Photo-assisted electrolysis apparatus

• US 6,471,834 B2
• Filed: 01/31/2001
• Issued: 10/29/2002
• Est. Priority Date: 01/31/2000
• Status: Expired due to Fees

• Current Assignee: Arthur N. Roe, Roe A. Nicholas
• Original Assignee: Arthur N. Roe, Roe A. Nicholas
• Inventors: Roe, A. Nicholas, Roe, Arthur N.
• Primary Examiner(s): Valentine, Donald R.
• Application Number:
  US09/773,306
• Publication Number:
  US 20020060161A1
• Time in Patent Office: 636 Days
• Field of Search: 204/242, 204/290.01
• US Class Current: 204/242
• CPC Class Codes: C25B 1/55 Photoelectrolysis
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

An apparatus and method for performing electrolysis on materials such as water, thereby electrically separating the electrolyte into its elemental components. More specifically, according to a preferred aspect of the instant invention, there is provided an apparatus for splitting water into hydrogen and oxygen that uses a specially prepared cathode in conjunction with incident light energy to increase the efficiency of that process. A preferred embodiment of this apparatus uses the photo collector/cathode which comprises a thin layer of metal, preferably nickel, deposited by electroplating or a similar technique onto a conductive surface (e.g., a sheet of copper metal). During the electrolysis process, the cathode is irradiated with light, thereby reducing the amount of electrical energy necessary to separate a given quantity of electrolytic material.

Claims

1. An apparatus for photoelectrolysis comprising:

a container;

a cathode positioned in said container; and

an anode positioned in said container,

said container being operable to allow transmission of light to said cathode from a light source external to said container,

said cathode comprising a sheet of conductive metal blacked with a layer of conductive metal disposed on one side of said sheet of conductive metal in a manner such that said layer of conductive metal is operable for both absorbing said light and for acting as a cathodic surface for electrolysis, and

said anode being an array of rods positioned adjacent said layer of conductive metal.

2. An apparatus for photoelectrolysis comprising:

a container;

a cathode positioned in said container; and

an anode positioned in said container;

said container being operable to allow transmission of light to said cathode from a light source external to said container,

said cathode comprising a sheet of conductive metal blacked with a layer of conductive metal in a manner such that said layer of conductive metal is operable for both absorbing said light and for acting as a cathodic surface for electrolysis, and

said sheet of conductive metal being formed in a shape of a partial cylinder having an inside surface and wherein said inside surface has been blacked with said layer of conductive metal.

3. The apparatus of claim 2 wherein said anode is an elongate member positioned adjacent said inside surface such that all points of said inside surface are substantially equidistant from said anode.

4. An apparatus for photo-assisted electrolysis comprising:

a cathode effective both for collecting light energy to assist said electrolysis and for acting as an electrode for said electrolysis;

an anode; and

an external electrical power source electrically connected to said cathode and to said anode such that said external electrical power source is effective for establishing an electrical potential between said cathode and said anode.

5. The apparatus of claim 4 wherein said external electrical power source is effective for establishing a sufficient electrical potential between said cathode and said anode such that light energy in the visible spectrum collected by said cathode will assist said electrolysis.

6. The apparatus of claim 4 wherein said cathode includes no semiconductor materials.

7. The apparatus of claim 4 wherein said anode includes no semiconductor materials.

8. The apparatus of claim 4 wherein said cathode comprises a base of conductive metal blacked with a layer of conductive metal in manner such that said layer of conductive metal is effective for both absorbing light and acting as a cathode surface for said electrolysis.

9. The apparatus of claim 8 wherein said base has been blacked by electroplating a surface of said base to form said layer of conductive metal thereon.

10. The apparatus of claim 8 wherein said cathode consists essentially of only said base and said layer of conductive metal and wherein said base and said layer of conductive metal include no semiconductor materials.

11. The apparatus of claim 8 wherein said base consists essentially of a metal, in elemental form, selected from the group consisting of:

copper, nickel, tin, silver, gold, platinum, palladium, graphite, graphite carbon, iron, chromium, manganese, titanium, and alloys thereof.

12. The apparatus of claim 11 wherein said base is formed of copper.

13. The apparatus of claim 8 wherein said layer of conductive metal consists essentially of a metal, in elemental form, selected from the group consisting of nickel, platinum, palladium, and cobalt.

14. The apparatus of claim 13 wherein said layer of conductive metal is formed of nickel.

15. The apparatus of claim 8 further comprising a container wherein said cathode and said anode are positioned, said container being effective for allowing transmission of light therethrough to said cathode from a light source external to said container.

16. The apparatus of claim 15 further comprising an acidic electrolyte in said container, said cathode and said anode being positioned in said acidic electrolyte.