Process for producing energy, feed material and fertilizer products from manure

• US 6,521,129 B1
• Filed: 08/24/2001
• Issued: 02/18/2003
• Est. Priority Date: 08/24/2001
• Status: Expired due to Fees

• Current Assignee: Ken Stamper, Richard Skinner
• Original Assignee: Ken Stamper, Richard Skinner
• Inventors: Skinner, Richard, Stamper, Ken
• Primary Examiner(s): PRINCE, FRED G
• Application Number:
  US09/938,905
• Publication Number:
  US 20030038078A1
• Time in Patent Office: 543 Days
• Field of Search: 210/603, 210/609, 210/612, 210/613, 210/631, 435/262, 435/262.5, 71/21, 481/273, 481/275
• US Class Current: 210/603
• CPC Class Codes: C02F 11/04 Anaerobic treatment; Production of methane by such processes
• CPC Class Codes: C02F 3/286 including two or more steps
• CPC Class Codes: C05F 17/40 Treatment of liquids or slurries
• CPC Class Codes: C05F 3/00 Fertilisers from human or animal excrements, e.g. manure
• CPC Class Codes: Y02A 40/20 Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin
• CPC Class Codes: Y02W 30/40 Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

A process for treating manure using anaerobic digestion includes introducing manure into a mixing vessel containing a digester liquid and agitating and filtering a slurry formed therefrom to remove substantially all water insoluble solids, thereby leaving a liquid containing ammonia and reactive organic materials. The liquid is then heated and ammonia is removed therefrom to produce a substantially ammonia-free liquid containing reactive organic materials, which is cooled and placed in a digester containing anaerobic bacteria to convert the reactive organic materials in the liquid to biogas and to produce a digester liquid. The biogas is withdrawn and utilized to generate electricity, and a small amount of the digester liquid is withdrawn from the digester and recycled back to the mixing vessel. The water insoluble solids and ammonia removed during the process may be converted to ruminant animal feed and concentrated liquid fertilizer, respectively.

Claims

1. A process for treating manure using anaerobic digestion, comprising the steps of:

providing manure having a mineral content;

introducing the manure into a mixing vessel containing a digester liquid which is substantially free of digestible organic materials and contains a mineral content;

agitating the manure and digester liquid in the mixing vessel for an effective amount of time to produce a pumpable slurry;

withdrawing the pumpable slurry from the mixing vessel;

filtering the pumpable slurry to remove substantially all water insoluble solids therefrom and provide a resultant liquid containing ammonia and reactive organic materials;

heating the resultant liquid to a temperature in the range of from about 150°

F. to about 230°

F. for an effective amount of time to break chemical bonds and destroy active bacteria present in the resultant liquid;

removing ammonia from the heated resultant liquid to produce a substantially ammonia-free liquid containing reactive organic materials;

cooling the substantially ammonia-free liquid containing reactive organic materials to a temperature in the range of from about 70°

F. to about 140°

F. to provide a cooled liquid stream containing reactive organic materials; and

passing the cooled liquid stream to a digester containing anaerobic bacteria to convert the reactive organic materials in the cooled liquid stream to biogas, thereby producing a digester liquid substantially free of digestible organic materials;

withdrawing the biogas from the digester; and

withdrawing an effective amount of the digester liquid from the digester and recycling the withdrawn digester liquid to the mixing vessel for mixing with manure.

2. The process of claim 1 wherein, in the step of passing the cooled liquid stream to the digester, the ammonia concentration in the digester is maintained at a level below about 1500 ppm to prevent inhibition of the anaerobic bacteria.

3. The process of claim 1 wherein the step of removing ammonia from the heated resultant liquid is further defined as passing the heated resultant liquid through a separator through which steam is passed such that the ammonia present in the heated resultant liquid is absorbed by the steam.

4. The process of claim 3 wherein the method further comprises passing the steam containing the ammonia to a second separator containing a dilute acid, wherein the ammonia is reacted with the dilute acid to produce an ammonia salt which may be utilized as a fertilizer.

5. The process of claim 1 wherein, in the step of passing the cooled liquid stream to the digester, the biogas comprises methane and carbon dioxide.

6. The process of claim 1 wherein, in the step of filtering the pumpable slurry to remove substantially all water insoluble solids therefrom, the water insoluble solids are collected and converted to at least one of ruminant animal feed, a feed stock for production of chemicals, and a fuel source to satisfy energy and process heat requirements.

