Detection of explosives in soils

• US 6,477,907 B1
• Filed: 06/23/2000
• Issued: 11/12/2002
• Est. Priority Date: 12/03/1998
• Status: Expired due to Term

• Current Assignee: National Technology & Engineering Solutions Of Sandia LLC (Honeywell International Inc.)
• Original Assignee: Sandia Corporation (Martin Marietta Corporation)
• Inventors: Chambers, William B., Rodacy, Philip J., Phelan, James M., Woodfin, Ronald L.
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): FAYYAZ, NASHMIYA SAQIB
• Application Number:
  US09/603,729
• Time in Patent Office: 872 Days
• Field of Search: 738/66, 738/631.1, 738/631.2, 738/632.1, 738/632.3, 738/648.1, 73/310.2, 73/234.1, 436/28
• US Class Current: 73/866
• CPC Class Codes: G01N 1/2214 by sorption
• CPC Class Codes: G01N 1/2294 Sampling soil gases or the like
• CPC Class Codes: G01N 2001/022 sampling for security purposes, e.g. contraband, warfare agents
• CPC Class Codes: G01N 33/24 Earth materials G01N33/42 takes precedence

Abstract

An apparatus and method for detecting explosive-indicating compounds in subsurface soil. The apparatus has a probe with an adsorbent material on some portion of its surface that can be placed into soil beneath the ground surface, where the adsorbent material can adsorb at least one explosive-indicating compound. The apparatus additional has the capability to desorb the explosive-indicating compound through heating or solvent extraction. A diagnostic instrument attached to the probe detects the desorbed explosive-indicating compound. In the method for detecting explosive-indicating compounds in soil, the sampling probe with an adsorbent material on at least some portion of a surface of the sampling probe is inserted into the soil to contact the adsorbent material with the soil. The explosive-indicating compounds are then desorbed and transferred as either a liquid or gas sample to a diagnostic tool for analysis. The resulting gas or liquid sample is analyzed using at least one diagnostic tool selected from the group consisting of an ion-mobility spectrometer, a gas chromatograph, a high performance liquid chromatograph, a capillary electrophoresis chromatograph, a mass spectrometer, a Fourier-transform infrared spectrometer and a Raman spectrometer to detect the presence of explosive-indicating compounds.

Claims

1. A field-portable apparatus for detecting at least one semi-volatile explosive-indicating compound in subsurface soil, comprising,

an inner probe having an adsorbent material contacting at least a portion of the surface of said inner probe, said adsorbent material selected from the group consisting of polyethylene, polystyrene and polystyrene-divinylbenzene, said adsorbent material capable of adsorbing at least one semi-volatile, explosive-indicating compound, said at least one explosive-indicating compound selected from the group consisting of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, hexahydro-1,3,5-trinitro-1,3,5-triazine, 1,3,5-trinitrobenzene, 1,3-dinitrobenzene, methyl-2,4,6-trinitrophenylnitramine, nitrobenzene, 2,4,6-trinitrotoluene, 2,4-dinitrotoluene, 2,6-dinitrotoluene, o-nitrotoluene, m-nitrotoluene, p-nitrotoluene, nitroglycerin, 4-amino-2,6-dinitrotoluene, 2-amino-4,6-dintrotoluene, and pentaerythritol tetranitrate;

an outer sheath enclosing said inner probe, said outer sheath capable of being retracted to expose said inner probe and adsorbent material to subsurface soil when inserted under ground surface;

means for desorbing in situ said at least one semi-volatile, explosive-indicating compound, said desorbing means, said means for desorbing in situ said at least one semi-volatile, explosive-indicating compound selected from a solvent, an inductive electrical circuit, a resistive electrical circuit, radiative energy, and a hot gas; and

diagnostic means for detecting said at least one semi-volatile, explosive-indicating compound.

