Low compression, resilient golf balls including an inorganic sulfide catalyst and methods for making the same

• US 6,508,968 B1
• Filed: 09/08/2000
• Issued: 01/21/2003
• Est. Priority Date: 12/24/1998
• Status: Expired due to Fees

• Current Assignee: David A. Bulpett, Derek Ladd, Jeffrey L. Dalton, Laurent Bissonnette, Mark M. Wrigley, Murali Rajagopalan, Steven M. Gosetti
• Original Assignee: David A. Bulpett, Derek Ladd, Jeffrey L. Dalton, Laurent Bissonnette, Mark M. Wrigley, Murali Rajagopalan, Steven M. Gosetti
• Inventors: Bulpett, David A., Dalton, Jeffrey L., Bissonnette, Laurent, Rajagopalan, Murali, Ladd, Derek, Gosetti, Steven M., Wrigley, Mark M.
• Primary Examiner(s): Silbaugh, Jan H.
• Assistant Examiner(s): Lee, Edmund H.
• Application Number:
  US09/658,382
• Time in Patent Office: 865 Days
• Field of Search: 264/250, 264/279.1, 264/320, 264/325, 264/319, 264/331.17
• US Class Current: 264/250
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0082 Density; Specific gravity
• CPC Class Codes: C08K 3/30 Sulfur-, selenium- or tellurium-containing compounds
• CPC Class Codes: C08L 9/00 Compositions of homopolymers or copolymers of conjugated diene hydrocarbons

Abstract

A low compression, resilient golf ball having a center and a cover, wherein at least a portion of the ball is formed from the conversion reaction of an amount of polybutadiene, a free radical source, and a cis-to-trans catalyst including at least one inorganic sulfide at a sufficient temperature to form a polybutadiene reaction product which includes an amount of trans-polybutadiene greater than the amount of trans-polybutadiene present before the conversion reaction and a cis-to-trans catalyst including at least one inorganic sulfide. The reaction product preferably has a first dynamic stiffness measured at −50° C. that is less than about 130 percent of a second dynamic stiffness measured at 0° C. A multi-layer golf ball having a center, at least one intermediate layer disposed concentrically about the center, and a cover, wherein at least a portion of at least one of the center, intermediate layer, or both, are made from the reaction product. Also included are methods of forming such golf balls.

Claims

1. A method for forming a golf ball which comprises:

combining (a) a cis-to-trans catalyst comprising at least one inorganic sulfide;

(b) a free radical source; and

(c) a first resilient polymer component comprising a cis-polybutadiene component present in an amount greater than about 70 percent;

converting a portion of the first resilient polymer component to a second resilient polymer component, wherein at least a portion of the cis-polybutadiene component is converted to a trans-polybutadiene component and wherein the polybutadiene in the second resilient polymer component is at least about 10 percent trans-polybutadiene and less than about 7 percent vinyl-polybutadiene; and

forming the second resilient polymer component into at least a portion of the golf ball.

2. The method of claim 1, wherein the portion of the second resilient polymer component is formed into a solid sphere.

3. The method of claim 2, which further comprises forming at least one layer over the solid sphere.

4. The method of claim 1, which further comprises forming the portion of the second resilient polymer component into at least one layer disposed concentrically about a sphere.

5. The method of claim 1, which further comprises forming the portion of the second resilient polymer component into a cover disposed concentrically about a sphere.

6. The method of claim 1, wherein the polybutadiene component comprises a cis-polybutadiene present in an amount of at least about 80 percent of the total first resilient polymer component.

7. The method of claim 1, wherein the combining further comprises a density-modifying filler.

8. The method of claim 1, wherein the steps of combining the first resilient polymer component and the cis-to-trans catalyst and forming the portion, comprises forming a sphere having a midpoint having a first amount of trans-polybutadiene and a surface having a second amount of trans-polybutadiene, wherein the first amount is at least about 6 percent less than the second amount.

9. The method of claim 1, wherein the second amount of trans-polybutadiene component is selected to comprise a vinyl polybutadiene component present in an amount of less than about 4 percent of the total resilient polymer component.

10. The method of claim 1, wherein the inorganic sulfide is selected to comprise at least one metal sulfide.

11. The method of claim 10, wherein the at least one inorganic sulfide is selected to comprise at least one of a titanium sulfide, manganese sulfide, iron sulfide, calcium sulfide, cobalt sulfide, molybdenum sulfide, tungsten sulfide, copper sulfide, selenium sulfide, yttrium sulfide, zinc sulfide, tin sulfide, potassium sulfide, or bismuth sulfide.

12. The method of claim 1, wherein the cis-to-trans catalyst is present in an amount from about 0.1 to 25 parts per hundred of the total resilient polymer component.

13. The method of claim 12, wherein the cis-to-trans catalyst is present in an amount from about 0.1 to 12 parts per hundred of the total resilient polymer component.

14. The method of claim 13, wherein the cis-to-trans catalyst is present in an amount from about 0.1 to 8 parts per hundred of the total resilient polymer component.

15. The method of claim 1, wherein the cis-to-trans catalyst is selected to further comprise at least one of an organosulfur compound, an aromatic organometallic compound, a metal-organosulfur compound, elemental sulfur, a polymeric sulfur, or an aromatic organic compound.

16. The method of claim 10, which further comprises providing an accelerator in an amount sufficient to facilitate cis-to-trans conversion.

17. The method of claim 16, wherein the accelerator is selected to comprise at least one of sulfenamide, thiazole, dithiocarbamate, thiuram, xanthate, thiadiazine, thiourea, guanadine, or aldehyde-amine.

18. The method of claim 16, wherein the accelerator is provided in an amount from about 0.05 to 2 phr of the total resilient polymer component.

19. The method of claim 18, wherein the accelerator is provided in an amount from about 0.1 to 1 phr of the total resilient polymer component.

20. The method of claim 4 wherein a portion of the sphere comprises a fluid.

21. The method of claim 4 wherein a tensioned elastomeric material is wound about the sphere.

22. The method of claim 21, wherein the tensioned elastomeric material comprises the reaction product.

23. The method of claim 1, wherein the forming comprises:

single- or multi-step compression molding of the first resilient polymer component to convert the first resilient polymer component to the second resilient polymer; and

forming the second resilient polymer component into a solid sphere.

24. The method of claim 23, wherein the converting and forming are substantially simultaneous.

25. A method for forming a golf ball which comprises:

combining (a) a cis-to-trans catalyst comprising at least one inorganic sulfur;

(b) a free radical source; and

(c) a first resilient polymer component comprising a cis-polybutadiene component present in an amount greater than about 70 percent of the polymer component;

converting a portion of the first resilient polymer component to a second resilient polymer component at a time and a temperature sufficient to convert at least a portion of the cis-polybutadiene component to a trans-polybutadiene component and wherein the polybutadiene in the second resilient polymer component is at least about 10 percent trans-polybutadiene and less than about 7 percent vinyl-polybutadiene; and

forming the second resilient polymer component into at least a portion of the golf ball, wherein the second resilient component has a first dynamic stiffness measured at −

50°

C. that is less than about 130 percent of a second dynamic stiffness measured at 0°

C.