Method and apparatus for detecting gases

• US 6,509,567 B2
• Filed: 05/30/2001
• Issued: 01/21/2003
• Est. Priority Date: 05/30/2000
• Status: Expired due to Fees

• Current Assignee: Gaz de France, Oldham France SA
• Original Assignee: Gaz de France, Oldham France SA
• Inventors: Gamarts, Emelian, Krylov, Vladimir, Fantini, Jérôme, Boudet, Thierry
• Primary Examiner(s): Hannaher, Constantine
• Assistant Examiner(s): Moran, Timothy J.
• Application Number:
  US09/866,872
• Publication Number:
  US 20020050567A1
• Time in Patent Office: 601 Days
• Field of Search: 250/343, 250/344, 250/345, 250/346, 250/575, 356/436, 356/437
• US Class Current: 250/345
• CPC Class Codes: G01M 3/002 by using thermal means
• CPC Class Codes: G01M 3/38 by using light G01M3/02 takes precedence
• CPC Class Codes: G01M 3/40 by using electric means, e.g. by observing electric discharges
• CPC Class Codes: G01N 21/314 with comparison of measurements at specific and non-specific wavelengths dual wavelength spectrometry G01J3/427
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis

Abstract

The apparatus for detecting the presence of a particular gas within a mixture of gases comprises first and second emitter means for emitting measurement and reference electromagnetic radiation beams respectively, which beams are activated in alternation, a measurement cell, a filter cell, first and second detector means for detecting electromagnetic radiation beams, a beam splitter, and acquisition and processing means for synchronously acquiring and processing the four signals U_S¹, U_S², U_R¹, U_R² delivered by the first and second detector means in succession when the first and second emitter means are respectively activated so as to determine the absolute concentration of the gas to be detected on the basis of the ratio R=(U_S¹×U_R²)/(U_S²×U_R¹) between the four signals, in which U_S¹ and U_S² respectively represent the signals delivered by the first and second detector means when the first emitter means is activated, and U_R¹ and U_R² respectively represent the signals delivered by the first and second detector means when the second emitter means is activated.

Claims

1. Portable apparatus for detecting gas by selective absorption of electromagnetic radiation to detect the presence of a particular gas in a gas mixture, the apparatus comprising:

a) first emitter means for emitting a measurement infrared electromagnetic radiation beam in a wavelength band containing a wavelength at which the gas to be detected presents an absorption characteristic;

b) second emitter means for emitting a reference infrared electromagnetic radiation beam, said first and second emitter means being activated in alternation;

c) a measurement cell containing the gas mixture to be analyzed, which measurement cell has an inlet section and an outlet section and receives at least a fraction of the measurement beam through its inlet section;

d) a filter cell containing a sample of the gas to be detected and having an inlet section and an outlet section, through which sections at least a fraction of the reference beam passes in succession;

e) first detector means for detecting electromagnetic radiation beams;

f) second detector means for detecting electromagnetic radiation beams;

g) a beam splitter disposed in such a manner as to split firstly the measurement beam and secondly the reference beam so as to transmit a first fraction of each of the measurement and reference beams to said first detector means, and a second fraction of each of the measurement and reference beams to the second detector means; and

h) processing and acquisition means for synchronously acquiring and processing the four signals U_S¹, U_S², U_R¹, U_R² delivered by the first and second detector means in succession when the first and second emitter means are respectively activated in order to determine the absolute concentration of the gas to be detected on the basis of the ratio R=(U_S¹×

U_R²)/(U_S<sup>2×

U</sup>_R¹) between said four signals where U_S¹ and U_S² respectively represent the signals delivered by the first and second detector means when the first emitter means is activated, and where U_R¹ and U_R² respectively represent the signals delivered by the first and second detector means when the second emitter means is activated.

2. The apparatus of claim 1, wherein the filter cell containing a sample of gas to be detected has inlet and outlet sections through which the entire reference beam passes in succession, wherein the beam splitter is placed in such a manner as to transmit the first fraction of each of the measurement and reference beams to said first detector means through the inlet and outlet sections of the measurement cell, and wherein the second detector means is placed in such a manner as to receive the second fraction of the measurement and reference beams directly, the beam splitter being arranged in such a manner as to receive the reference beam after it has passed through the outlet section of the filter cell.

