In situ water and soil remediation method and system

• US 6,502,633 B2
• Filed: 03/26/2001
• Issued: 01/07/2003
• Est. Priority Date: 11/14/1997
• Status: Expired due to Fees

• Current Assignee: James Carey, Kent Cooper, Robert J. Crim
• Original Assignee: James Carey, Kent Cooper, Robert J. Crim
• Inventors: Carey, James, Cooper, Kent, Crim, Robert J.
• Primary Examiner(s): SUCHFIELD, GEORGE A
• Application Number:
  US09/817,803
• Publication Number:
  US 20020036082A1
• Time in Patent Office: 652 Days
• Field of Search: 166/52, 166/177.5, 166/245, 166/271, 166/308, 166/370, 210/170, 210/747, 210/759, 210/908, 210/909, 405/128.25, 405/128.3, 405/128.5, 405/128.75, 405/129.4, 405/263, 588/205, 588/206, 588/900
• US Class Current: 210/747.8
• CPC Class Codes: B01F 2101/305 Treatment of water, waste water or sewage
• CPC Class Codes: B01F 23/23123 consisting of rigid porous or perforated material
• CPC Class Codes: B01F 23/231265 being tubes, tubular elements, cylindrical elements or set of tubes
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: Y10S 210/908 Organic
• CPC Class Codes: Y10S 210/909 Aromatic compound, e.g. pcb, phenol

Abstract

The remediation treatment creates environmentally neutral species from hydrocarbon contaminants. For soils having a low porosity, fissures are created in the site by, for example, fluid, i.e., hydraulic or pneumatic, fracturing. A catalyst is injected into the site and is permitted to diffuse through the site. An oxidizing agent is then introduced into the site to release a free radical in a Fenton-type reaction. The compounds react to release a free radical, which acts upon the contaminants to form environmentally neutral species. Diffusion of both compounds is aided by turbulence induced in the groundwater. A pH-adjusting compound is added to optimize reaction conditions. Reaction vapors are collected above ground, filtered, and vented to the atmosphere, reducing the chance for gas pressure buildup and possibly dangerous, potentially explosive conditions.

Claims

1. A method for remediating a contaminated site comprising the steps of:

increasing a porosity of soil at a site containing ground water, the soil having a hydrocarbon contaminant therein;

introducing a first compound into the site, the site essentially chemically untreated prior to the first compound introduction;

permitting the first compound to diffuse through the site;

introducing a second compound into the site, the second compound comprising an oxidizing agent reactable with the first compound to release a free radical;

permitting the first and the second compounds to react to release a free radical;

introducing a pH-adjusting compound into the site for optimizing the reaction between the first and the second compounds; and

permitting the free radical to act upon a site contaminant to form an environmentally neutral species.

2. The method recited in claim 1, wherein the second compound comprises hydrogen peroxide.

3. The method recited in claim 1, wherein the first compound comprises a metallic salt.

4. The method recited in claim 3, wherein the metallic salt comprises iron sulfate.

5. The method recited in claim 1, wherein the first and the second compounds are reactable via a Fenton-type reaction.

6. The method recited in claim 5, wherein gases generated by the Fenton-type reaction and an oxidation of the contaminant effect a further increase in porosity of the soil.

7. The method recited in claim 1, wherein the soil porosity increasing step comprises creating a plurality of fissures in the soil.

8. The method recited in claim 7, wherein the fissure creating step comprises performing fluid fracturing, the fluid fracturing comprising at least one of hydraulic fracturing and pneumatic fracturing.

9. The method recited in claim 8, wherein the fluid fracturing performing step comprises forcing a fluid into the soil under sufficient pressure to create the fissures.

10. The method recited in claim 7, wherein the fissure-creating step comprises creating substantially horizontal fissures.

11. The method recited in claim 7, further comprising the step, following the fissure-creating step, of injecting into the fissures means for holding the fissures open.

12. The method recited in claim 11, wherein the holding means comprises a proppant.

13. The method recited in claim 12, wherein the proppant comprises a graded sand.

14. The method recited in claim 1, wherein the introduction steps comprise injecting the first and the second compounds at a plurality of locations selected to permit diffusion of the first and the second compounds throughout the site.

