Process for producing ethanol

• US 6,509,180 B1
• Filed: 12/29/2000
• Issued: 01/21/2003
• Est. Priority Date: 03/11/1999
• Status: Expired due to Term

• Current Assignee: ZeaChem, Inc.
• Original Assignee: ZeaChem, Inc.
• Inventors: Verser, Dan, Eggeman, Tim
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US09/720,930
• Time in Patent Office: 753 Days
• Field of Search: 435/161, 435/140, 435/139, 435/162, 568/885
• US Class Current: 435/161
• CPC Class Codes: C07C 29/149 with hydrogen or hydrogen-containing gases
• CPC Class Codes: C07C 31/08 Ethanol
• CPC Class Codes: C07C 67/08 by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
• CPC Class Codes: C07C 69/14 of monohydroxylic compounds
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: C12P 7/14 Multiple stages of fermentation; Multiple types of microorganisms or re-use of microorganisms
• CPC Class Codes: C12P 7/54 Acetic acid vinegar C12J
• CPC Class Codes: C12P 7/56 Lactic acid
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

A process for producing ethanol including a combination of biochemical and synthetic conversions results in high yield ethanol production with concurrent production of high value coproducts. An acetic acid intermediate is produced from carbohydrates, such as com, using enzymatic milling and fermentation steps, followed by conversion of the acetic acid into ethanol using esterification and hydrogenation reactions. Coproducts can include corn oil, and high protein animal feed containing the biomass produced in the fermentation.

Claims

1. A method to produce ethanol at very high yield, said method comprising:

(a) culturing a homoacetogens microorganism in a medium comprising a carbohydrate source to produce acetate, acetic acid or mixture thereof; and

(b) chemically converting said acetate, acetic acid or mixtures thereof to said ethanol;

wherein said step of chemically converting is not a fermentation; and

wherein at least about 70% of arbon in said carbohydrate source is converted into said etaol.

2. The Method of claim 1, wherein said bomoacetic fermentation is accomplished by a microorganism of the genus Clostridium.

3. The method of claim 1, wherein at least about 80% of carbon in said carbohydrate source is converted into said ethanol.

4. The method of claim 1, wherein at least about 90% of carbon in said carbohydrate source is converted into said ethanol.

5. The method of claim 1, wherein essentially none of the carbon in said carbohydrate source is evolved as carbon dioxide.

6. The method of claim 1, wherein the only substantial amount of carbon dioxide produced in the process is during the formation of hydrogen by steam reforming of natural gas.

7. The method of claim 1, wherein said medium comprises less than about 20% nitrogen.

8. The method of claim 1, wherein said step of fermenting further yields a biomass byproduct which is useful as an animal feed.

9. The method of claim 1, wherein said step of fermenting further yields at least about 10% by weight biomass byproduct.

10. The method of claim 1, wherein said carbohydrate source is selected from the group consisting of corn, wheat, biomass, wood, waste paper, manure, cheese whey, molasses, sugar beets and sugar cane.

11. The method of claim 10, wherein said corn is ground to produce ground corn and corn oil prior to said step of fermenting.

12. The method of claim 11, wherein said corn oil is recovered.

13. The method of claim 10, wherein said corn is enzymatically hydrolyzed prior to said step of fermenting.

14. The method of claim 11, wherein said corn is enzymatically hydrolyzed to sugars and amino acids prior to said step of fermenting.

15. The method of claim 1, wherein said step of fermenting is a homoacetic fermentation is accomplished by a microorganism of the species Clostridium thermoaceticum or Clostridium formicoaceticum.