Water-stabilized organosilane compounds and methods for using the same
First Claim
1. A composition comprising a mixture of:
- a) an organosilane of the formula RnSiX4−
n where n is an integer of from 0 to 3; and
R is, independently, a nonhydrolizable organic group; and
each X is, independently, a hydrolyzable group;
with b) a polyol selected from the group consisting of (i) glucose, sucrose, fructose, mannitol, ascorbic acid and optionally including an anti-oxidant, adenosine, glucuronic acid, glucurone, dextrose, cellulose, partially hydrolyzed cellulose, soluble starch, a starch-acrylic acid graft copolymer, a nucleoside, a nucleotide, an oligonucleotide, or a polynucleotide;
(ii) an aldose, ketose, or aldose or ketose oxidized or reduced in a single step;
(iii) substituted aldose, substituted ketose, or substituted aldose or substituted ketose oxidized or reduced in a single step;
(iv) a polymer of aldose, a polymer of ketose, a polymer of aldose and ketose, or any thereof oxidized or reduced in a single step; and
(v) a substituted polymer of aldose, a substituted polymer of ketose, a substituted polymer of aldose and ketose, or any thereof oxidized or reduced in a single step; and
c) water;
wherein said organosilane amounts to about 20% or less by weight of said composition.
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Abstract
The composition formed by mixing an organosilane, optionally having a nonhydrolizable organic group, but having one or more hydrolyzable groups, with a polyol containing at least two hydroxy groups, wherein at least any two of the hydroxy groups are separated by no more than two intervening atoms. Water-stabilized organosilane compounds. A water stable composition made from the polyol and organosilane or compound and water. A method of treating a substrate by mixing or contacting the substrate with the product, compound, or composition of this invention for a period of time sufficient for treatment of the substrate. A treated substrate having adhered thereto the product, compound, or composition of this invention. A method of dyeing and treating a substrate. A method of antimicrobially treating a food article. A method of antimicrobially coating a fluid container. A method of antimicrobially coating a latex medical article. A method of making a siloxane in the presence of a stabilizer.
144 Citations
6 Claims
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1. A composition comprising a mixture of:
-
a) an organosilane of the formula RnSiX4−
n where n is an integer of from 0 to 3; and
R is, independently, a nonhydrolizable organic group; and
each X is, independently, a hydrolyzable group;
withb) a polyol selected from the group consisting of (i) glucose, sucrose, fructose, mannitol, ascorbic acid and optionally including an anti-oxidant, adenosine, glucuronic acid, glucurone, dextrose, cellulose, partially hydrolyzed cellulose, soluble starch, a starch-acrylic acid graft copolymer, a nucleoside, a nucleotide, an oligonucleotide, or a polynucleotide;
(ii) an aldose, ketose, or aldose or ketose oxidized or reduced in a single step;
(iii) substituted aldose, substituted ketose, or substituted aldose or substituted ketose oxidized or reduced in a single step;
(iv) a polymer of aldose, a polymer of ketose, a polymer of aldose and ketose, or any thereof oxidized or reduced in a single step; and
(v) a substituted polymer of aldose, a substituted polymer of ketose, a substituted polymer of aldose and ketose, or any thereof oxidized or reduced in a single step; and
c) water;
wherein said organosilane amounts to about 20% or less by weight of said composition. - View Dependent Claims (2, 3, 4, 5, 6)
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3. The composition of claim 1, wherein the organosilane is
(CH3O)3Si(CH2)3N+(CH3)2C18H37Cl− - , (CH3O)3Si(CH2)3N+(CH3)2C18H37BR−
,(CH3O)3Si(CH2)3N+(C10H21)2CH3Cl−
, (CH3O)3Si(CH2)3N+(C10H21)2CH3BR−
,(CH3O)3Si(CH2)3N+(CH3)3Cl−
, (CH3)3Si(CH2)3N+(CH3)2C8H17Cl−
,(CH3O)3Si(CH2)3N+(CH3)2C10C21Cl−
, (CH30)3Si(CH2)3N+(CH3)2C12H25Cl−
,(CH3O)3Si(CH2)3N+(CH3)2C14H29Cl−
, (CH3)3Si(CH2)3N+(CH3)2C16H33Cl−
,(CH3O)3Si(CH2)3N+(CH3)2C20H41Cl−
, (CH3)3Si(CH2)3N+(C4H9)3Cl−
,(CH3O)3Si(CH2)3N+(C2H5)3Cl−
, (CH3CH2)3Si(CH2)3N+(CH3)2C18H37Cl−
,(CH3O)3Si(CH2)3NHC(O)(CF2)6CF3, (CH3O)3Si(CH2)3NHC(O)(CF2)8CF3, (CH3O)3Si(CH2)3NHC(O)(CF2)10CF3, (CH3O)3Si(CH2)3NHC(O)(CF2)12CF3, (CH3O)Si(CH2)3NHC(O)(CF2)14CF3, (CH3O)3Si(CH2)3NHC(O)(CF2)16CF3, (CH3O)3Si(CH2)3NHSO2(CF2)7CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CH2)6CH3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CH2)8CH3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CH2)10CH3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CH2)12CH3, CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CH2)14CH3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CH2)16CH3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)(CH2)3NHC(O)(CF2)6CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CF2)8CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CF2)10CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CF2)12CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CF2)14CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHC(O)(CF2)16CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHSO2(CF2)7CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHSO2(CF2)9CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHSO2(CF2)11CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHSO2(CF2)13CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHSO2(CF2)15CF3, (CH3O)3Si(CH2)3N+(CH3)2(CH2)3NHSO2(CF2)16CF3, (CH3O)3Si(CH2)3NHC6H4COOH, (CH3O)3Si(CH2)3NHC6H4COOCH3, (CH3O)3Si(CH2)3NHC6H4COOC2H5, (CH3O)3Si(CH2)3NHC6H4COOC3H7, (CH3O)3Si(CH2)3NHC6H4COOC4H9, (CH3O)3Si(CH2)3NHC6H4COOCH2C6H5, (CH3O)3Si(CH2)3NHC6H4COOCH2C6H4NH2, (CH3O)3Si(CH2)3NHC6H4COOCH2C6H4N(CH3)2, (CH3O)3Si(CH2)3NHC6H4COOCH2C6H4N(CH2CH3)2, (CH3O)3Si(CH2)3NHC6H4COOCH2C6H4N(CH3)3Y−
,(CH3O)3Si(CH2)3NHC6H4COOCH2C6H4N+(CH2CH3)3Y−
