Method of producing a coal combustion ash composition

• US 6,517,631 B2
• Filed: 12/28/2001
• Issued: 02/11/2003
• Est. Priority Date: 07/20/1998
• Status: Expired due to Term

• Current Assignee: Alan Bland
• Original Assignee: The University of Wyoming Research Corporation
• Inventors: Bland, Alan E.
• Primary Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US10/034,361
• Publication Number:
  US 20020144631A1
• Time in Patent Office: 410 Days
• Field of Search: 106/705, 106/DIG.1, 264/DIG.49
• US Class Current: 106/705
• CPC Class Codes: C04B 18/021 agglomerated by a mineral binder, e.g. cement
• CPC Class Codes: C04B 18/06 Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
• CPC Class Codes: C04B 18/061 Ashes from fluidised bed furnaces
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 18/106 Fly ash from waste incinerators
• CPC Class Codes: C04B 20/023 Chemical treatment
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete
• CPC Class Codes: Y10S 106/01 Fly ash
• CPC Class Codes: Y10S 264/49 Processes of using fly ash

Abstract

This invention discloses a system for cold bond processing of combustion ash which enhances various characteristics of the resulting cured consolidated combustion ash materials. Specifically, the invention relates to processing techniques which enhances both density and strength of the of the consolidated combustion ash materials. The invention also relates to processing techniques which control various chemical reactions which assure that certain types of minerals are formed in the proper amounts which results in a cured consolidated combustion ash material which has greater dimensional stability and enhanced resistance to degradation. Embodiments for both normal weight and light weight combustion ash aggregates are disclosed which meet various ASTM and AASHTO specifications.

Claims

1. A method of generating a combustion ash composition, comprising the steps of:

a. providing an amount of combustion ash;

b. providing an amount of water having a weight of about 10% to about 40% relative to the weight of said combustion ash;

c. mixing said amount of combustion ash and said amount of water; and

d. reducing the average pore volume of the generated combustion ash composition to between about 15% to about 40%.

2. A method of generating a combustion ash composition as described in claim 1, wherein said combustion ash is selected from the group consisting of fluidized bed combustion ash, pressurized fluidized combustion ash, Class C ash, off specification Class C ash, Class F ash, off specification Class F ash, CFBC ash, spray drier ash, sorbent injection ashes, and incinerator ash.

3. A method of generating a combustion ash composition as described in claim 2, which further comprises the step of adding an amount of strength additive to said combustion ash.

4. A method of generating a combustion ash composition as described in claim 2, wherein said combustion ash comprises Class F, and wherein said strength additive is selected from the group consisting of Portland Cement, Class C ash, lime, and self cementing ash.

5. A method of generating a combustion ash composition as described in claim 2, wherein said combustion ash comprises Class PFBC, and wherein said strength additive is selected from the group consisting of Portland Cement, Class C ash, lime, and self cementing ash, soluble silicates, and soluble aluminates.

6. A method of generating a combustion ash composition as described in claim 1, further comprising the step of adding an amount of pore filling controlling compound selected from the group consisting of soluble carbonate, carbon dioxide gas, sodium carbonate, potassium carbonate, magnesium hydroxide, trona, and carbonic acid.

7. A method of generating a combustion ash composition as described in claim 1, wherein said step of providing an amount of water having a weight of about 10% to about 40% relative to the weight of said combustion ash, comprises the steps of:

a. providing an amount of water sufficient to reduce the amount of hydratable oxide contained in said combustion ash to less than five weight percent; and

b. adding a second amount of water sufficient to reduce said less than about five weight percent of said hydratable oxide to substantially zero hydratable oxide.

8. A method of generating a combustion ash composition as described in claim 1, wherein said step of providing an amount of water comprises the step of providing an amount of waste water selected from the group consisting of coal pile runoff, cooling tower blow down, paper mill effluent, industrial waste waters and seawater.

9. A method of generating a combustion ash composition as described in claim 1, which further comprises the step of establishing a linear expansion selected from the group consisting of less than about 0.100 percent in a saturated bath, less than about 0.050 percent in a saturated bath, and less than about 0.010 percent in a saturated bath.

10. A method of generating a combustion ash composition as described in claim 1, which further comprise the steps of:

a. generating a cured combustion ash composition; and

b. sizing said cured combustion ash composition to meet specifications selected from the group consisting of ASTM specifications and AASHTO specifications.

11. A product produced in accordance with the process of any one of claims 1, 3, 5, 6, 7, 9, or 10.

12. A product produced in accordance with the process of claim 11, and further comprising the step of selecting the amount and type of said combustion ash, said water, said pore filling controlling compound, and said precursor pore filling compound to result in a product which meets specifications selected from the group consisting of ASTM specifications or AASHTO specifications.

13. A method of generating a combustion ash composition, comprising the steps of:

a. providing an amount of combustion ash;

b. providing an amount of water;

c. providing an amount of pore filling controlling compound;

d. combining said amount of water, said amount of combustion ash, and said amount of pore filling controlling compound;

e. forming an amount of non-pore filling compound by reaction of said pore filling controlling compound with at least a portion of precursor pore filling compound present in said amount of combustion ash; and

f. generating a combustion ash composition.

