Desalination and concomitant carbon dioxide capture yielding liquid carbon dioxide

• US 6,475,460 B1
• Filed: 02/09/2000
• Issued: 11/05/2002
• Est. Priority Date: 07/12/1999
• Status: Expired due to Fees

• Current Assignee: Water Generating Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael David
• Primary Examiner(s): Hendrickson, Stuart L.
• Application Number:
  US09/500,422
• Time in Patent Office: 1,000 Days
• Field of Search: 423/220, 423/437.1, 210/750, 210/711, 621/21, 629/28, 625/32, 625/33
• US Class Current: 423/437.1
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/26 by extraction
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 1/38 by centrifugal separation
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2103/18 from the purification of gaseous effluents
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 62/928 Recovery of carbon dioxide

Abstract

Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Saline (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas or liquid to form either positively buoyant (also assisted buoyancy) or negatively buoyant hydrate. The hydrate rises or sinks or is carried into a lower pressure area and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths, and input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth. The fresh water produced by the system is cold enough that it can be used to provide refrigeration, air conditioning, or other cooling; heat removed from the system with the heated residual water can be used for heating or other applications. In other embodiments, desalination or other purification is carried out in “artificially” or mechanically pressurized vessels, which embodiments may be comparatively mobile. Such pressurized systems can be used to capture carbon dioxide from industrial waste gases and to provide liquid carbon dioxide.

Claims

1. A method of 1) capturing carbon dioxide from exhaust gas containing carbon dioxide and produced by an exhaust gas-producing plant and 2) producing purified water generally concurrently therewith, said method comprising:

providing said exhaust gas directly from said exhaust gas-producing plant to a water purification installation;

at said water purification installation, mixing said exhaust gas, or an exhaust gas remainder produced at said water purification installation by washing said exhaust gas to remove non-carbon dioxide components therefrom, with saline or otherwise polluted water under pressure and temperature conditions conducive to the formation of carbon dioxide hydrate such that carbon dioxide hydrate is formed from carbon dioxide contained within said exhaust gas and water molecules contained within said saline or otherwise polluted water;

causing or allowing said carbon dioxide hydrate to be subjected to conditions under which it dissociates and allowing said carbon dioxide hydrate to dissociate into said carbon dioxide and said water molecules;

collecting carbon dioxide released upon dissociation of said carbon dioxide hydrate; and

collecting fresh water released upon dissociation of said carbon dioxide hydrate;

whereby carbon dioxide from said exhaust gas-producing plant is captured or sequestered to prevent its release into the atmosphere and purified water is produced generally concurrently with said capture or sequestration.

2. The method of claim 1, further comprising pretreating the exhaust gas at said water purification installation using one or more means selected from the group consisting of filters, absorbents, electrostatic means, chemical sorption techniques, and catalysis to remove non-carbon dioxide components from said exhaust gas.

3. The method of claim 1, further comprising cooling said exhaust gas at said water purification installation.

4. The method of claim 3, further comprising transferring heat removed from said exhaust gas by said cooling to said carbon dioxide hydrate to facilitate dissociation thereof.

5. The method of claim 1, further comprising transferring heat from said exhaust gas to said carbon dioxide hydrate to facilitate dissociation thereof.

6. The method of claim 1, wherein, during said washing to produce said exhaust gas remainder, hydrate of a component of said exhaust gas other than said carbon dioxide is formed.

7. The method of claim 1, wherein said carbon dioxide hydrate is allowed to dissociate while pressure and temperature conditions are controlled such that said carbon dioxide hydrate dissociates along a P-T pathway that causes said carbon dioxide hydrate to release said carbon dioxide directly or essentially directly as liquid carbon dioxide.

8. The method of claim 1, further comprising delivering said fresh water to a person or animal for drinking.

9. A method of producing liquid carbon dioxide, said method comprising:

forming carbon dioxide hydrate from gaseous carbon dioxide and water under pressure and temperature conditions conducive to the formation of said carbon dioxide hydrate;

causing said carbon dioxide hydrate to be subjected to conditions under which it dissociates and causing said carbon dioxide hydrate to dissociate directly or essentially directly into liquid carbon di oxide and water by controlling pressure and temperature conditions such that when said carbon dioxide hydrate dissociates, said carbon dioxide hydrate dissociates along a P-T pathway that causes said carbon dioxide hydrate to release said carbon dioxide directly or essentially directly as liquid carbon dioxide.

10. The method of claim 9, wherein said gaseous carbon dioxide comprises a component of exhaust gas and said carbon dioxide hydrate is formed by mixing said exhaust gas, or an exhaust gas remainder produced by washing said exhaust gas to remove non-carbon dioxide components therefrom, with said water.

11. The method of claim 10, further comprising pretreating the exhaust gas using one or more means selected from the group consisting of filters, absorbents, electrostatic means, chemical sorption techniques, and catalysis to remove non-carbon dioxide components from said exhaust gas.

12. The method of claim 10, further comprising cooling said exhaust gas.

13. The method of claim 12, further comprising transferring heat removed from said exhaust gas by said cooling to said carbon dioxide hydrate to facilitate dissociation thereof.

14. The method of claim 10, further comprising transferring heat from said exhaust gas to said carbon dioxide hydrate to facilitate dissociation thereof.

15. The method of claim 9, further comprising delivering water released by said dissociation to a person or animal for drinking.

16. The method of claim 10, wherein, during said washing to produce said exhaust gas remainder, hydrate of a component of said exhaust gas other than said carbon dioxide is formed.