Quantum dot white and colored light emitting diodes

• US 6,501,091 B1
• Filed: 10/07/1998
• Issued: 12/31/2002
• Est. Priority Date: 04/01/1998
• Status: Expired due to Term

• Current Assignee: Lumileds LLC (Apollo Global Management, Inc.)
• Original Assignee: Hewlett-Packard Company (HP Inc.), Massachusetts Institute of Technology
• Inventors: Heine, Jason, Bawendi, Moungi G., Jensen, Klavs F., Moon, Ronald L., Miller, Jeffrey N.
• Primary Examiner(s): Tran, Minh Loan
• Application Number:
  US09/167,795
• Time in Patent Office: 1,546 Days
• Field of Search: 257/79, 257/89, 257/14, 257/98, 257/100
• US Class Current: 257/14
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/565 with zinc cadmium
• CPC Class Codes: C09K 11/883 with zinc or cadmium
• CPC Class Codes: H01L 33/06 within the light emitting region, e.g. quantum confinement structure or tunnel barrier
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H01S 3/169 Nanoparticles, e.g. doped nanoparticles acting as a gain material
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
• CPC Class Codes: Y10S 977/95 Electromagnetic energy

Abstract

An electronic device comprising a population of quantum dots embedded in a host matrix and a primary light source which causes the dots to emit secondary light of a selected color, and a method of making such a device. The size distribution of the quantum dots is chosen to allow light of a particular color to be emitted therefrom. The light emitted from the device may be of either a pure (monochromatic) color, or a mixed (polychromatic) color, and may consist solely of light emitted from the dots themselves, or of a mixture of light emitted from the dots and light emitted from the primary source. The dots desirably are composed of an undoped semiconductor such as CdSe, and may optionally be overcoated to increase photoluminescence.

Claims

1. An electronic device comprising:

a solid-state device which serves as a primary light source; and

a population of photoluminescent quantum dots dispersed in a host matrix, at least a portion of the quantum dots having a band gap energy smaller than the energy of at least a portion of the light produced by the source, and the matrix allowing light from the source to pass therethrough.

2. The device of claim 1, where the quantum dots comprise at least one material selected from the group consisting of CdS, CdSe, CdTe, ZnS, and ZnSe.

3. The device of claim 2, where the quantum dots further comprise an overcoat of at least one material selected from the group consisting of ZnS, ZnSe, CdS, CdSe, CdTe, and MgSe.

4. The device of claim 1, where the host matrix comprises at least one material selected from the group consisting of polymers, silica glasses, and silica gels.

5. The device of claim 1, where the host matrix comprises at least one polymer selected from the group consisting of polystyrene, polyimides, and epoxies.

6. The device of claim 1, where the quantum dots comprise a coating having an affinity for the host matrix.

7. The device of claim 6, where the host matrix comprises a polymer and the coating comprises a related monomer.

8. The device of claim 1, where the primary light source is selected from the group consisting of a light-emitting diode, a solid-state laser, and a solid-state ultraviolet source.

9. The device of claim 1, where the quantum dots have a size distribution having less than a 10% in diameter of the dots.

10. The device of claim 1, wherein the quantum dots comprise an undoped semiconductor material.

11. The device of claim 1, wherein the quantum dots photoluminensce light of a color characteristic of their sizes in response to light from the light source.

12. A quantum dot colloid, comprising a population of quantum dots dispersed in a nonconductive host matrix, each quantum dot having a substantially uniform surface energy, wherein the dots are of a size distribution, composition, or a combination thereof, selected to photoluminesce light of a spectral distribution of wavelengths characteristic of a selected color when the host matrix is irradiated with light from a primary source whose wavelength is shorter than the longest wavelength of said spectral distribution.

13. The colloid of claim 12, where the quantum dots comprise at least one material selected from the group consisting of CdS, CdSe, CdTe, ZnS, and ZnSe.

14. The colloid of claim 13, where the quantum dots further comprise an overcoating of at least one material selected from the group consisting of ZnS, ZnSe, CdS, CdSe, CdTe, and MgSe.

15. The colloid of claim 12, where the host matrix comprises at least one material selected from the group consisting of a polymer, a silica glass, and a silica gel.

16. The colloid of claim 12, where the host matrix comprises a polymer selected from the group consisting of polystyrene, polyimides, and epoxies.

17. The colloid of claim 12, where the quantum dots are coated with a coating material having an affinity for the host matrix.

18. The colloid of claim 17, where the host matrix comprises a polymer and the coating material comprises a related monomer.

19. The colloid of claim 12, where the size distribution is characterized by an rms deviation in diameter of the quantum dots of less than 10%.

20. The quantum dot of claim 12, wherein the spectral distribution is determined by the size distribution of the quantum dots.

21. A method of producing light of a selected color, comprising:

providing at least one population of photoluminescent quantum dots dispersed in a host matrix, each quantum dot having a characteristic band gap energy, and

irradiating the host matrix with a solid-state primary light source, said source emitting light of an energy greater than the characteristic band gap energy of at least a portion of the dots;

whereby the quantum dots photoluminesce light of the selected color when irradiated by the primary light source.

22. The method of claim 21, where the quantum dots comprise at least one material selected from the group consisting of CdS, CdSe, CdTe, ZnS, and ZnSe.

23. The method of claim 22, where the quantum dots further comprise an overcoating of at least one material selected from the group consisting of ZnS, ZnSe, CdS, CdSe, CdTe, and MgSe.

24. The method of claim 21, where providing a population of quantum dots disposed in a host matrix includes,

providing at least one precursor material having quantum dots disposed therein; and

reacting the precursor material to form a solid host matrix having quantum dots dispersed therein.

25. The method of claim 21, where providing a population of quantum dots disposed in a host matrix includes,

providing at least two precursor materials, including a first precursor material having a first population of quantum dots having a first size distribution disposed therein and a second precursor material having a second population of quantum dots having a second size distribution disposed therein;

combining the precursor materials; and

reacting the precursor materials to form a solid host matrix having quantum dots dispersed therein.

26. The method of claim 25, where combining comprises mixing the precursor materials.

27. The method of claim 25, where combining comprises depositing layers of the precursor materials.

28. The method of claim 21, where the host matrix comprises at least one material selected from the group consisting of a polymer, a silica glass, and a silica gel.

29. The method of claim 21, where the host matrix comprises a polymer selected from the group consisting of polystyrene, polyimides, and epoxies.