Lithium secondary battery for use in electric vehicle

• US 6,479,186 B1
• Filed: 09/02/1999
• Issued: 11/12/2002
• Est. Priority Date: 09/14/1998
• Status: Expired due to Term

• Current Assignee: NGK Insulators Limited
• Original Assignee: NGK Insulators Limited
• Inventors: Kitoh, Kenshin, Nemoto, Hiroshi
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): WILLS, MONIQUE M
• Application Number:
  US09/389,767
• Time in Patent Office: 1,167 Days
• Field of Search: 307/66, 320/72, 429/231.95, 429/123, 429/149, 429/224, 429/66, 429/72, 429/178, 429/240
• US Class Current: 429/149
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0587 of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
• CPC Class Codes: H01M 2004/021 Physical characteristics, e.g. porosity, surface area
• CPC Class Codes: H01M 2010/4292 Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode
• CPC Class Codes: H01M 4/505 of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries

Abstract

A lithium secondary battery for use in electric vehicle, includes: a battery case, and an electricity-generating body including a positive electrode, a negative electrode, and a separator, the positive and the negative electrode being wound or laminated via the separator so that the positive electrode and negative electrode are not brought into direct contact with each other. Each single battery has a ratio (X/E) of battery output X (W) and battery energy E (Wh), of 2 to 36 or a product (R×E) of battery internal resistance R (mΩ) and battery energy E (Wh), of 50 to 900 (mΩ·Wh). The lithium secondary battery is used in an electric vehicle as combined batteries formed by connecting a required number of the single batteries in series. The lithium secondary battery is designed so as to have a particular ratio of battery output and battery energy or a particular product of battery internal resistance and battery energy and thereby is capable of exhibiting performances necessary for electric vehicle, such as acceleration and the like when used as combined batteries obtained by connecting a required number of single batteries in series.

Claims

1. A lithium secondary battery series for use in an electric vehicle, said battery series comprising:

a plurality of lithium secondary batteries connected in series, each lithium secondary battery comprising;

a battery case, and

an electricity-generating body including a positive electrode having a plurality of current collecting portions, a negative electrode having a plurality of current collecting portions, a separator and a non-aqueous organic electrolyte, the positive and the negative electrode being wound or laminated via the separator so that the positive electrode and negative electrode are not brought into direct contact with each other,

 

wherein each lithium secondary battery has a ratio (X/E) of battery output X (W) and battery energy E (Wh), of 2 to 36,

said lithium secondary battery series having an output of 20 kW or more and weighing 100 kg or less.

3. A lithium secondary battery according to claim 1, wherein the combined batteries have an output of 50 kW or more.

5. A lithium secondary battery according to claim 1, wherein the combined batteries have a weight of 50 kg or less.

7. A lithium secondary battery according to claim 1, wherein the positive electrode comprises, as the active material, lithium manganese oxide (LiMn₂O₄) having a spinel structure.

9. A lithium secondary battery according to claim 1, wherein the positive electrode comprises, as the active material, Li-rich lithium manganese oxide having a spinel structure.

11. A lithium secondary battery according to claim 1, wherein the negative electrode comprises amorphous carbon material or carbon powder.

2. A lithium secondary battery series for use in an electric vehicle, said battery series comprising:

a plurality of lithium secondary batteries connected in series, each lithium secondary battery comprising;

a battery case, and

an electricity-generating body including a positive electrode having a plurality of current collecting portions, a negative electrode having a plurality of current collecting portions, a separator and a non-aqueous organic electrolyte, the positive and the negative electrode being wound or laminated via the separator so that the positive electrode and negative electrode are not brought into direct contact with each other,

 

wherein each lithium secondary battery has a product (R×

E) of battery internal resistance R (mΩ

) and battery energy E (Wh), of 50 to 900 (mΩ

·

Wh),

said lithium secondary battery series having an output of 20 kW or more and weighing 100 kg or less.

4. A lithium secondary battery according to claim 2, wherein the combined batteries have an output of 50 kW or more.

6. A lithium secondary battery according to claim 2, wherein the combined batteries have a weight of 50 kg or less.

8. A lithium secondary battery according to claim 2, wherein the positive electrode comprises, as the active material, lithium manganese oxide (LiMn₂O₄) having a spinel structure.

10. A lithium secondary battery according to claim 2, wherein the positive electrode comprises the active material, Li-rich lithium manganese oxide having a spinel structure.

12. A lithium secondary battery according to claim 2, wherein the negative electrode comprises amorphous carbon material or carbon powder.

13. An electric vehicle comprising a lithium secondary battery series, said battery series comprising:

a plurality of lithium secondary batteries connected in series, each lithium secondary battery comprising;

a battery case, and

an electricity-generating body including a positive electrode having a plurality of current collecting portions, a negative electrode having a plurality of current collecting portions, a separator and a non-aqueous organic electrolyte, the positive and the negative electrode being wound or laminated via the separator so that the positive electrode and negative electrode are not brought into direct contact with each other,

 

wherein each lithium secondary battery has a ratio (X/E) of battery output X (W) and battery energy E (Wh), of 2 to 36,

said lithium secondary battery series having an output of 20 kW or more and weighing 100 kg or less.

14. An electric vehicle comprising a lithium secondary battery series, said battery series comprising:

a plurality of lithium secondary batteries connected in series, each lithium secondary battery comprising;

a battery case, and

an electricity-generating body including a positive electrode having a plurality of current collecting portions, a negative electrode having a plurality of current collecting portions, a separator and a non-aqueous organic electrolyte, the positive and the negative electrode being wound or laminated via the separator so that the positive electrode and negative electrode are not brought into direct contact with each other,

 

wherein each lithium secondary battery has a product (R×

E) of battery internal resistance R (mΩ

) and battery energy E (Wh), of 50 to 900 (mΩ

·

Wh),

said lithium secondary battery series having an output of 20 kW or more and weighing 100 kg or less.