Dishwashing compositions comprising modified alkybenzene sulfonates

• US 6,506,717 B1
• Filed: 07/19/2001
• Issued: 01/14/2003
• Est. Priority Date: 01/20/1999
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Scheper, William Michael, Severson, Roland George, Scheibel, Jeffrey John, Kasturi, Chandrika, Burckett-St. Laurent, James Charles Theophile Roger, Kott, Kevin Lee, Cripe, Thomas Anthony
• Primary Examiner(s): OGDEN JR, NECHOLUS
• Application Number:
  US09/889,629
• Time in Patent Office: 544 Days
• Field of Search: 510/357, 510/424, 510/426, 510/428
• US Class Current: 510/357
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/37 Mixtures of compounds all of which are anionic
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/721 End blocked ethers
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 11/04 by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising

Abstract

The present invention relates to surfactant mixtures, improved detergent and cleaning products containing particular types of modified alkylbenzenesulfonate surfactants.

Claims

1. A hand dishwashing detergent composition comprising:

(i) from about 0.01% to about 95% by weight of composition of a modified alkylbenzene sulfonate surfactant mixture comprising;

(a) from about 60% to about 95% by weight of surfactant mixture, a mixture of branched alkylbenzene sulfonates having formula (I);

wherein L is an acyclic aliphatic moiety consisting of carbon and hydrogen, said L having two methyl termini and said L having no substituents other than A, R¹ and R²; and

wherein said mixture of branched alkylbenzene sulfonates contains two or more of said branched alkylbenzene sulfonates differing in molecular weight of the anion of said formula (I) and wherein said mixture of branched alkylbenzene sulfonates has

a sum of carbon atoms in R¹, L and R² of from 9 to 15;

an average aliphatic carbon content of from about 10.0 to about 14.0 carbon atoms;

M is a cation or cation mixture having a valence q;

a and b are integers selected such that said branched alkylbenzene sulfonates are electroneutral;

R¹ is C₁-C₃ alkyl;

R² is selected from H and C₁-C₃ alkyl;

A is a benzene moiety; and

(b) from about 5% to about 40% by weight of surfactant mixture, of a mixture of nonbranched alkylbenzene sulfonates having formula (II);

wherein a, b, M, A and q are as defined hereinbefore and Y is an unsubstituted linear aliphatic moiety consisting of carbon and hydrogen having two methyl termini, and wherein said Y has a sum of carbon atoms of from 9 to 15, and said Y has an average aliphatic carbon content of from about 10.0 to about 14.0; and

 

wherein said modified alkylbenzene sulfonate surfactant mixture is further characterized by a 2/3-phenyl index of from about 275 to about 10,000;

(i) from about 0.00001% to about 99.9% by weight of composition of a conventional hand dishwashing adjunct;

wherein said composition is further characterized by a 2/3-phenyl index of from about 275 to about 10,000.

2. A hand dishwashing detergent composition according to claim 1 wherein said Y has a sum of caron atoms of from 10 to 14.

3. A hand dishwashing detergent composition according to claim 1 wherein said M is selected from H, Na, K and mixtures thereof, said a=1, said b=1, said q=1, and said modified alkylbenzene sulfonate surfactant mixture has a 2-methyl-2-phenyl index of less than about 0.3.

4. A hand dishwashing detergent composition according to claim 3 wherein said 2-methyl-2-phenyl index is from 0 to about 0.1.

5. A hand dishwashing detergent composition according to claim 4 wherein said modified alkylbenzene sulfonate surfactant mixture is the product of a process using as catalyst a zeolite selected from mordenite, offretite and H-ZSM-12 in at least partially acidic form.