2. The apparatus of claim 1 wherein the diagnostic means comprises at least one chemical detector selected from the group consisting of a mass detector, an optical-based detector, a charged-mass detector, a thermal conductivity detector, an electron capture detector, and an immunoassasy detector.

3. The apparatus of claim 2 wherein the mass detector is selected from a group consisting of a mass spectrometer, an acoustic wave detector or a quartz crystal microbalance.

4. The apparatus of claim 2 wherein the optical-based detector is selected from a group consisting of a infrared detector, an ultraviolet-visible detector, a refractive index detector, a fluorescence detector, a chemiluminescence detector, and a Raman detector.

5. The apparatus of claim 1 wherein the diagnostic means is selected from a group consisting of an ion-mobility spectrometer, a gas chromatograph, a high performance liquid chromatograph, a capillary electrophoresis chromatograph, a mass spectrometer, a Fourier-transform infrared spectrometer, a Raman spectrometer.

6. The apparatus of claim 1 wherein the inner probe additionally comprises a permeable screen that is placed over the adsorbent material.

7. The apparatus of claim 6 further comprising a means for pumping air from a region between the permeable screen and the adsorbent material to provide a pressure less than atmospheric air pressure.

8. The apparatus of claim 1 further comprising a means for introducing an aqueous solvent to a volume around the adsorbent material.

9. A method for detecting at least one semi-volatile explosive-indicating compound in subsurface soil, comprising,

inserting an apparatus into subsurface soil, said apparatus comprising an inner probe having an adsorbent material contacting at least a portion of the surface of said inner probe, an outer sheath enclosing said inner probe, said outer sheath capable of being retracted to expose said inner probe and adsorbent material to subsurface soil when inserted under ground surface, means for desorbing in situ at least one semi-volatile, explosive-indicating compound attached to said inner probe, said means for desorbing in situ said at least one semi-volatile, explosive-indicating compound selected from a solvent, an inductive electrical circuit, a resistive electrical circuit, radiative energy, and a hot gas, and diagnostic means for detecting said at least one semi-volatile, explosive-indicating compound, said adsorbent material selected from the group consisting of polyethylene, polystyrene and polystyrene-divinylbenzene, said adsorbent material adsorbing at least one semi-volatile, explosive-indicating compound, said at least one explosive-indicating compound selected from the group consisting of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, hexahydro-1,3,5-trinitro-1,3,5-triazine, 1,3,5-trinitrobenzene, 1,3-dinitrobenzene, methyl-2,4,6-trinitrophenylnitramine, nitrobenzene, 2,4,6-trinitrotoluene, 2,4-dinitrotoluene, 2,6-dinitrotoluene, o-nitrotoluene, m-nitrotoluene, p-nitrotoluene, nitroglycerin, 4-amino-2,5-dinitrotoluene, 2-amino-4,6-dintrotoluene, and pentaerythritol tetranitrate;

desorbing in situ said at least one semi-volatile, explosive-indicating compound to produce a sample for analysis,

analyzing said sample to detect the presence of said at least one semi-volatile, explosive-indicating compound.

10. The method of claim 9 further comprising the step of adding an aqueous solvent to the subsurface soil in contact with the adsorbent material.

11. The method of claim 9 wherein analyzing said sample to detect the presence of said at least one explosive-indicating compound is performed using a diagnostic means comprising at least one chemical detector selected from the group consisting of a mass detector, an optical-based detector, a charged-mass detector, a thermal conductivity detector, an electron capture detector, and an immunoassay detector.

12. The method of claim 10 wherein the aqueous solvent is added at a temperature above ambient temperature.

13. The method of claim 9 wherein analyzing said sample to detect the presence of said at least one explosive-indicating compound is performed using at least one diagnostic tool selected from the group consisting of an ion-mobility spectrometer, a gas chromatograph, a high performance liquid chromatograph, a capillary electrophoresis chromatograph, a mass spectrometer, a Fourier-transform infrared spectrometer, a Raman spectrometer.