Methods and apparatus for downhole fluids analysis

• US 6,476,384 B1
• Filed: 10/10/2000
• Issued: 11/05/2002
• Est. Priority Date: 10/10/2000
• Status: Expired due to Term

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Mullins, Oliver C., Terabayashi, Toru, Okuda, Ikko, Kegasawa, Kazuyoshi
• Primary Examiner(s): Hannaher, Constantine
• Application Number:
  US09/686,646
• Time in Patent Office: 756 Days
• Field of Search: 250/269.1, 250/265, 250/262, 250/261
• US Class Current: 250/269.1
• CPC Class Codes: E21B 49/10 using side-wall fluid samplers or testers
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: G01N 33/241 for hydrocarbon content drilling mud G01N33/2823; drilling per se E21B; prospecting G01V
• CPC Class Codes: G01N 33/2823 raw oil, drilling fluid or polyphasic mixtures hydrocarbon content of earth materials G01N33/241; prospecting G01V; drilling per se E21B

Abstract

A method of determining GOR comprising subjecting a fluid to spectroscopic analysis at a first wavelength sensitive to gas and a second wavelength sensitive to oil, determining a response matrix for the contribution of gas at the first and second wavelengths and the contribution of oil at the first and second wavelengths, determining a signal response vector and the two wavelengths, calculating a mass fraction vector from the response matrix and the signal response vector and using the mass fraction vector to determine GOR.

Claims

1. A method of determining gas-oil ratio of a formation fluid comprising:

a) subjecting the fluid to spectroscopic analysis at at least two wavelengths, one of which is sensitive to the presence of gas and the other of which is sensitive to the presence of oil and generating response data;

b) determining a response matrix {circumflex over (B)} from the response of gas at the two wavelengths and the response of oil at the two wavelengths;

c) determining a signal response vector {right arrow over (S)} at the two wavelengths;

d) calculating a mass fraction vector {right arrow over (m)} of a gas-oil mixture according to the relationship {right arrow over (S)}={circumflex over (B)}{right arrow over (m)}; and

e) determining the gas-oil ratio from the mass fraction vector.

7. A method as claimed in claim 1, wherein the gas-oil ratio is determined according to the relationship GOR=c1(m1/(m2−

c2m1)), wherein c1 and c2 are constants, m1 is the mass fraction of gas and m2 is the mass fraction of oil.

8. A method as claimed in claim 1, wherein one of the wavelengths is approximately 1671 nm and the other is approximately 1725 nm.

9. A method as claimed in claim 1, wherein the spectroscopic analysis is performed in a predetermined spectroscopy apparatus, the method comprising determining a response matrix {circumflex over (B)} for that predetermined spectroscopy apparatus.

10. A method as claimed in claim 1, wherein the spectroscopic analysis of the fluid is performed in a tool located in a borehole and in communication with a formation from which the fluid is obtained.

2. A method as claimed in claim l,wherein the response matrix {circumflex over (B)} comprises a first column comprising the spectroscopic response of gas at each of the two wavelengths, and a second column comprising the spectroscopic response of oil at each of the two wavelengths.

3. A method as claimed in claim 2, further comprising solving the equation {right arrow over (S)}={circumflex over (B)}{right arrow over (m)} to derive mass fractions of gas m1 and oil m2 according to m1=D₁/D and m2=D₂/D;

wherein D is the determinant of {circumflex over (B)}, D₁ is the determinant obtained from the response matrix with the first column replaced by {right arrow over (S)}, and D₂ is the determinant of the response matrix with the second column replaced by {right arrow over (S)}.

4. A method as claimed in claim 2, wherein the response matrix is derived from a series of measurements made on synthetic mixtures of gas and a hydrocarbon.

5. A method as claimed in claim 4, wherein a correction factor is applied to the response matrix so derived when applying it to measurements from real formation fluids.

6. A method as claimed in claim 2, wherein the elements of the matrix comprise the slopes of the integrated and average spectrometer OD values obtained over specified wavelength windows for gas and oil.

11. Apparatus for determining gas-oil ratio of a fluid obtained from a formation surrounding a borehole comprising:

a) a tool body which can be located in the borehole and establish fluid communication with the formation so as to withdraw a sample of fluid therefrom;

b) a spectroscopy module located in the tool body for subjecting the fluid sample to spectroscopic analysis at at least two wavelengths, one of which is sensitive to the presence of gas and the other of which is sensitive to the presence of oil and generating response data;

c) means for determining the gas-oil ratio of the sample which calculates a mass fraction vector {right arrow over (m)} of a gas-oil mixture according to the relationship {right arrow over (S)}={circumflex over (B)}{right arrow over (m)}, wherein {right arrow over (S)} is a signal response vector at the two wavelengths, {circumflex over (B)} is a response matrix formed from the response of gas at the two wavelengths and the response of oil at the two wavelengths; and

determines the gas-oil ratio from the mass fraction vector {right arrow over (m)}.

12. Apparatus as claimed in claim 11, wherein the spectroscopy module includes a broadband light source for illuminating the fluid sample and detectors which include bandpass filters with pass bands including one or other of the two wavelengths.

13. Apparatus as claimed in claim 12, wherein the pass band including the wavelength responsive to gas includes 1671 nm, and the pass band including the wavelength responsive to oil includes 1725 nm.

14. Apparatus as claimed in claim 13, wherein the pass band including 1671 nm wavelength is defined by a filter having a pass band of about 1660 nm to about 1675 nm.

15. Apparatus as claimed in claim 13, wherein the pass band including 1671 nm wavelength is defined by a filter having pass band of about 1640 nm to about 1675 nm.

16. Apparatus as claimed in claim 13, wherein the pass band including 1671 nm wavelength also includes 1650 nm.

17. Apparatus as claimed in claim 13, wherein the pass band including 1725 nm wavelength is defined by a filter having a pass band of about 1715 nm to about 1730 nm.

18. A method of analysing fluids from an underground formation using a spectrometer having a light source, a measurement cell and a detector, the method comprising:

a) determining a temperature dependency curve for source data made from measurements made by the detector of light passing directly from the source;

b) determining a temperature dependency curve for measure data made from measurements made by the detector of light passing through the measurement cell;

c) measuring the response of the detector to light passing through the measurement cell when filled with fluid; and

d) analysing the fluid based on the measured response and the determined temperature dependency curves.

19. A method as claimed in claim 18, wherein the step of analysing the fluid comprises determining the optical density (OD) of the fluid according to the relationship:

20. Apparatus for analysing fluids from a formation surrounding a borehole, comprising:

a) a tool body for location in the borehole;

b) means for establishing fluid communication with the formation;

c) a flow line in the tool body for flowing fluid samples from the formation; and

d) first and second optical analysis modules in the tool body and connected by a flow line, each module capable of making optical measurements on the fluids in the flow line.

21. Apparatus as claimed in claim 20, wherein the optical analysis modules are spectroscopic analysis modules which can make measurements sensitive to the presence of gas in the formation fluid.

22. A method of analyzing fluids from an underground formation using a spectrometer having a light source, a flow line including a measurement cell and a detector, the method comprising:

a) making spectroscopic measurements of fluid in the measurement cell at a wavelength responsive to the presence of alkanes; and

b) using the measurements to indicate the presence of gas in the flow line.

23. The method as claimed in claim 22 wherein the wavelength responsive to the presence of alkane comprises approximately 1725 nm.