6. A hand dishwashing detergent composition according to claim 5 wherein said catalyst is an acidic mordenite.

7. A hand dishwashing detergent composition comprising:

(i) from about 0.1% to about 95% by weight of composition of a medium 2/3-phenyl surfactant system consisting essentially of;

(1) from 1% to about 60% by weight of surfactant system of a first alkylbenzene sulfonate surfactant, wherein said first alkylbenzene sulfonate surfactant is a modified alkylbenzene sulfonate surfactant mixture, said surfactant mixture comprising;

(a) from about 60% to about 95% by weight of surfactant mixture, a mixture of branched alkylbenzene sulfonates having formula (I);

wherein L is an acyclic aliphatic moiety consisting of carbon and hydrogen, said L having two methyl termini and said L having no substituents other than A, R¹ and R²; and

wherein said mixture of branched alkylbenzene sulfonates contains two or more of said branched alkylbenzene sulfonates differing in molecular weight of the anion of said formula (I) and wherein said mixture of branched alkylbenzene sulfonates has

a sum of carbon atoms in R¹, L and R² of from 9 to 15;

an average aliphatic carbon content of from about 10.0 to about 14.0 carbon atoms;

M is a cation or cation mixture having a valence q;

a and b are integers selected such that said branched alkylbenzene sulfonates are electroneutral;

R¹ is C₁-C₃ alkyl;

R² is selected from H and C₁-C₃ alkyl;

A is a benzene moiety; and

(b) from about 5% to about 40% by weight of surfactant mixture, of a mixture of nonbranched alkylbenzene sulfonates having formula (II);

wherein a, b, M, A and q are as defined hereinbefore and Y is an unsubstituted linear aliphatic moiety consisting of carbon and hydrogen having two methyl termini, and wherein said Y has a sum of carbon atoms of from 9 to 15, and said Y has an average aliphatic carbon content of from about 10.0 to about 14.0; and

 

wherein said modified alkylbenzene sulfonate surfactant mixture is further characterized by a 2/3-phenyl index of from about 275 to about 10,000; and

(2) from 40% to about 99%, by weight of surfactant system of a second alkylbenzene sulfonate surfactant, wherein said second alkylbenzene sulfonate surfactant is an alkylbenzene sulfonate surfactant mixture other than said modified alkylbenzene sulfonate surfactant mixture (1), and wherein said second alkylbenzene sulfonate surfactant has a 2/3-phenyl index of from about 75 to about 160;

 

provided that said medium 2/3-phenyl surfactant system has a 2/3-phenyl index of from about 160 to about 275;

(i) from about 0.00001% to about 99.9% by weight of composition of a conventional hand dishwashing adjunct.

8. A hand dishwashing detergent composition according to claim 7 wherein said Y has a sum of caron atoms of from 10 to 14.

9. A hand dishwashing detergent composition according to claim 7 wherein said modified alkylbenzene sulfonate surfactant mixture consists essentially of said mixture of (a) and (b), wherein said 2-methyl-2-phenyl index of said modified alkylbenzene sulfonate surfactant mixture is less than about 0.1, and said average aliphatic carbon content is from about 11.5 to about 12.5 carbon atoms;

said R¹ is methyl;

said R² is selected from H and methyl provided that in at least about 0.7 mole fraction of said branched alkylbenzene sulfonates R² is H; and

wherein said sum of carbon atoms in R¹, L and R² is from 10 to 14; and

further wherein in said mixture of nonbranched alkylbenzene sulfonates, said Y has a sum of carbon atoms of from 10 to 14 carbon atoms, said average aliphatic carbon content of said nonbranched alkylbenzene sulfonates is from about 11.5 to about 12.5 carbon atoms, and said M is a monovalent cation or cation mixture selected from H, Na and mixtures thereof.

10. A hand dishwashing detergent composition comprising:

(i) a modified alkylbenzene sulfonate surfactant mixture comprising the product of a process comprising the steps of;

(I) alkylating benzene with an alkylating mixture;

(II) sulfonating the product of (I); and

(III) neutralizing the product of (II);

 

wherein said alkylating mixture comprises;

(a) from about 1% to about 99.9%, by weight of alkylating mixture of branched C₉-C₂₀ monoolefins, said branched monoolefins having structures identical with those of the branched monoolefins formed by dehydrogenating branched paraffins of formula R¹LR² wherein L is an acyclic aliphatic moiety consisting of carbon and hydrogen and containing two terminal methyls;