7. The process of claim 1 wherein, in the step of providing a manure, the manure is poultry manure.

8. The process of claim 7 wherein the poultry manure is caged layer manure.

9. The process of claim 1 wherein such process is conducted at a facility in proximity to a facility at which the manure is produced.

10. The process of claim 1 wherein the process is continuous.

11. The process of claim 1 wherein the step of withdrawing the biogas from the digester further includes utilizing the biogas for generating electricity.

12. The process of claim 1 wherein the step of withdrawing the biogas from the digester further includes collecting the biogas.

13. A process for treating poultry manure using anaerobic digestion, comprising the steps of:

providing poultry manure having a mineral content;

introducing the manure into a mixing vessel containing a digester liquid which is substantially free of digestible organic materials and contains a mineral content;

agitating the manure and digester liquid in the mixing vessel for an effective amount of time to produce a pumpable slurry;

withdrawing the pumpable slurry from the mixing vessel;

filtering the pumpable slurry to remove substantially all water insoluble solids therefrom and provide a resultant liquid containing ammonia and reactive organic materials;

heating the resultant liquid to a temperature in the range of from about 150°

F. to about 230°

F. for an effective amount of time to break chemical bonds and destroy active bacteria present in the resultant liquid;

removing ammonia from the heated resultant liquid to produce a substantially ammonia-free liquid containing reactive organic materials;

recovering the ammonia removed from the heated resultant liquid such that the ammonia may be utilized as a fertilizer;

cooling the substantially ammonia-free liquid containing reactive organic materials to a temperature in the range of from about 70°

F. to about 140°

F. to provide a cooled liquid stream containing reactive organic materials; and

passing the cooled liquid stream to a digester containing anaerobic bacteria to convert the reactive organic materials in the cooled liquid stream to biogas, thereby producing a digester liquid substantially free of digestible organic materials, wherein the ammonia concentration in the digester is maintained at a level below about 1500 ppm to prevent inhibition of the anaerobic bacteria;

withdrawing the biogas from the digester and collecting the biogas for utilizing to generate electricity; and

withdrawing an effective amount of the digester liquid from the digester and recycling the withdrawn digester liquid to the mixing vessel for mixing with manure.

14. The process of claim 13 wherein the poultry manure is caged layer manure.

15. The process of claim 13 wherein such process is conducted at a facility in proximity to a facility at which the manure is produced.

16. The process of claim 13 wherein the process is continuous.

17. A process for treating poultry manure using anaerobic digestion, comprising the steps of:

providing poultry manure having a mineral content;

introducing the manure into a mixing vessel containing a digester liquid which is substantially free of digestible organic materials and contains a mineral content;

agitating the manure and digester liquid in the mixing vessel for an effective amount of time to produce a pumpable slurry;

withdrawing the pumpable slurry from the mixing vessel;

filtering the pumpable slurry to remove substantially all water insoluble solids therefrom and provide a resultant liquid containing ammonia and reactive organic materials;

recovering the substantially water insoluble solids;

heating the resultant liquid to a temperature in the range of from about 150°

F. to about 230°

F. for an effective amount of time to break chemical bonds and destroy active bacteria present in the resultant liquid;

removing ammonia from the heated resultant liquid to produce a substantially ammonia-free liquid containing reactive organic materials;

recovering the ammonia removed from the heated resultant liquid in the form of an ammonia salt, an ammonia/water blend or anhydrous ammonia wherein the ammonia salt, ammonia/water blend or anhydrous ammonia may be utilized as a fertilizer;

cooling the substantially ammonia-free liquid containing reactive organic materials to a temperature in the range of from about 70°

F. to about 140°

F. to provide a cooled liquid stream containing reactive organic materials; and

passing the cooled liquid stream to a digester containing anaerobic bacteria to convert the reactive organic materials in the cooled liquid stream to biogas, thereby producing a digester liquid substantially free of digestible organic materials, wherein the ammonia concentration in the digester is maintained at a level below about 1500 ppm to prevent inhibition of the anaerobic bacteria;

withdrawing the biogas from the digester and collecting the biogas for utilizing to generate electricity; and

withdrawing an effective amount of the digester liquid from the digester and recycling the withdrawn digester liquid to the mixing vessel for mixing with manure.

18. The process of claim 17 wherein the poultry manure is caged layer manure.

19. The process of claim 17 wherein such process is conducted at a facility in proximity to a facility at which the manure is produced.

20. The process of claim 17 wherein the process is continuous.