Process for purification by combination of an effluent that contains carbon dioxide and hydrocarbons

• US 6,505,683 B2
• Filed: 04/27/2001
• Issued: 01/14/2003
• Est. Priority Date: 04/27/2000
• Status: Expired due to Fees

• Current Assignee: Institut Francais Du Petrole
• Original Assignee: Institut Francais Du Petrole
• Inventors: Rojey, Alexandre, Minkkinen, Ari
• Primary Examiner(s): SUCHFIELD, GEORGE A
• Application Number:
  US09/843,645
• Publication Number:
  US 20020036086A1
• Time in Patent Office: 627 Days
• Field of Search: 166/75.12, 166/266, 166/267, 166/268, 166/272.1, 166/302, 166/404
• US Class Current: 166/266
• CPC Class Codes: C01B 32/50 Carbon dioxide
• CPC Class Codes: E21B 43/164 Injecting CO2 or carbonated water in combination with organic material C09K8/594
• CPC Class Codes: E21B 43/40 Separation associated with re-injection of separated materials E21B43/385 takes precedence
• CPC Class Codes: F25J 2260/80 Integration in an installation using carbon dioxide, e.g. for EOR, sequestration, refrigeration etc.
• CPC Class Codes: F25J 3/04533 for the direct combustion of fuels in a power plant, so-called "oxyfuel combustion"
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

For the purification of an effluent that contains carbon dioxide and hydrocarbons resulting from a carbon dioxide-assisted recovery stage, the effluent is circulated in a gas-liquid separator (3) to recover C₃⁺ liquid and a gas that contains carbon dioxide and, for example, less than 10% of methane and ethane. Pressurized combustion (13) of the gas with air produced a combustion gas (21) enriched with carbon dioxide and water vapor. The combustion gas (21) is cooled (11) (22) to recover heat, and the cooled combustion gas is recycled under pressure by a compressor (27) to an injection well (29). Nitrogen is at least partly separated from the combustion gas before the recycling, and in an optional intermediate step the condensed water is also separated from the carbon dioxide. The invention has a particular application for the assisted recovery of petroleum by CO₂ with a reduction of the greenhouse effect.

Claims

1. A process for purification of a G/L two-phase effluent containing carbon dioxide and gaseous and liquid hydrocarbons obtained from at least one hydrocarbon production well utilizing an injection of carbon dioxide into a formation, said process comprising:

a) separating said G/L effluent in at least one main gas-liquid separator (3), to separate C₃⁺ hydrocarbons (5) from a gaseous effluent (10) containing a major portion of carbon dioxide (CO₂) and a minor portion of methane and ethane,

b) subjecting said gaseous effluent to pressurized combustion (13) in the presence of oxygen in a combustion reactor, and recovering a combustion effluent (21) containing carbon dioxide, water vapor, and nitrogen,

c) cooling (11/22) said combustion effluent (21),

d) separating the nitrogen at least in part from the cooled combustion effluent; and

e) recycling the pressurized, cooled combustion effluent into an injection well.

2. A process according to claim 1, wherein a temperature increase of the combustion effluent, due to the exothermicity of the combustion reaction, is controlled by indirect heat exchange between the combustion effluent and a coolant (30) to recover the heat of combustion.

3. A process according to claim 1, further comprising, after stage c), cooling the combustion effluent and separating the resultant condensed water from the combustion effluent in an H₂O/CO₂ separator (24).

4. A process according to claim 1, wherein the combustion of the gaseous effluent is carried out in the presence of a catalyst.

5. A process according to claim 3, wherein the G/L effluent from the production well contains hydrogen sulfide, the separation stage of the water in the separator comprises a sulfur dioxide (SO₂) scrubbing stage to remove SO₂ resulting from the combustion of hydrogen sulfide in the combustion reactor, and an effluent that contains water and at least the major portion of SO₂ is recovered from said scrubbing stage.

6. A process according to claim 5, wherein the SO₂ scrubbing stage comprises a direct contact of the combustion effluent with water.

7. A process according to claim 3, further comprising cooling at least a portion of the separated condensed water and recycling the cooled water to the H₂O/CO₂ separator.

8. A process according to claim 1, wherein separation of said G/L effluent comprises introducing G/L effluent from the production well into gas-liquid separator (3), recovering a first fraction (5) containing the C₃⁺ liquid hydrocarbons at the bottom of said separator (3), and recovering a second fraction (4) containing carbon dioxide and a minor portion of hydrocarbons from the top of said separator (3);

compressing (6) said second fraction, and introducing the compressed second fraction into a secondary gas-liquid separator (8) wherein said gaseous effluent (10) is separated from remaining C₃⁺ hydrocarbons (9).

9. A process according to claim 1, further comprising reheating said gaseous effluent (10) by indirect heat exchange (11) with effluent (21) from the combustion reaction (13) before said gaseous effluent is subjected combustion reaction.

10. A process according to claim 1, further comprising introducing fuel into the combustion reactor at a rate sufficient to maintain a substantially constant temperature level in the combustion reactor.

11. A process according to claim 1, wherein the separation of the nitrogen from the combustion effluent is carried out by cryogenic distillation.