3. Apparatus of claim 1, wherein the measurement cell containing the mixture of gases to be analyzed comprises an inlet section and an outlet section through which the entire measurement beam passes in succession, wherein the beam splitter is placed in such a manner as to transmit the first fraction of each of the measurement and reference beams directly to said first detector means, and wherein the second detector means is placed in such a manner as to receive the second fractions of the measurement and reference beams via the inlet and outlet sections of the filter cell, the beam splitter being arranged in such a manner as to receive the measurement beam after it has passed through the outlet section of the measurement cell.

4. Apparatus according to claim 1, further comprising means for measuring the temperature of the medium in which the component elements of the apparatus are placed, and wherein the signals delivered by said temperature measuring means are applied to said processing means.

5. Apparatus according to claim 1, wherein the first and second emitter means comprise light emitting diodes.

6. Apparatus according to claim 1, wherein the first and second emitter means comprise laser diodes or solid lasers.

7. Apparatus according to claim 1, including modulator means associated with the emitter means, which modulator means are synchronized in such a manner that the first and second emitter means emit radiation in turns.

8. Apparatus according to claim 1, including filter means associated with the emitter means.

9. Apparatus according to claim 1, wherein the beam splitter comprises a semitransparent plate for transmitting a fraction of the electromagnetic radiation, and for reflecting a fraction thereof.

10. Apparatus according to claim 1, wherein the inlet and outlet sections of the measurement cell are situated on the same side of said measurement cell.

11. Apparatus according to claim 1, wherein the inlet and outlet sections of the measurement cell are situated on opposite sides of said measurement cell.

12. Apparatus according to claim 1, wherein the inlet and outlet sections of the filter cell are situated on opposite faces of the filter cell.

13. Apparatus according to claim 1, wherein the gas to be detected is methane.

14. Apparatus according to claim 1, wherein the first and second emitter means for emitting electromagnetic radiation beams present similar emission spectra.

15. Apparatus according to claim 1, wherein the first and second emitter means for emitting electromagnetic radiation beams present different emission spectra.

16. A method of detecting a gas by selective absorption of electromagnetic radiation to detect the presence of a particular gas within a mixture of gases, the method comprising the following steps:

a) emitting a measurement infrared electromagnetic radiation beam in a wavelength band containing a wavelength at which the gas to be detected presents an absorption characteristic;

b) emitting a reference infrared electromagnetic radiation beam;

c) modulating the emission of the measurement and reference beams in synchronized manner such that pulses of the measurement beam alternate in time with pulses of the reference beam;

d) causing at least a fraction of the measurement beam to pass through a measurement cell containing the mixture of gases;

e) causing at least a fraction of the reference beam to pass through a filter cell containing a sample of the gas to be detected;

f) separating the reference beam and the measurement beam into first and second fractions;

g) measuring the energies of the first fractions of the measurement and reference beams;

h) measuring the energies of the second fractions of the measurement and reference beams; and

i) determining the absolute concentration of the gas to be detected by using the four signals U_S¹, U_S², U_R¹, U_R² representing the energy measured in the first and second fractions of the measurement and reference beams as delivered in succession when the pulses of the measurement and reference beams are emitted respectively, using the ratio R=(U_S¹×

U_R²)/(U_S²×

U_R¹) between said four signals in which U_S¹ and U_S² respectively represent the energy measurement signals of the first and second fractions of the measurement and reference beams when the pulses of the measurement beam are emitted, and U_R¹ and U_R² respectively represent the energy measurement signals of the first and second fractions of the measurement and reference beams when the pulses of the reference beam are emitted.

17. A method according to claim 16, wherein the temperature of the medium in which the measurement and reference beams propagate is measured and the value determined for the absolute concentration of the gas to be detected is corrected as a function of the measured temperature.

18. A method according to claim 16, wherein the gas to be detected is methane.

19. A method according to claim 16, wherein the entire reference beam is passed through the filter cell containing a sample of the gas to be detected, wherein said splitting is performed on the measurement beam and on the reference beam after it has passed through the filter cell, and wherein the energies of the first fractions of the measurement and reference beams are measured after said first fractions have passed through the measurement cell containing the mixture of gases.

20. A method according to claim 16, wherein the entire measurement beam is passed through the measurement cell containing the mixture of gases, wherein said beam splitting is performed on the reference beam and on the measurement beam after it has passed through the measurement cell, and wherein the energies of the second fractions of the measurement and reference beams are measured after these second fractions have passed through the filter cell containing a sample of the gas to be detected.