Elastomeric compositions and methods for making same

• US 6,494,791 B1
• Filed: 10/04/2000
• Issued: 12/17/2002
• Est. Priority Date: 03/26/1998
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Bissonnette, Laurent C., Pasqua, Samuel A. Jr., Desimas, Antonio U.
• Primary Examiner(s): Wong, Steven
• Assistant Examiner(s): Gorden, Raeann
• Application Number:
  US09/678,018
• Time in Patent Office: 804 Days
• Field of Search: 473/351, 525/193, 525/194, 525/177, 525/222, 525/236
• US Class Current: 473/351
• CPC Class Codes: A63B 2225/30 Maintenance
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0069 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0086 Flexural modulus; Bending stiffness
• CPC Class Codes: B29C 43/18 incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles B29C43/206 takes precedence
• CPC Class Codes: B29D 99/0042 Producing plain balls hollow balls B29D22/04
• CPC Class Codes: B29L 2031/54 Balls
• CPC Class Codes: B29L 2031/546 Golf balls
• CPC Class Codes: C08F 285/00 Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/04 grafted on to rubbers
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes

Abstract

A multi-layer golf ball and methods for preparing a portion thereof including a core having at least one core layer, a mantle having at least one layer including an amount of reinforcing polymer component and a resilient polymer component disposed concentrically adjacent the core, and at least one cover layer disposed concentrically adjacent the mantle, wherein the layer of the mantle is sufficiently rigid to inhibit the resilient polymer component from substantially altering shape prior to crosslinking. The invention also includes an elastomeric composition including a polybutadiene having a high molecular weight average and a predominantly 1,4-cis content, a free-radical initiator, and a reinforcing polymer component having a sufficiently low viscosity at a mixing temperature to permit substantially uniform dispersion of the polymer component with the polybutadiene and having a crystalline melting point sufficiently low to permit mixing while avoiding substantial crosslinking.

Claims

1. An elastomeric composition comprising a blend or reaction product of:

a resilient polymer component of at least one polybutadiene having a high molecular weight average and a 1,4-cis content of greater than about 50 weight percent;

a free-radical initiator; and

about 1 to 19.8 weight percent of a reinforcing polymer component having a sufficiently low viscosity at a mixing temperature to facilitate mixing of the reinforcing polymer component with the resilient polymer component and having a crystalline melting point sufficiently low to facilitate the mixing while avoiding substantial crosslinking, wherein the uncrosslinked mixture has a flexural modulus of greater than about 3.5 MPa.

2. The composition of claim 1, further comprising a crosslinking agent in an amount sufficient to increase crosslinking between the polymer components.

3. An ellipsoidal article comprising the composition of claim 1.

4. The composition of claim 1, wherein the resilient polymer component has a molecular weight from about 50,000 to 1,000,000.

5. The composition of claim 4, wherein the molecular weight average of the resilient polymer component is from about 250,000 to 750,000.

6. The composition of claim 1, wherein the free-radical initiator is an organic peroxide.

7. The composition of claim 1, wherein the reinforcing polymer component comprises a block copolymer ether/ester, an acrylic polyol, a transpolyisoprene, a transpolybutadiene, a 1,2-polybutadiene, an ethylene-vinyl acetate copolymer, a polyethylene or copolymer thereof, or a cyclooctene.

8. The composition of claim 1, further comprising a crosslinking agent which includes a metallic salt selected from the group consisting of an unsaturated fatty acid, a monocarboxylic acid, and mixtures thereof.

9. The composition of claim 1, wherein the reinforcing polymer component is present in an amount of about 5 to 19.8 weight percent.

10. The composition of claim 1, wherein the composition after being at least partially crosslinked has a loss tangent of less than about 0.15 at −

60°

C. and less than about 0.05 at 30°

C. and a tensile storage modulus of greater than about 100 MPa at −

60°

C. and greater than about 50 MPa at 30°

C., each when measured at 1 Hz and one percent strain.

11. The composition of claim 1, wherein the reinforcing polymer component comprises a crystalline melting temperature of about 35°

C. to 120°

C.