R¹ is C₁ to C₃ alkyl; and

R² is selected from H and C₁ to C₃ alkyl; and

(b) from about 0.1% to about 85%, by weight of alkylating mixture of C₉-C₂₀ linear aliphatic olefins;

 

wherein said alkylating mixture contains said branched C₉-C₂₀ monoolefins having at least two different carbon numbers in said C₉-C₂₀ range, and has a mean carbon content of from about 9.0 to about 15.0 carbon atoms; and

wherein said components (a) and (b) are at a weight ratio of at least about 15;

85;

(ii) from about 0.00001% to about 99.9% by weight of composition of a conventional hand dishwashing adjunct;

wherein said composition is further characterized by a 2/3-phenyl index of from about 275 to about 10,000.

11. A hand dishwashing detergent composition comprising:

(i) A modified alkylbenzene sulfonate surfactant mixture consisting essentially of the product of a process comprising the steps, in sequence, of;

(I) alkylating benzene with an alkylating mixture;

(II) sulfonating the product of (I); and

(III) neutralizing the product of (II);

 

wherein said alkylating mixture comprises;

(a) from about 1% to about 99.9%, by weight of alkylating mixture of a branched alkylating agent selected from the group consisting of;

(A) C₉-C₂₀ internal monoolefins R¹LR² wherein L is an acyclic olefinic moiety consisting of carbon and hydrogen and containing two terminal methyls;

(B) C₉-C₂₀ alpha monoolefins R¹AR² wherein A is an acyclic alpha-olefinic moiety consisting of carbon and hydrogen and containing one terminal methyl and one terminal olefinic methylene;

(C) C₉-C₂₀ vinylidene monoolefins R¹BR² wherein B is an acyclic vinylidene olefin moiety consisting of carbon and hydrogen and containing two terminal methyls and one internal olefinic methylene;

(D) C₉-C₂₀ primary alcohols R¹QR² wherein Q is an acyclic aliphatic primary terminal alcohol moiety consisting of carbon, hydrogen and oxygen and containing one terminal methyl;

(E) C₉-C₂₀ primary alcohols R¹ZR² wherein Z is an acyclic aliphatic primary nonterminal alcohol moiety consisting of carbon, hydrogen and oxygen and containing two terminal methyls; and

(F) mixtures thereof;

 

wherein in any of (A)-(F), said R¹ is C₁ to C₃ alkyl and said R² is selected from H and C¹ to C₃ alkyl; and

(b) from about 0.1% to about 85%, by weight of alkylating mixture of C₉-C₂₀ linear alkylating agent selected from C₉-C₂₀ linear aliphatic olefins, C₉-C₂₀ linear aliphatic alcohols and mixtures thereof;

 

wherein said alkylating mixture contains said branched alkylating agents having at least two different carbon numbers in said C₉-C₂₀ range, and has a mean carbon content of from about 9.0 to about 15.0 carbon atoms; and

wherein said components (a) and (b) are at a weight ratio of at least about 15;

85;

(i) from about 0.00001% to about 99.9% by weight of composition of a conventional hand dishwashing adjunct;

wherein said composition is further characterized by a 2/3-phenyl index of from about 275 to about 10,000.

12. A hand dishwashing composition according to claim 11 wherein said alkylating mixture consists essentially of:

(a) from about 0.5% to about 47.5%, by weight of alkylating mixture of said branched alkylating agent selected from;

(G) C₉-C₁₄ internal monoolefins R¹LR² wherein L is an acyclic olefinic moiety consisting of carbon and hydrogen and containing two terminal methyls;

(H) C₉-C₁₄ alpha monoolefins R¹AR² wherein A is an acyclic alpha-olefinic moiety consisting of carbon and hydrogen and containing one terminal methyl and one terminal olefinic methylene; and

(J) mixtures thereof;

 

wherein in any of (G), (H) and (J), said R¹ is methyl, and said R² is H or methyl provided that in at least about 0.7 mole fraction of the total of said monoolefins, R² is H; and

(b) from about 0.1% to about 25%, by weight of alkylating mixture of C₉-C₁₄ linear aliphatic olefins; and

(c) from about 50% to about 98.9%, by weight of alkylating mixture of carrier materials selected from paraffins and inert nonparaffinic solvents;

wherein said alkylating mixture contains said branched alkylating agents having at least two different carbon numbers in said C₉-C₁₄ range, and has a mean carbon content of from about 11.5 to about 12.5 carbon atoms; and

wherein said components (a) and (b) are at a weight ratio of from about 51;

49 to about 90;

10.

