Method for stabilizing operation of fluid catalytic converter units

• US 6,508,930 B1
• Filed: 04/29/1998
• Issued: 01/21/2003
• Est. Priority Date: 04/29/1998
• Status: Expired due to Term

• Current Assignee: Intercat Inc. (Johnson Matthey PLC)
• Original Assignee: Intercat Inc. (Johnson Matthey PLC)
• Inventors: Evans, Martin, Paraskos, John A., Vierheilig, Albert A.
• Primary Examiner(s): Yildirim, Bekir L.
• Application Number:
  US09/069,300
• Time in Patent Office: 1,728 Days
• Field of Search: 208/113, 208/152, 208/155, 208/158, 208/160, 208/163, 208/164, 208/DIG.1
• US Class Current: 208/113
• CPC Class Codes: C10G 11/187 Controlling or regulating
• CPC Class Codes: Y02P 30/40 Ethylene production
• CPC Class Codes: Y10S 208/01 Automatic control

Abstract

The operation of fluid catalytic converter (FCC) units can be stabilized through use of tests wherein a first catalyst and a second catalyst are introduced into the FCC unit in at least two different ratios, at two different times, in order to establish the effect of these catalyst ratios on a given operating parameter. This information is used to establish a unit response curve (or unit response envelope) for the catalyst ratios versus the operating parameter. This unit response curve (or envelope) is thereafter used to control the operation of the FCC unit.

Claims

1. A method for controlling operation of a multiple-catalyst-employing FCC unit, said method comprising:

(1) selecting an operating characteristic of the multiple-catalyst-employing FCC unit that is affected by each of at least two different catalyst species;

catalyst A and catalyst B;

(2) injecting an operating characteristic-affecting amount of catalyst A and an operating characteristic-affecting amount of catalyst B into the multiple-catalyst-employing FCC unit in a first catalyst A;

catalyst B test ratio;

(3) determining the effect of the first catalyst A;

catalyst B test ratio on the operating characteristic;

(4) injecting an operating characteristic-affecting amount of catalyst A and an operating characteristic-affecting amount of catalyst B into the multiple-catalyst-employing FCC unit in a second catalyst A;

catalyst B test ratio that is not the same as the first catalyst A;

catalyst B test ratio;

(5) determining the effect of the second catalyst A;

catalyst B test ratio on the operating characteristic;

(6) establishing a unit response curve for the operating characteristic based, at least in part, upon the effect of the first catalyst A;

catalyst B test ratio and the second catalyst A;

catalyst B test ratio on said operating characteristic;

(7) selecting a desired level of the operating characteristic that can be attained by the multiple-catalyst-employing FCC unit by some catalyst A;

catalyst B ratio;

(8) programming a unit response curve in a central processing unit that controls a catalyst addition system associated with the FCC unit; and

(9) injecting at least one of the two catalysts (catalyst A or catalyst B) into the multiple-catalyst-employing FCC unit during subsequent normal operation of said unit in an amount that brings the catalyst A;

catalyst B ratio in the unit to a value that correlates with a point on the unit response curve.

2. The process of claim 1 wherein the at least two different catalyst species are each stored in, and supplied by, a separate catalyst addition system.

3. The process of claim 1 wherein the unit response curve is established through use of three or more injections of three or more different catalyst A:

catalyst B test ratios.

4. The process of claim 1 wherein more than two catalyst species are tested in the FCC unit.

5. The process of claim 1 wherein more than two catalyst species are each stored in, and supplied by, a separate catalyst addition system.

6. The process of claim 1 wherein operating parameter is selected from the group consisting of SO_x emissions, NO_x emissions, CO combustion, gasoline sulfur reduction, olefin product make, olefin product molecular structure, vanadium reduction and CO₂ production.

7. The method of claim 1 wherein the operating parameter is the SO_x emissions level of the FCC unit.

8. The method of claim 1, wherein catalyst A and the second catalyst B are each SO_x removal catalysts.

9. A method for controlling operation of a multiple-catalyst-employing FCC unit, said method comprising:

(1) selecting an operating characteristic of the multiple-catalyst-employing FCC unit that is effected by each of at least two different catalyst species;

catalyst A and catalyst B;

(2) injecting an operating characteristic-affecting amount of catalyst A and an operating characteristic-affecting amount of catalyst B into the multiple-catalyst-employing FCC unit in a first catalyst A;

catalyst B test ratio;

(3) determining the effect of the first catalyst A;

catalyst B test ratio on the operating characteristic;

(4) injecting an operating characteristic-affecting amount of catalyst A and an operating characteristic-affecting amount of catalyst B into the multiple-catalyst-employing FCC unit in a second catalyst A;

catalyst B test ratio that is not the same as the first catalyst A;

catalyst B test ratio;

(5) determining the effect of the second catalyst A;

catalyst B test ratio on the operating characteristic;

(6) establishing a unit response curve for the operating characteristic based, at least in part, upon the effect of the first catalyst A;

catalyst B test ratio and the second catalyst A;

catalyst B test ratio on said operating parameter;

(7) selecting a desired level of the operating characteristic that can be attained by the multiple-catalyst-employing FCC unit by some catalyst A;

catalyst B ratio;

(8) defining an operating envelope for the FCC unit through use of the response curve and a desired level of the operating characteristic;

(9) programming a unit response envelope in a central processing unit that controls a catalyst addition system associated with the FCC unit; and

(10) injecting at least one of the two catalysts into the multiple-catalyst-employing FCC unit during subsequent normal operation of said unit in an amount that brings the catalyst A;

catalyst B ratio in the FCC unit to a value that correlates with a point in the operating envelope.

10. The process of claim 9 wherein the at least two different catalyst species are each stored in, and supplied by, a separate catalyst addition system.

11. The process of claim 9 wherein the response curve is established through use of three or more different injections of three or more different catalyst A:

catalyst B test ratios.

12. The process of claim 9 wherein operating parameter is selected from the group consisting of SO_x emissions, NO_x emissions, CO combustion, gasoline sulfur reduction, olefin product make, olefin product molecular structure, vanadium reduction and CO₂ production.

13. The method of claim 9 wherein the operating parameter is the SO_x emissions level of the FCC unit.

14. The method of claim 9 wherein the catalyst A and the second catalyst B are each SO_x reduction catalysts.