15. The method recited in claim 1, wherein the pH-adjusting compound comprises carbon dioxide.

16. A method for remediating a contaminated site comprising the steps of:

increasing a porosity of soil at a site containing ground water, the soil having a hydrocarbon contaminant therein;

introducing a first compound into the site;

permitting the first compound to diffuse through the site;

introducing a second compound into the site, the second compound comprising an oxidizing agent reactable with the first compound to release a free radical;

during the first and the second compound introducing steps, causing turbulence in the ground water to facilitate dispersion of the first and the second compound throughout the site;

permitting the first and the second compounds to react to release a free radical;

introducing a pH-adjusting compound into the site for optimizing the reaction between the first and the second compounds; and

permitting the free radical to act upon a site contaminant to form an environmentally neutral species.

17. The method recited in claim 16, further comprising the step of extracting a vapor component of the environmentally neutral species below ground.

18. The method recited in claim 16, wherein:

the first and the second compound introducing steps comprise injecting the first and the second compound at a first location; and

the turbulence-causing step comprises injecting a gas in a plurality of on/off pressure cycles at a second location in spaced relation to the first location.

19. The method recited in claim 16, wherein:

the first and the second compound introducing steps comprise injecting the first and the second compound at a first location; and

the turbulence-causing and the pH-adjusting steps comprise injecting cabon dioxide gas in a plurality of on/off pressure cycles at a second location in spaced relation to the first location.

20. The method recited in claim 19, wherein the second location comprises a depth lower than a depth of the first location.

21. A method for controlling a Fenton-type reaction at a contaminated site comprising the steps of:

increasing a porosity of soil at a below-ground contaminated site containing ground water, the soil having a hydrocarbon contaminant therein;

introducing a Fenton reagent into the site;

enhancing a diffusion of the Fenton reagent throughout the site;

introducing an oxidizing agent into the site;

enhancing a diffusion of the oxidizing agent throughout the site;

permitting a Fenton reaction to occur, releasing a free radical;

introducing a pH-adjusting compound into the site for optimizing the reaction between the Fenton reagent and the oxidizing agent; and

permitting the free radical to act upon a contaminant to form environmentally neutral species.

22. The method recited in claim 21, further comprising the step of extracting a gaseous component of the environmentally neutral species.

23. The method recited in claim 21, wherein the pH-adjusting compound introducing step and the diffusion-enhancing steps comprise causing turbulence in the groundwater by injecting carbon dioxide gas under pressure there into and performing a hydraulic fracturing on the soil.

24. A method for delivering a Fenton-type reaction to a contaminated below-ground site comprising the steps of:

creating a portal into a contaminated site beneath a water table thereof, the contaminated site essentially free from prior chemical treatment;

increasing a porosity of soil at the site;

introducing a Fenton reagent into the portal;

permitting the Fenton reagent to diffuse through the site;

introducing an oxidizing agent into the portal;

permitting a Fenton reaction to occur, releasing a free radical for acting upon contaminant bonds to create environmentally neutral species therefrom; and

introducing a pH-adjusting agent into the site to optimize the Fenton reaction.

25. The method recited in claim 24, further comprising the steps, following the Fenton reagent introducing step, of causing turbulence in the site groundwater, for facilitating the diffusion permitting step.

26. The method recited in claim 25, wherein the turbulence-causing and pH-adjusting steps comprise injecting carbon dioxide gas into the groundwater under pressure.

27. The method recited in claim 25, wherein the portal comprises a first portal and the turbulence-causing step comprises:

creating a second portal into the site in spaced relation to the first portal beneath a depth thereof; and

injecting a gas into the second portal in a plurality of on/off pressure cycles.

28. The method recited in claim 27, wherein the gas comprises carbon dioxide.

29. A system for remediating a contaminated site comprising:

means for increasing a porosity of soil at a site containing ground water, the soil having a hydrocarbon contaminant therein;

means for sequentially introducing a first and a second composition into the site, the site essentially chemically untreated, the first and the second compositions comprising Fenton-type reactants;

means for adjusting a pH of the site to optimize a Fenton reaction between the first and the second compositions; and

means for introducing turbulence in the ground water, for facilitating a dispersion of the first and the second composition throughout the site and for enhancing a mixing thereof.

