Process for recovering processing liquids

• US 6,508,916 B1
• Filed: 06/14/1999
• Issued: 01/21/2003
• Est. Priority Date: 06/14/1999
• Status: Expired due to Term

• Current Assignee: CCR Technologies Ltd.
• Original Assignee: Canadian Chemical Reclaiming Ltd.
• Inventors: Razzaghi, Minoo, Keast, Brian A., Kresnyak, Stephen G., Giles, Timothy W.
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US09/332,801
• Time in Patent Office: 1,317 Days
• Field of Search: 203/14, 203/80, 203/77, 203/1, 203/40, 203/11, 203/90, 203/73, 203/2, 203/78, 203/20, 203/74, 203/75, 203/100, 203/27, 203/22, 203/DIG.8, 202/205, 202/236, 202/160, 202/237, 159/23, 159/47.3, 159/48.1, 159/DIG.4, 159/44, 159/DIG.16, 952/42, 952/43, 952/51, 210/774
• US Class Current: 203/11
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: Y10S 159/16 Vacuum
• CPC Class Codes: Y10S 203/08 Waste heat

Abstract

A process for recovering processing liquids such as gas-treating liquids wherein a feed mixture containing the processing liquid, water, and optionally additional components that are more volatile than the processing liquid and components that are less volatile than the processing liquid, is initially heated in a first heating zone to a temperature sufficient to volatilize at least some of the water and a portion of the processing liquid without decomposing the processing liquid to produce a vapor stream containing volatilized water and processing liquid and a residuum containing the bulk of the processing liquid and less volatile component, the vapor stream being separated from the residuum and treated to produce recycle streams of water, purified processing liquid, and low and high boiling liquid fractions recovered from the purified processing liquid.

Claims

1. A process for recovering a processing liquid from a feed mixture comprising water, a processing liquid having a higher boiling point than water, and at least one component that is less volatile than said processing liquid, comprising:

providing a stream of said feed mixture;

introducing said stream of said feed mixture into a first heating zone and initially heating said feed mixture to a temperature sufficient to volatilize at least some of said water and at least a portion of said processing liquid, said temperature in said first heating zone being below the decomposition temperature of said processing liquid, to produce a vapor stream comprising said volatilized water and said volatilized portion of said processing liquid, and a residuum comprising said processing liquid and at least some of said at least one less volatile component;

separating said vapor stream from said residuum in a first separation zone;

passing at least a portion of said residuum through a second heating zone at a temperature below the decomposition temperature of said processing liquid to produce a heated, first recycle stream;

reducing the concentration of said less volatile component in said residuum;

admixing said heated recycle stream with said stream of said feed mixture to effect said initial heating of said feed mixture;

treating said vapor stream to recover a water stream and a purified processing liquid stream; and

admixing, by recycle, at least a portion of at least one of said water stream and said purified processing stream with said stream of said feed mixture.

2. The process of claim 1 wherein at least some of said less volatile component is removed from said residuum by purging a portion of said residuum from said process.

3. The process of claim 1 wherein said residuum contains solids of said less volatile component and wherein a second portion of said residuum is passed through a solids/liquid separation zone to produce a substantially solids-free, second recycle stream and a substantially solids waste stream, said second recycle stream being recycled to said first separation zone.

4. The process of claim 1 wherein said second heating zone comprises a tubular heating zone and said residuum is passed through said second heating zone at a flow rate of greater than 10 feet per second, the pressure inside the second heating zone being regulated by back pressure regulation to minimize vaporization in said second heating zone.

5. The process of claim 4 wherein said residuum is passed through said second heating zone at a flow rate of from about 11 to about 16 feet per second.

6. The process of claim 4 wherein said back pressure regulation is effected between said second heating zone and said first heating zone, said initial heating of said feed mixture and said separating in said first separation zone being conducted under vacuum conditions.

7. The process of claim 4 wherein said back pressure regulation is effected between said first heating zone and said first separation zone, said first heating zone being under positive pressure, said separating in said first separation zone being conducted under vacuum conditions.

8. The process of claim 1 conducted on a continuous basis.

9. The process of claim 1 wherein said stream of said feed mixture contains at least one additional component more volatile than said processing liquid and water, and said vapor stream is separated in a second separation zone into a light fraction containing water and said at least one more volatile component and a heavy fraction containing said purified processing liquid stream, and said water stream is separated from said light fraction in a third separation zone.

10. A process for recovering a processing liquid from a feed mixture comprising water, a processing liquid having a higher boiling point than water, and at least one component that is less volatile than said processing liquid, comprising:

providing a stream of said feed mixture;

introducing said stream of said feed mixture into a first heating zone and initially heating said feed mixture to a temperature sufficient to volatilize at least some of said water and at least a portion of said processing liquid, said temperature in said first heating zone being below the decomposition temperature of said processing liquid, to produce a vapor stream comprising said volatilized water and said volatilized portion of said processing liquid, and a residuum comprising said processing liquid and at least some of said at least one less volatile component;

separating said vapor stream from said residuum in a first separation zone;

passing at least a portion of said residuum through a second heating zone at a temperature below the decomposition temperature of said processing liquid to produce a heated, first recycle stream;

reducing the concentration of said less volatile component in said residuum;

admixing said heated recycle stream with said stream of said feed mixture to effect said initial heating of said feed mixture;

treating said vapor stream to recover a water stream and a purified processing liquid stream;

separating said purified processing liquid stream into a low boiling liquid fraction and a high boiling fraction; and

admixing, by recycle, at least a portion of at least one of said water stream, said high boiling fraction, and said low boiling fraction with said stream of said feed mixture.

11. The process of claim 10 wherein at least some of said less volatile component is removed from said residuum by purging a portion of said residuum from said process.

12. The process of claim 10 wherein said residuum contains solids of said less volatile component and wherein a second portion of said residuum is passed through a solids/liquid separation zone to produce a substantially solids-free, second recycle stream and a substantially solids waste stream, said second recycle stream being recycled to said first separation zone.

13. The process of claim 10 wherein said second heating zone comprises a tubular heating zone and said residuum is passed through said second heating zone at a flow rate of greater than 10 feet per second, the pressure inside the second heating zone being regulated by back pressure regulation to minimize vaporization in said second heating zone, said back pressure regulation being of a type that minimizes turbulent flow.

14. The process of claim 13 wherein said residuum is passed through said second heating zone at a flow rate of from about 11 to about 16 feet per second.

15. The process of claim 13 wherein said back pressure regulation is effected between said second heating zone and said first heating zone, said initial heating of said feed mixture and said separating in said first separation zone being conducted under vacuum conditions.

16. The process of claim 13 wherein said back pressure regulation is effected between said first heating zone and said first separation zone, said first heating zone being under positive pressure, said separating in said first separation zone being conducted under vacuum conditions.

17. The process of claim 10 conducted on a continuous basis.