14. A method of generating a combustion ash composition as described in claim 13, wherein said step of providing an amount of a combustion ash comprises providing said combustion ash from the group consisting of fluidized bed combustion ash, pressurized fluidized bed combustion ash, Class C ash, and off specification Class C ash.

15. A method of generating a combustion ash composition as described in claim 13, which further comprises the step of adding an amount of strength additive to said combustion ash.

16. A method of generating a combustion ash composition as described in claim 13, which further comprises the step of achieving a cured combustion ash composition having unconfined compressive strength of at least 1000 pounds per square inch.

17. A method of generating a combustion ash composition as described in claim 15, wherein said step of providing an amount of combustion ash comprises selecting said combustion ash from the group consisting of PFBC ash, Class F ash, off specification Class F ash, off specification Class C ash, and incinerator ash.

18. A method of generating a combustion ash composition as described in claim 13, which further comprises the step of adjusting water-combustion ash solids ratio to between about 0.1 to about 0.4.

19. A method of generating a combustion ash composition as described in claim 18, wherein said step of adjusting the water-combustion ash solids ratio comprises adjusting said water-combustion ash solids ratio to achieve a density of said cured combustion ash composition of greater than 90 pounds per cubic foot.

20. A method of generating a combustion ash composition as described in claim 18, wherein said step of adjusting the water-combustion ash solids ratio comprises adjusting said water-combustion ash solids ratio to achieve a density of said cured combustion ash composition to a density of between about 60 pounds per cubic foot to about 90 pounds per cubic foot.

21. A method of generating a combustion ash composition as described in claim 13, wherein said step of providing an amount of water comprises providing an amount of water sufficient to reduce hydratable oxide contained in said amount of combustion ash to less than five weight percent, and further comprising the step of adding a second amount of water to said combustion ash composition sufficient to reduce said less than five weight percent hydratable oxide to substantially zero hydratable oxide.

22. A method of generating a combustion ash composition as described in claim 21, wherein said step of providing an amount of combustion ash comprises selecting said combustion ash from the group consisting of fluidized bed combustion ash, pressurized fluidized bed combustion ash, Class F ash, off specification Class F ash, spray drier ash, sorbent injection ashes, incinerator ash.

23. A method of generating a combustion ash composition as described in claim 21, which further comprises the steps of:

a. selecting a set retardant;

b. determining an amount of set retardant; and

c. adding said amount of set retardant to said amount of combustion ash.

24. A method of generating a combustion ash composition as described in claim 13, wherein said step of selecting a retardant comprises selecting sodium borate in an amount between about one percent to about two percent by weight.

25. A method of generating a combustion ash composition as described in claim 23, which further comprises the step of adding a lightweight filler.

26. A method of generating a combustion ash composition as described in claim 25, wherein said step of providing an amount of combustion ash comprises selecting said combustion ash from the group consisting of fluidized bed combustion ash, pressurized fluidized bed combustion ash, Class C ash, off specification Class C ash, off specification Class F ash, Spray drier ash, sorbent injection ashes, or incinerator ash.

27. A method of generating a combustion ash composition as described in claim 13, wherein said step of providing an amount of water comprises providing an amount of waste water selected from the group consisting of cooling tower blow down, coal pile runoff, cooling tower blow down, paper mill effluent, industrial waste waters or seawater.

28. A method of generating a combustion ash composition as described in claim 13, wherein said step of providing an amount of a pore filling controlling compound comprises providing an amount of pore filling controlling compound to generate an amount of said pore filling compound insufficient to fill the average pore volume of said cured combustion ash composition.

29. A method of generating a combustion ash composition as described in claim 13, wherein said step of providing an amount of a pore filling controlling compound comprises providing an amount of pore filling controlling compound to generate an amount of pore filling compound sufficient to fill the average pore volume, and wherein said amount of pore filling compound sufficient to fill the average pore volume damages the surrounding cured combustion ash composition.

30. A method of generating a combustion ash composition as described in claim 13, further comprising the step of consolidating said combustion ash composition using an ASTM 698 compactive effort to generate a density substantially equivalent to using an ASTM 1557 compactive effort.

31. A method of generating a combustion ash composition as described in claim 13, which further comprises the step of mixing at least two types of combustion ash.

32. A method of generating a combustion ash composition as described in any one of claims 13, 15, 21, 23, or 25 further comprising the step of sizing cured consolidated combustion ash composition to meet ASTM specifications.

33. A method of generating a combustion ash composition as described in any one of claims 13, 15, 21, 23, or 25, wherein said step of sizing said cured consolidated combustion ash composition comprises meeting specifications selected from the group consisting of ASTM specifications or AASHTO specifications.

34. A composition produced in accordance with the process of any one of claims 13, 15, 21, 23, or 25.

35. A product produced from cured consolidated combustion ash composition made in accordance with the process of any one of claims 13, 15, 21, 23, or 25.