30. The system recited in claim 29, wherein the turbulence-introducing means comprises a source of gas under pressure.

31. The system recited in claim 29, wherein the turbulence-introducing means and the pH-adjusting means comprise a source of carbon dioxide gas under pressure.

32. The system recited in claim 29, wherein the composition introducing means comprises a first portal having an outlet at a first depth below a water table.

33. The system recited in claim 32, wherein the turbulence introducing means further comprises a second portal having an outlet at a second depth below the first depth and above a confining layer.

34. The system recited in claim 33, further comprising means for collecting vapors produced during Fenton reaction.

35. The system recited in claim 34, wherein the vapor collecting means comprises means for introducing a partial vacuum within the site.

36. The system recited in claim 29, wherein the composition introducing means comprises a plurality of injection portals positioned throughout the site in spaced relation from each other.

37. The system recited in claim 36, wherein each injection portal has a radius of influence within the site and the injection portals are positioned to achieve overlapping radii of influences therebetween to achieve essentially complete diffusion of the Fenton-type reactants throughout the site.

38. The system recited in claim 36, wherein each injection portal has an outlet at a first depth beneath a water table of the site.

39. The system recited in claim 38, wherein the turbulence introducing means comprises a plurality of pressurized gas portals positioned throughout the site in spaced relation from each other and from the injection portals.

40. The system recited in claim 39, wherein each gas portal has an outlet at a second depth beneath t he first depth.

41. The system recited in claim 40, further comprising means for collecting vapor produced by a reaction of the Fenton-type reactants.

42. The system recited in claim 41, wherein the vapor collecting means comprises a vapor capture portal having a first opening at a third depth above the water table.

43. The system recited in claim 42, wherein the vapor collecting means further comprises means for applying a partial vacuum to a second opening of the vapor capture portal for enhancing a removal of vapor from the site.

44. The system recited in claim 43, further comprising a means in fluid communication with the vacuum applying means for filtering collected vapors.

45. The system recited in claim 44, wherein the filter means comprises an activated carbon filter having an inlet in communication with the vacuum applying means and an outlet in communication with the atmosphere.

46. The system recited in claim 29, wherein the composition introducing means comprises a first pipe having an opening at an outlet end and the turbulence introducing means comprises a second pipe having an opening at an outlet end.

47. The system recited in claim 46, further comprising:

means for creating a bore having a diameter sufficient to place the first and the second pipe thereinto and a depth sufficient to reach beneath a water table of the site; and

a fluid-permeable packing for surrounding the first and the second pipe in the bore.

48. The system recited in claim 29, wherein the porosity-increasing means comprises means for creating fissures in the soil.

49. The system recited in claim 48, further comprising means for injecting into the fissures means for holding the fissures open.

50. The system recited in claim 49, wherein the holding means comprises a proppant.

51. The system recited in claim 50, wherein the proppant comprises a graded sand.

52. A remediation site for reducing a below-ground contaminant level, the site comprising:

ground water and soil having been essentially chemically unpretreated, the soil having a porosity sufficiently low to inhibit liquid diffusion therethrough;

a contaminant plume having a hydrocarbon contaminant therein present in the ground water and the soil;

means for increasing a porosity of the soil;

means for sequentially introducing a first and a second composition into the contaminant plume, the first and the second compositions comprising Fenton-type reactants;

means for introducing a pH-adjusting compound into the ground water and the soil; and

means for introducing turbulence in the ground water, for facilitating a dispersion of the first and the second composition throughout the contaminant plume and for enhancing a mixing thereof.

53. The site recited in claim 52, wherein the porosity-increasing means comprises means for performing hydraulic fracturing.

54. The site recited in claim 52, further comprising a vapor extraction system for collecting reaction gases, the system comprising:

means for producing a partial vacuum; and

a vapor capture portal having a bottom opening below ground spaced above the contaminant plume and a top opening above ground in fluid communication with the vacuum producing means.