13. A hand dishwashing composition according to claim 12 wherein in step (I), said alkylation is performed in the presence of an alkylation catalyst, said alkylation catalyst is an intermediate acidity solid porous alkylation catalyst, and step (II) comprises removal of components other than monoalkylbenzene prior to contacting the product of step (I) with sulfonating agent.

14. A hand dishwashing composition according to claim 12 wherein said alkylation catalyst is other than a member selected from the group consisting of HF, AlCl₃, sulfuric acid and mixtures thereof.

15. A hand dishwashing composition according to claim 12 wherein a hydrotrope, hydrotrope precursor, or mixtures thereof is added after step (I).

16. A hand dishwashing composition according to claim 12 wherein a hydrotrope, hydrotrope precursor or mixtures thereof is added during or after step (II) and prior to step (III).

17. A hand dishwashing composition according to claim 12 wherein a hydrotrope is added during or after step (III).

18. A hand dishwashing composition according to claim 12 wherein said alkylation catalyst is selected from the group consisting of non-fluoridated acidic mordenite-type catalyst, fluoridated acidic mordenite-type catalyst and mixtures thereof.

19. A hand dishwashing composition according to claim 12 wherein in step (I) said alkylation is performed at a temperature of from about 125°

C. to about 230°

C. and at a pressure of from about 50 psig to about 1000 psig.

20. A hand dishwashing composition according to claim 12 wherein step (II) is performed using a sulfonating agent selected from the group consisting of sulfur trioxide, sulfur trioxide/air mixtures, and sulfuric acid.

21. A hand dishwashing composition comprising:

(i) from about 0.01% to about 95% by weight of composition of a modified alkylbenzene sulfonate surfactant mixture comprising;

(a) from about 60% to about 95% by weight of surfactant mixture, a mixture of branched alkylbenzene sulfonates having formula (I);

wherein L is an acyclic aliphatic moiety consisting of carbon and hydrogen, said L having two methyl termini and said L having no substituents other than A, R¹ and R²; and

wherein said mixture of branched alkylbenzene sulfonates contains two or more of said branched alkylbenzene sulfonates differing in molecular weight of the anion of said formula (I) and wherein said mixture of branched alkylbenzene sulfonates has

a sum of carbon atoms in R¹, L and R² of from 9 to 15;

an average aliphatic carbon content of from about 10.0 to about 14.0 carbon atoms;

M is a cation or cation mixture having a valence q;

a and b are integers selected such that said branched alkylbenzene sulfonates are electroneutral;

R¹ is C₁-C₃ alkyl;

R² is selected from H and C₁-C₃ alkyl;

A is a benzene moiety; and

(b) from about 5% to about 40% by weight of surfactant mixture, of a mixture of nonbranched alkylbenzene sulfonates having formula (II);

wherein a, b, M, A and q are as defined hereinbefore and Y is an unsubstituted linear aliphatic moiety consisting of carbon and hydrogen having two methyl termini, and wherein said Y has a sum of carbon atoms of from 9 to 15, and said Y has an average aliphatic carbon content of from about 10.0 to about 14.0; and

 

wherein said modified alkylbenzene sulfonate surfactant mixture is further characterized by a 2/3-phenyl index of from about 275 to about 10,000 and wherein said modified alkylbenzene sulfonate surfactant mixture has a 2-methyl-2-phenyl index of less than about 0.3;

(ii) from about 0.00001% to about 99.9% by weight of composition of a conventional hand dishwashing adjunct; and

