolites, zirconium oxide, lanthanum oxide, as well as alloys and combinations comprising at least one of the foregoing metal oxides.

15. The method of claim 10, wherein said metal oxide is barium oxide.

16. The method of claim 10, wherein said zeolite is a Y-type zeolite, whose molecules enclose cations of strontium, barium, or a corresponding synthetic compound, as well as combinations comprising at least one of the foregoing cations.

17. The method of claim 10, wherein said protective coating has a thickness of up to about 200 μ

m.

18. The method of claim 17, wherein said protective coating has a thickness of about 120 μ

m to about 160 μ

m.

20. The method of claim 14, wherein said metal oxide comprises calcium oxide, strontium oxide, barium oxide, manganese oxide, tin oxide, copper oxide, cobalt oxide, lead oxide, silicon oxide, titanium oxide, zeolites, zirconium oxide, lanthanum oxide, as well as alloys and combinations comprising at least one of the foregoing metal oxides.