Polymer electrolyte membrane electrochemical fuel cells and stacks with adhesively bonded layers

• US 6,495,278 B1
• Filed: 03/10/2000
• Issued: 12/17/2002
• Est. Priority Date: 03/29/1997
• Status: Expired due to Term

• Current Assignee: Daimler AG (Mercedes-Benz Group AG)
• Original Assignee: Ballard Power Systems Corporation (Superior Plus Corporation)
• Inventors: Schmid, Ottmar, Einhart, Johann
• Primary Examiner(s): Brouillette, Gabrielle
• Assistant Examiner(s): WILLS, MONIQUE M
• Application Number:
  US09/523,240
• Time in Patent Office: 1,012 Days
• Field of Search: 429/30, 429/34, 429/35, 429/36, 429/38, 429/39, 429/41, 429/44, 429/162, 429/304, 429/207
• US Class Current: 429/465
• CPC Class Codes: C25B 9/23 comprising ion-exchange membranes in or on which electrode material is embedded
• CPC Class Codes: C25B 9/77 having diaphragms
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/0258 characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: H01M 8/0271 Sealing or supporting means around electrodes, matrices or membranes
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: H01M 8/04074 Heat exchange unit structures specially adapted for fuel cell
• CPC Class Codes: H01M 8/2404 Processes or apparatus for grouping fuel cells
• CPC Class Codes: H01M 8/242 comprising framed electrodes or intermediary frame-like gaskets H01M8/2425, H01M8/244 take precedence
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrochemical cell stack comprises a plurality of membrane electrode assemblies interposed between pairs of separator plates. The stack comprises adhesively bonded layers. Preferably each membrane electrode assembly is adhesively bonded to the adjacent pair of separator plates. The adhesive bond between the plate and membrane electrode assembly preferably provides a substantially gas and liquid-tight seal around the perimeter of the electrochemically active area of the membrane electrode assembly and around any fluid manifold openings formed therein. Alternatively, or in addition, adjoining pairs of separator plates in an electrochemical cell stack may be adhesively bonded together. Such pairs of adhesively bonded plates may define cooling spaces between neighboring cells. Stacks comprising a plurality of individual cell modules may be formed, each module comprising a membrane electrode assembly bonded to a pair of separator plates.

Claims

1. An electrochemical cell comprising:

a first separator plate;

a second separator plate;

a membrane electrode assembly interposed between said first and second separator plates, said membrane electrode assembly comprising a polymer electrolyte membrane interposed between first and second electrode layers; and

a substantially gas and liquid impermeable adhesive bond formed between a portion of said membrane, said first and second electrodes, and each of said separator plates, wherein said adhesive bond is formed by an adhesive material, and wherein said membrane electrode assembly, said first and second separator plates, and said adhesive bond form a unitary structural unit.

2. The electrochemical cell of claim 1 wherein fluid flow spaces are formed between the surfaces of each of first and second separator plates and said membrane electrode assembly, and said adhesive bond forms a substantially gas and liquid-tight seal around said fluid flow spaces.

3. The electrochemical cell of claim 2 wherein said fluid flow spaces comprise grooves formed in the surfaces of said separator plates facing said membrane.

4. The electrochemical cell of claim 1 wherein said first and second separator plates and said membrane electrode assembly have a plurality of aligned fluid manifold openings formed therein for the supply and exhaust of fluid streams, and said adhesive bond circumscribes at least one of said manifold openings.

5. The electrochemical cell of claim 1, wherein said membrane protrudes beyond the edges of said electrode layers.

6. The electrochemical cell of claim 1 wherein a surface of at least one of said separator plates facing said membrane electrode assembly comprises a protrusion in an area where said adhesive bond joins said membrane to said separator plate.

7. The electrochemical cell of claim 1, wherein a surface of at least one of said separator plates facing said membrane electrode assembly comprises a groove in an area where said adhesive bond joins said membrane electrode assembly to said separator plate said groove containing adhesive.

8. An electrolyzer or fuel cell stack comprising a plurality of membrane electrode assemblies each interposed between a pair of separator plates, each of one of said membrane electrode assemblies comprising:

a solid polymer electrolyte membrane interposed between said first and second electrodes;

an adhesive bond between a portion of each said membrane, said first and second electrodes and a respective pair of said separator plates, thereby forming an adhesively bonded unitary structural unit,

wherein said stack comprises a plurality of unitary structural units.

9. The electrochemical cell stack of claim 8 wherein adjacent ones of said individual cell modules in said stack are not adhesively bonded together.

10. The electrochemical cell stack of claim 8 wherein adjacent ones of said individual cell modules in said stack are adhesively bonded together and adjoining separator plates of adjacent modules plates define a cooling space therebetween, and said adhesive bond between said adjoining separator plates forms a substantially gas and liquid-tight seal around said cooling space.

11. The electrochemical cell stack of claim 8 wherein said stack comprises bipolar separator plates which are interposed between and adhesively bonded to two membrane electrode assemblies.