(iii) from about 0.00001% to about 99.9% of composition of a surfactant selected from the group consisting of anionic surfactants other than those of (i), nonionic surfactants, zwitterionic surfactants, cationic surfactants, amphoteric surfactant and mixtures thereof;

wherein said composition is further characterized by a 2/3-phenyl index of from about 275 to about 10,000;

provided that when said composition comprises any alkylbenzene sulfonate surfactant other than said modified alkylbenzene sulfonate surfactant mixture, said composition is further characterized by an overall 2/3-phenyl index of at least about 200, wherein said overall 2/3-phenyl index is determined by measuring 2/3-phenyl index, as defined herein, on a blend of said modified alkylbenzene sulfonate surfactant mixture and said any other alkylbenzene sulfonate to be added to said composition, said blend, for purposes of measurement, being prepared from aliquots of said modified alkylbenzene sulfonate surfactant mixture and said other alkylbenzene sulfonate not yet exposed to any other of the components of said composition; and

further provided that when said composition comprises any alkylbenzene sulfonate surfactant other than said modified alkylbenzene sulfonate surfactant mixture, said composition is further characterized by an overall 2-methyl-2-phenyl index of less than about 0.3, wherein said overall 2-methyl-2-phenyl index is to be determined by measuring 2-methyl-2-phenyl index, as defined herein, on a blend of said modified alkylbenzene sulfonate surfactant mixture and any other alkylbenzene sulfonate to be added to said composition, said blend, for purposes of measurement, being prepared from aliquots of said modified alkylbenzene sulfonate surfactant mixture and said other alkylbenzene sulfonate not yet exposed to any other of the components of said composition.

22. A hand dishwashing detergent composition according to claim 21 wherein said Y has a sum of caron atoms of from 10 to 14.

23. A hand dishwashing composition according to claim 21 which is substantially free from alkylbenzene sulfonate surfactants other than said modified alkylbenzene sulfonate surfactant mixture.

24. A hand dishwashing composition according to claim 21 which comprises, in said component (iii), at least about 0.1%, of a commercial C₁₀-C₁₄ linear alkylbenzene sulfonate surfactant.

25. A hand dishwashing composition according to claim 21 which comprises, in said component (iii), at least about 0.1% of a commercial highly branched alkylbenzene sulfonate surfactant.

26. A hand dishwashing composition according to claim 21 which comprises, in said component (iii), a nonionic surfactant at a level of from about 0.5% to about 25% by weight of said detergent composition, and wherein said nonionic surfactant is a polyalkoxylated alcohol in capped or non-capped form having:

a hydrophobic group selected from linear C₁₀-C₁₆ alkyl, mid-chain C₁-C₃ branched C₁₀-C₁₆ alkyl, guerbet branched C₁₀-C₁₆ alkyl, and mixtures thereof and

a hydrophilic group selected from 1-15 ethoxylates, 1-15 propoxylates 1-15 butoxylates and mixtures thereof, in capped or uncapped form.

27. A hand dishwashing composition according to claim 21 which comprises, in said component (iii), an alkyl sulfate surfactant at a level of from about 0.5% to about 25% by weight of said detergent composition, wherein said alkyl sulfate surfactant has a hydrophobic group selected from linear C₁₀-C₁₈ alkyl, mid-chain C₁-C₃ branched C₁₀-C₁₈ alkyl, guerbet branched C₁₀-C₁₈ alkyl, and mixtures thereof and a cation selected from Na, K and mixtures thereof.

28. A hand dishwashing composition according to claim 21 which comprises, in said component (iii), an alkyl(polyalkoxy)sulfate surfactant at a level of from about 0.5% to about 25% by weight of said detergent composition, wherein said alkyl(polyalkoxy)sulfate surfactant has

a hydrophobic group selected from linear C₁₀-C₁₆ alkyl, mid-chain C₁-C₃ branched C₁₀-C₁₆alkyl, guerbet branched C₁₀-C₁₆alkyl, and mixtures thereof;

and

a (polyalkoxy)sulfate hydrophilic group selected from 1-15 polyethoxysulfate, 1-15 polypropoxysulfate, 1-15 polybutoxysulfate, 1-15 mixed poly(ethoxy/propoxy/butoxy)sulfates, and mixtures thereof, in capped or uncapped form; and

a cation selected from Na, K and mixtures thereof.