Metal hydrazine complexes for use as gas generants

• US 6,481,746 B1
• Filed: 11/07/1996
• Issued: 11/19/2002
• Est. Priority Date: 01/19/1994
• Status: Expired due to Term

• Current Assignee: Northrop Grumman Innovation Systems, Inc. (Northrop Grumman Corporation)
• Original Assignee: Alliant Techsystems Incorporated (Northrop Grumman Corporation)
• Inventors: Hinshaw, Jerald C., Doll, Daniel W., Lund, Gary K., Blau, Reed J.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/746,224
• Time in Patent Office: 2,203 Days
• Field of Search: 149/36, 149/37, 149/41, 149/42, 149/43, 149/45, 149/19.1, 149/35, 280/741
• US Class Current: 280/741
• CPC Class Codes: C06B 29/00 Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
• CPC Class Codes: C06B 31/00 Compositions containing an inorganic nitrogen-oxygen salt
• CPC Class Codes: C06B 41/00 Compositions containing a nitrated metallo-organic compound
• CPC Class Codes: C06B 43/00 Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.

Claims

1. A solid gas generating composition formulated for generating gas suitable for use in deploying an air bag or balloon from a supplemental safety restraint system, said gas generating composition comprising:

a complex of a metal cation and at least one neutral ligand comprising hydrazine such that when the complex combusts, a mixture of gases containing nitrogen gas and water vapor is produced;

sufficient oxidizing anion to balance the charge of the metal cation,

said, solid gas generating composition containing (a) a co-oxidizer, (b) a secondary fuel, or (c) both a co-oxidizer and a secondary fuel,

wherein the complex consists essentially of at least one metal nitrate hydrazine.

3. A gas generating composition as defined in claim 1, wherein the metal cation is a transition metal, alkaline earth metal, metalloid, or lanthanide metal cation.

4. A gas generating composition as defined in claim 1, wherein the metal cation is a transition metal cation.

5. A gas generating composition as defined in claim 4, wherein the transition metal cation is cobalt.

6. A gas generating composition as defined in claim 1, wherein the oxidizing anion is coordinated with the metal cation.

7. A gas generating composition as defined in claim 1, wherein the inorganic oxidizing anion and the inorganic neutral ligand are free of carbon.

8. A gas generating composition as defined in claim 1, further comprising a binder.

9. A gas generating composition as defined in claim 8, wherein the binder is water soluble.

10. A gas generating composition as defined in claim 9, wherein the binder is selected from naturally occurring gums, polyacrylic acids, and polyacrylamides.

11. A gas generating composition as defined in claim 1, further comprising carbon powder present from 0.1% to 6% by weight of the gas generating composition, wherein the composition exhibits improved crush strength compared to the composition without carbon powder.

12. A gas generating composition as defined in claim 1, further comprising carbon powder present from 0.3% to 3% by weight of the gas generating composition.

2. A solid gas generating composition formulated for generating,gas suitable for use in deploying an air bag or balloon from a supplemental safety restraint system, said gas generating composition comprising:

a complex of a metal cation and at least one neutral ligand comprising hydrazine such that when the complex combusts, a mixture of gases containing nitrogen gas and water vapor is produced;

sufficient oxidizing anion to balance the charge of the metal cation,

said solid gas generating composition containing (a) a co-oxidizer, (b) a secondary fuel, or (c) both a co-oxidizer and a secondary fuel,

wherein the complex in said gas generating composition is a cobalt (III) nitrate hydrazine, and said gas generating composition further comprises 0.1 to 6 weight percent of carbon powder, and a binder in an amount of 0.5 to 12 percent by weight.

13. An inflator assembly for an inflatable safety system comprising:

(a) a gas generator housing having at least one gas outlet;

(b) a pyrotechnic propellant composition disposed inside said gas generator housing, said propellant composition comprising a compound containing hydrazine, wherein said compound containing hydrazine comprises a metal complex of hydrazine; and

(c) a propellant ignition assembly.

14. An inflator assembly for an inflatable safety system according to claim 13, wherein said compound containing hydrazine comprises a cobalt complex of hydrazine.

15. An inflator assembly for an inflatable safety system according to claim 14, wherein said cobalt complex of hydrazine is Co(N₂H₄)₃(NO₃)₂.