12. An electrochemical cell stack comprising a plurality of membrane electrode assemblies each interposed between a pair of substantially fluid impermeable separator plates, said stack comprising adjoining said separator plates which are adhesively bonded together.

13. The electrochemical cell of claim 12 wherein said adjoining separator plates define a cooling space therebetween, and said adhesive bond between said adjoining separator plates forms a substantially gas and liquid-tight seal around said cooling space.

14. The electrochemical cell stack of claim 13 where said cooling space comprises grooves formed in at least one of said adjoining separator plates.

15. The electrochemical cell stack of claim 12 wherein said membrane electrode assemblies and separator plates have a plurality of aligned fluid manifold openings formed therein for the supply and exhaust of fluid streams, and said adhesive bond between said adjoining separator plates circumscribes at least one of said manifold openings.

16. An electrochemical cell stack comprising:

a plurality of electrochemical cells, each cell comprising;

a first separator plate having outer and inner surfaces;

a second separator plate having outer and inner surfaces;

a membrane electrode assembly having a polymer electrolyte membrane interposed between electrodes, the membrane electrode assembly being interposed between the inner surfaces of the first and second separator plates;

wherein, in at least one of the cells in the cell stack, the outer surface of the first separator plate comprises first and second grooves, the first groove being sized to receive a bead of adhesive prior to assembly of the cell stack, the second groove being spaced apart from the first groove, and the outer surface of the first separator plate of the at least one cell abuts the outer surface of the second separator plate of an adjacent electrochemical cell, at least a passage portion of the first separator plate between the first and second grooves being configured to allow adhesive to pass from the first groove to the second groove during assembly of the cell stack.

17. The cell stack of claim 16 wherein at least a portion of the passage portion of the first separator plate is reduced in height to create a gap between the second separator plate of the adjacent electrochemical cell in the cell stack to allow adhesive to pass from the first groove to the second groove during assembly.

18. The cell stack of claim 16 wherein the second groove is substantially parallel with the first groove along at least a portion of the first groove.

19. The cell stack of claim 16 wherein the passage portion comprises an elongated finger separating the second groove from the first groove.

20. The cell stack of claim 16 wherein the passage portion comprises an elongated finger separating the second groove from the first groove and the height of at least a portion of the elongated finger is spaced below a plane of the outer surface of the first separator plate of the at least one cell.

21. A plate for an electrochemical cell, for use in combination with other electrochemical cells, to form a cell stack, the plate comprising:

an outer surface configured to abut the outer surface of another plate when the cell stack is assembled, the outer surface having first and second grooves, the first groove being sized to receive a bead of adhesive prior to assembly of the cell stack, the second groove being spaced apart from the first groove, at least a passage portion of the plate between the first and second grooves being configured to allow adhesive to pass from the first groove to the second groove during assembly of the cell stack.

22. The plate of claim 21 wherein at least a portion of the passage portion of the plate is reduced in height to create a gap between a plate of the adjacent cell in the cell stack to allow adhesive to pass from the first groove to the second groove during assembly.

23. The plate of claim 21 wherein the second groove is substantially parallel with the first groove along at least a portion of the first groove.

24. The plate of claim 21 wherein the passage portion comprises an elongated finger separating the second groove from the first groove.

25. The plate of claim 21 wherein the passage portion comprises an elongated finger separating the second groove from the first groove and the height of at least a portion of the elongated finger is spaced below a plane of the outer surface of the plate.

26. A method for bonding a first separator plate in an electrochemical cell stack to a second separator plate in the cell stack, the method comprising:

providing a first groove in a first mating surface of the first separator plate;

providing a second groove in the first mating surface, the second groove being at least substantially parallel with the first groove along at least a portion of the first groove;

providing an elongated finger separating the second groove from the first groove;

depositing a bead of adhesive in the first groove;

abutting a second mating surface of the second separator plate against the first mating surface of the first separator plate to displace a portion of the bead of adhesive out of the first groove, and

receiving at least some of the displaced portion of the bead of adhesive in the second groove.

27. The method of claim 26 wherein the first separator plate is an element of a first electrochemical cell and the second separator plate is an element of an adjacent second electrochemical cell, and wherein bonding the first separator plate to the second separator plate forms at least a portion of the cell stack.

28. The method of claim 26 further comprising reducing a height of at least a portion of the elongated finger such that a shortened portion of the elongated finger is spaced below a plane of the first mating surface, and wherein at least some of the portion of the bead of adhesive displaced from the first groove passes over the shortened portion of the elongated finger into the second groove during assembly.

29. The method of claim 26 wherein depositing the bead of adhesive comprises screen printing the bead of adhesive into the first groove.

30. The method of claim 26 wherein providing the first groove in the first mating surface of the first separator plate comprises embossing the first mating surface.

31. The method of claim 26 wherein providing the first and second grooves in the first mating surface of the first separator plate comprises embossing the first mating surface.

32. The method of claim 26 wherein providing the first and second grooves in the first mating surface of the first separator plate comprises embossing portions of the first mating surface to a groove depth, and wherein providing an elongated finger comprises embossing the portion of the plate between the first and second grooves to a finger depth different from the groove depth.