Anisotropic melt-forming polymers having a high degree of stretchability

• US 6,514,611 B1
• Filed: 08/21/2001
• Issued: 02/04/2003
• Est. Priority Date: 08/21/2001
• Status: Expired due to Term

• Current Assignee: Ticona LLC (Celanese Corporation)
• Original Assignee: Ticona LLC (Celanese Corporation)
• Inventors: Linstid, H. Clay III, Shepherd, James P., Provino, Vincent J.
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US09/933,645
• Time in Patent Office: 532 Days
• Field of Search: 428/36.6, 428/36.7, 428/373, 428/480, 428/483, 528/176, 528/190, 528/194, 528/195, 528/298, 528/302, 528/308, 528/308.6
• US Class Current: 428/373
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: C08G 63/605 the hydroxy and carboxylic groups being bound to aromatic rings
• CPC Class Codes: Y10T 428/2929 Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

Highly stretchable, anisotropic melt-forming polymers consisting essentially of recurring units derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, isophthalic acid, terephthalic acid and hydroquinone are disclosed.

Claims

1. An anisotropic melt-forming polymer consisting essentially of recurring units I, II, III, IV, and V wherein recurring unit I is:

recurring unit II is;

recurring unit III is;

recurring unit IV is;

and recurring unit V is;

 

wherein recurring unit I is present in the polymer in an amount of from about 20 to about 40 mole percent, recurring unit II is present in the polymer in an amount of from about 25 to about 50 mole percent, recurring unit III is present in the polymer in an amount of from about 7.5 to about 25 mole percent, recurring unit IV is present in the polymer in an amount of from about 2.5 to about 12.5 mole percent, and recurring unit V is present in the polymer in an amount of from about 10 to about 27.5 mole percent and wherein recurring units I and II combined are present in the polymer in an amount of from about 45 to about 75 mole percent, and the mole ratio of recurring unit III to recurring unit is at least about 1.

2. A polymer as described in claim 1 wherein the mole ratio of recurring unit III to recurring unit IV is from about 1:

1 to about 10;

1.

3. A polymer as described in claim 2 wherein recurring unit I is present in the polymer an amount of from about 30 to about 40 mole percent.

4. A polymer as described in claim 3 wherein recurring unit V is present in the polymer in amount of from about 15 to about 25 mole percent.

5. A polymer as described in claim 4 wherein recurring units I and II combined are present in the polymer in an amount of from about 55 to about 70 mole percent.

6. A polymer as described in claim 5 wherein recurring unit III is present in the polymer in an amount of from about 7.5 to about 20 mole percent.

7. A polymer as described in claim 1 wherein no ring substitution is present on any of the recurring units.

8. A shaped article formed from the polymer of claim 1.

9. A shaped article as described in claim 8 selected from the group consisting of fiber, film, sheet and blow molded articles.

10. A multilayer laminate comprising a layer formed from the polymer of claim 1 and at least one layer formed from a thermoplastic resin.

11. A multilayer laminate as described in claim 10 wherein said thermoplastic resin comprises a thermoplastic polymer selected from the group consisting of polyolefins and polyalkylene terephthalates.

12. A multilayer laminate as described in claim 11 which further comprises at least one adhesive layer located between the layer comprised of the polymer of claim 1 and the layer comprised of said thermoplastic resin.

13. A fiber formed from the polymer of claim 1.

14. A fiber as described in claim 13 which is a bicomponent fiber.

15. A multilayer shaped article wherein the polymer of claim 1 is present as a barrier layer.

16. A highly stretchable, amorphous anisotropic melt-forming polymer consisting essentially of recurring units I, II, III, IV, and V wherein recurring unit I is:

recurring unit II is;

recurring unit III is;

recurring unit IV is;

and recurring unit V is;

 

wherein recurring unit I is present in the polymer in an amount of from about 30 to about 40 mole percent, recurring unit II is present in the polymer in an amount of from about 25 to about 40 mole percent, recurring unit III is present in the polymer in an amount of from about 7.5 to about 20 mole percent, recurring unit IV is present in the polymer in an amount of from about 2.5 to about 10 mole percent, and recurring unit V is present in the polymer in an amount of from about 15 to about 25 mole percent and wherein recurring units I and II combined are present in the polymer in an amount of from about 55 to about 70 mole percent, and the mole ratio of recurring unit III to recurring unit IV is from about 1;

1 to about 10;

1.