,(CH3O)3Si(CH2)3NCH3C6H4COOH, (CH3O)3Si(CH2)3NCH3C6H4COOCH3, (CH3O)3Si(CH2)3NCH3C6H4COOC2H5, (CH3O)3Si(CH2)3NCH3C6H4COOC3H7, (CH3O)3Si(CH2)3NCH3C6H4COOC4H9, (CH3O)3Si(CH2)3NCH3C6H4COOCH2C6H5, (CH3O)3Si(CH2)3NCH3C6H4COOCH2C6H4NH2, (CH3O)3Si(CH2)3NCH3C6H4COOCH2C6H4N(CH3)2, (CH3O)3Si(CH2)3NCH3C6H4COOCH2C6H4N(CH2CH3)2, (CH3O)3Si(CH2)3NCH3C6H4COOCH2C6H4N+(CH3)3Y−
,(CH3O)3Si(CH2)3NCH3C6H4COOCH2C6H4N+(CH2CH3)3Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOHY−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH3Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOC2H5Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOC3H7Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOC4H9Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H5Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4NH2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N(CH3)2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N(CH2CH3)2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N+(CH3)3Y−
Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N+(CH2CH3)3Y−
Y−(CH3O)3Si(CH2)3NC2H5C6H4COOH, (CH3O)3Si(CH2)3NC2H5C6H4COOCH3, (CH3O)3Si(CH2)3NC2H5C6H4COOC3H7, (CH3O)3Si(CH2)3NC2H5C6H4COOC4H9, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H5, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4NH2, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N(CH3)2, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N(CH2CH3)2, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N+(CH3)3Y−
,(CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N+(CH2CH3)3Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOHY−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH3Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOC2H5Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOC3H7Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOC4H9Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H5Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H4N2Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H4N(CH3)2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH3Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOC2H5Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOC3H7Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOC4H9Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H5Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4NH2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N(CH3)2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N(CH2CH3)2Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N+(CH3)3Y−
Y−
,(CH3O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N+(CH2CH3)3Y−
Y−(CH3O)3Si(CH2)3NC2H5C6H4COOH, (CH3O)3Si(CH2)3NC2H5C6H4COOCH3, (CH3O)3Si(CH2)3NC2H5C6H4COOC3H7, (CH3O)3Si(CH2)3NC2H5C6H4COOC4H9, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H5, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4NH2, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N(CH3)2, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N(CH2CH3)2, (CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N+(CH3)3Y−
,(CH3O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N+(CH2CH3)3Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOHY−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH3Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOC2H5Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOC3H7Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOC4H9Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H5Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H4N2Y−
,(CH3O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H4N(CH3)2Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOC3H7Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOC4H9Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H5Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4NH2Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N(CH3)2Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N(CH2CH3)2Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N+(CH3)3Y−
Y−
,(CH3CH2O)3Si(CH2)3N+(CH3)2C6H4COOCH2C6H4N+(CH2CH3)3Y−
Y−
,(CH3CH2O)3Si(CH2)3NC2H5C6H4COOH, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH3, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOC2H5, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOC3H7, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOC4H9, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH2C6H5, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH2C6H4NH2, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N(CH3)2, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N(CH2CH3)2, (CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N+(CH3)3Y−
,(CH3CH2O)3Si(CH2)3NC2H5C6H4COOCH2C6H4N+(CH2CH3)3Y−
,(CH3CH2O)3Si(CH2)3N+(C2H4)2C6H4COOHY−
,(CH3CH2O)3Si(CH2)3N+(C2H)2C6H4COOCH3Y−
,(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4COOC2H5Y−
,(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4COOC3H7Y−
,CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4COOC4H9Y−
,(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H5Y−
,(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H4NH2Y−
,(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4COOCH2C6H4N(CH3)2Y−
,(CH3CH2O)3Si(CH2)3N+(C2H2C6H4COOCH2C6H4N(CH2CH2Y−
,(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4N+(CH3)3Y−
Y−
, or(CH3CH2O)3Si(CH2)3N+(C2H5)2C6H4N+CH2CH3Y−
Y−
.
- , (CH3O)3Si(CH2)3N+(CH3)2C18H37BR−
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4. The composition of claim 1 formed from mixing an organosilane of the formula II, III, IV, or V:
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5. The composition of claim 1, wherein the organosilane is 3-(trimethoxysilyl) propyldimethyloctadecyl ammonium chloride, 3-(trimethoxysily)propylmethyldi(decyl)ammonium chloride, 3-chloropropyl trimethoxysilane, 3-chloropropyltrimethoxysilane, octadecyltrimethoxysilane, or perfluorooctyltriethoxysilane.
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6. A method of treating a substrate, comprising contacting the substrate with a sufficient amount of the composition of claim 1 for a period of time sufficient for treatment of the substrate.
Specification