Desalination using positively buoyant or negatively buoyant/assisted buoyancy hydrate

• US 6,497,794 B1
• Filed: 09/17/1999
• Issued: 12/24/2002
• Est. Priority Date: 07/12/1999
• Status: Expired due to Fees

• Current Assignee: Water Generating Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael David
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US09/397,500
• Time in Patent Office: 1,194 Days
• Field of Search: 625/32, 625/33, 585/15, 210/712, 210/718, 210/737, 210/749, 210/750, 210/772, 210/774, 210/765, 210/766, 210/747, 203/10, 203/100
• US Class Current: 203/10
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/26 by extraction
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2103/18 from the purification of gaseous effluents
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 203/11 Batch distillation

Abstract

Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Saline (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas or liquid to form either positively buoyant (also assisted buoyancy) or negatively buoyant hydrate. The hydrate rises or sinks or is carried into a lower pressure area and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths, and input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth. The fresh water produced by the system is cold enough that it can be used to provide refrigeration, air conditioning, or other cooling; heat removed from the system with the heated residual water can be used for heating or other applications. In other embodiments, desalination or other purification is carried out in “artificially” or mechanically pressurized vessels, which embodiments may be comparatively mobile.

Claims

1. A method of desalinating or purifying saline or polluted input water, respectively, said method comprising:

providing said input water to a hydrate formation region of a desalination fractionation installation that is located in a shalt formed in land and causing said input water to be mixed with a hydrate-forming substance under pressure conditions and temperature conditions conducive to formation of hydrate such that hydrate spontaneously forms;

providing said hydrate to a hydrate dissociation region of said installation;

removing heat from said desalination fractionation installation by removing residual saline or polluted water that has been warmed by heat of exothermic formation of said hydrate;

allowing said hydrate to dissociate into fresh water and the hydrate-forming substance in a dissociation region of said desalination fractionation installation; and

collecting said fresh water;

said method further comprising at least partially cooling said input water toward said temperature conditions conducive to formation of hydrate before said input water is mixed with said hydrate-forming substance;

wherein said hydrate-forming substance is less dense than said input water and produces hydrate which, per se, is negatively buoyant;

wherein said hydrate-forming substance is mixed with said input water in a manner such that hydrate formation is incomplete and traps pockets of said hydrate-forming substance within a shell or meshwork of said hydrate to produce assisted buoyancy hydrate masses; and

wherein said hydrate is provided to said hydrate dissociation region by virtue of said assisted buoyancy hydrate masses being permitted to rise into said hydrate dissociation region.

2. The method of claim 1, further comprising diverting said assisted buoyancy hydrate masses laterally as they rise into said hydrate dissociation region such that as said assisted buoyancy hydrate masses dissociate, negatively buoyant hydrate which sinks settles within said hydrate dissociation region, thereby substantially minimizing the amount of negatively buoyant hydrate which settles within said hydrate formation region of said desalination fractionation installation.

3. A method of desalinating or purifying saline or polluted input water, respectively, said method comprising:

providing said input water to a hydrate formation region of a desalination fractionation installation that is located in a shaft formed in land and causing said input water to be mixed with a hydrate-forming substance under pressure conditions and temperature conditions conducive to formation of hydrate such that hydrate spontaneously forms;

providing said hydrate to a hydrate dissociation region of said installation;

removing heat from said desalination fractionation installation by removing residual saline or polluted water that has been warmed by heat of exothermic formation of said hydrate;

allowing said hydrate to dissociate into fresh water and the hydrate-forming substance in a dissociation region of said desalination fractionation installation; and

collecting said fresh water;

said method further comprising at least partially cooling said input water toward said temperature conditions conducive to formation of hydrate before said input water is mixed with said hydrate-forming substance;

wherein said hydrate-forming substance comprises a gas or gas mixture that produces hydrate which, per se, is negatively buoyant; and

wherein said gas or gas mixture is mixed with said input water in a manner such that hydrate formation is incomplete and traps pockets of said gas or gas mixture within a shell or meshwork of said hydrate to produce assisted buoyancy hydrate masses.

4. A method of desalinating or purifying saline or polluted input water, respectively, said method comprising:

providing said input water to a hydrate formation region of a desalination fractionation installation that is located in a shaft formed in land and causing said input water to be mixed with a hydrate-forming substance under pressure conditions and temperature conditions conducive to formation of hydrate such that hydrate spontaneously for ms;

providing said hydrate to a hydrate dissociation region of said installation;

removing heat from said desalination fractionation installation by removing residual saline or polluted water that has been warmed by heat of exothermic formation of said hydrate;

allowing said hydrate to dissociate into fresh water and the hydrate-forming substance in a dissociation region of said desalination fractionation installation; and

collecting said fresh water;

wherein said input water is at least partially cooled toward said temperature conditions conducive to formation of hydrate before said input water is mixed with said hydrate-forming substance;

wherein provision of said hydrate to said hydrate dissociation region of said installation is controlled such that said hydrate dissociates while remaining under elevated pressure substantially greater than atmospheric pressure; and

wherein said hydrate-forming substance is captured while said hydrate-forming substance is under said elevated pressure and said hydrate-forming substance is recycled for re-use while being maintained substantially at said elevated pressure.

5. A method of desalinating or purifying saline or polluted input water, respectively, said method comprising:

providing said input water to a hydrate formation region of a desalination fractionation installation and causing said input water to be mixed with a hydrate-forming substance under pressure conditions and temperature conditions conducive to formation of hydrate such that hydrate spontaneously forms;

providing said hydrate to a hydrate dissociation region of said installation;

removing heat from said desalination fractionation installation by removing residual saline or polluted water that has been warmed by heat of exothermic formation of said hydrate;

allowing said hydrate to dissociate into fresh water and the hydrate-forming substance in a dissociation region of said desalination fractionation installation; and

collecting said fresh water;

said method further comprising at least partially cooling said input water toward said temperature conditions conducive to formation of hydrate before said input water is mixed with said hydrate-forming substance;

wherein said hydrate formation region is mechanically pressurized to generate said pressure conditions conducive to formation of hydrate;

wherein said hydrate dissociation region is mechanically pressurized; and

wherein provision of said hydrate to said hydrate dissociation region is controlled by controlling relative pressure within said hydrate formation region and said hydrate dissociation region.