12. The composition of claim 1, wherein the uncrosslinked composition has a flexural modulus of greater than about 7 MPa.

13. The composition of claim 1, wherein the melting temperature of the reinforcing polymer component differs from a crosslinking temperature of a mixture of reinforcing polymer component and resilient polymer component by about 60°

C. to 160°

C.

14. The composition of claim 1, wherein the resilient polymer component comprises at least one of polybutadiene, polyisoprene, styrene-butadiene polymer, styrene-propylene-diene rubber, ethylene propylene-diene, or a combination thereof.

15. The composition of claim 1, which further comprises a filler.

16. The composition of claim 15, wherein the filler comprises at least one of zinc oxide, tin oxide, barium sulfate, zinc sulfate, calcium carbonate, barium carbonate, clay, tungsten, tungsten carbide, a silica, cured ground rubber, or a combination thereof, with the filler being present in an amount from about 0.5 to 50 weight percent of the composition.

17. A composition comprising a blend or reaction product of:

a resilient polymer component of at least one of polyisoprene, styrene-butadiene, styrene-propylene-diene rubber (EPDM), and mixtures thereof;

a free-radical initiator; and

a reinforcing polymer component having a sufficiently low viscosity at a mixing temperature to facilitate mixing of the reinforcing polymer component with the resilient polymer component and having a crystalline melting point sufficiently low to facilitate the mixing while avoiding substantial crosslinking, wherein the uncrosslinked composition has a flexural modulus of greater than about 3.5 MPa.

18. The composition of claim 17, wherein the composition after being at least partially crosslinked has a loss tangent of less than about 0.15 at −

60°

C. and less than about 0.05 at 30°

C. and a tensile storage modulus of greater than about 100 MPa at −

60°

C. and greater than about 50 MPa at 30°

C., each when measured at 1 Hz and one percent strain.

19. The composition of claim 17, further comprising a crosslinking agent which includes a metallic salt selected from the group consisting of an unsaturated fatty acid, a monocarboxylic acid, and mixtures thereof.

20. The composition of claim 17, wherein the reinforcing polymer component is present in an amount of about 1 to 40 weight percent of the resilient and reinforcing polymer components.

21. The composition of claim 17, wherein the reinforcing polymer component is present in an amount of about 5 to 25 weight percent of the composition.

22. The composition of claim 17, wherein the reinforcing polymer component comprises a block copolymer ether/ester, an acrylic polyol, a transpolyisoprene, a transpolybutadiene, a 1,2-polybutadiene, an ethylene-vinyl acetate copolymer, a polyethylene or copolymer thereof, or a cyclooctene.

23. A method of preparing an elastomeric composition, comprising the steps of:

providing a resilient polymer component having a 1,4-cis-content greater than about 50 percent;

providing a free radical initiator;

providing a reinforcing polymer component; and

mixing the resilient polymer component, the free radical initiator, and about 1 to about 19.8 weight percent of the reinforcing polymer component to provide an uncrosslinked mixture with a flexural modulus greater than about 3.5 MPa.

24. The method of claim 23, wherein the step of providing the resilient polymer component comprises selecting at least one of polybutadiene, polyisoprene, styrene-butadiene, styrene-butadiene polymer, styrene-propylene-diene rubber, ethylene propylene-diene, or mixtures thereof.

25. The method of claim 23, wherein the step of providing the reinforcing polymer component comprises providing at least one of a transpolyisoprene, transpolybutadiene, a block copolymer ether, a block copolymer ester, an acrylic polyol, a polyethylene, a polyethylene copolymer, 1,2-polybutadiene, an ethylene-vinyl acetate copolymer, a cyclooctene, or combinations thereof.

26. The method of claim 23, wherein the step of providing the reinforcing polymer component comprises providing a polymer having a crystalline melting temperature of about 35°

C. to 120°

C.

27. The method of claim 23, wherein the step of mixing comprises mixing at least about 60 weight percent resilient polymer component by weight of the composition.

28. The method of claim 23, further comprising the steps of:

providing a crosslinking agent;

mixing the crosslinking agent with the resilient polymer component, the free radical initiator, and the reinforcing polymer component.