Method and apparatus for manufacturing fiber-reinforced, foamed paperlike products

• US 6,521,147 B1
• Filed: 12/02/1999
• Issued: 02/18/2003
• Est. Priority Date: 09/27/1996
• Status: Expired due to Term

• Current Assignee: Vertis BV (Sopra Steria Group SA)
• Original Assignee: Vertis B. V.
• Inventors: Arentsen, Jan Hendrik Adolf, Huisman, Jan Wietze
• Primary Examiner(s): Kuhns, Allan R.
• Application Number:
  US09/269,318
• Time in Patent Office: 1,174 Days
• Field of Search: 264/51, 264/53, 264/328.18, 264/45.3, 264/55, 264/211.11
• US Class Current: 264/45.3
• CPC Class Codes: B29C 44/3402 Details of processes or apparatus for reducing environmental damage or for working-up compositions comprising inert blowing agents or biodegradable components
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 3/02 Starch; Degradation products thereof, e.g. dextrin

Abstract

A method for manufacturing products with a blown foamy structure, starting from a mass comprising at least natural polymers such as starch and fibers, in particular natural fibers, wherein the mass (M, S) is passed under pressure into or through a mould (23, 63) and the mass (M, S) is heated in the mould (23, 63) in a manner such as to give rise to gelatinization and cross-linking of the natural polymers, with the fibers extending through the product, while the mass prior to the introduction into the mould has temperature which is below the gelatinization temperature and in the mould is brought at least to the baking temperature.

Claims

1. A method of manufacturing a molded product having a blown, foamy structure via an injection mold designed to form said molded product, said method comprising:

forming a fluid mass substantially free of gelatinized matter and having a low viscosity, said fluid mass comprising a natural polymer and natural fibers;

maintaining said fluid mass at temperatures below a gelatinization temperature such that substantially no gelatinization of said natural polymers occurs in said fluid mass outside said injection mold;

injecting said fluid mass under high pressure into said injection mold such that said fluid mass substantially fills said injection mold under said high pressure;

heating said injection mold to raise the temperature of said fluid mass, while under said high pressure, to a baking temperature at least equal to or above said gelatinization temperature, to cause baking of said injected fluid mass with gelatinization and cross linking of said natural polymers, and with bonding of said natural polymers to said natural fibers to form said molded product with said natural fibers extending throughout said molded product; and

removing said molded product from said injection mold.

2. A method according to claim 1, wherein the injecting step is such that the pressure under which said fluid mass is passed into said mold is higher than 0.5 bar.

3. A method according to claim 1, further including heating said injection mold to approximately said baking temperature prior to introduction of said fluid mass into said injection mold.

4. A method according to claim 1, wherein the step of heating said fluid mass includes raising the temperature of said injection mold to at least 240°

C.

5. A method according to claim 1, wherein the forming step includes forming said fluid mass such that it contains at least 20% water by weight.

6. A method according to claim 1, wherein the forming step includes forming said fluid mass such that it contains less than 20% of a filling material other than said natural fibers.

7. A method according to claim 1, wherein the heating step includes forming said molded product with cells substantially having a wall of natural polymers cross-linked during said heating, while the cell size across the wall thickness varies in such a manner that it decreases in an outward direction.

8. A method according to claim 1, wherein at least a part of said fibers added during said forming step is derived from recycled fibers.

9. A method according to claim 1, wherein at least a part of said fibers added during said forming step originates from annual plants.

10. A method according to claim 1, wherein at least a part of said fibers added during said forming step is coated.

11. A method according to claim 1, wherein the forming step includes forming said fluid mass with between 15% and 75% dry substance.

12. A method according to claim 1, wherein the heating step forms said product with a number of sheet, bar or dish-shaped parts each having in at least one direction a dimension that is relatively small with respect to the total dimensions of said product.

13. A method according to claim 1, wherein the forming step forms said fluid mass as a liquid batter, comprising a suspension or solution of at least said natural polymers.

14. A method according to claim 13, wherein the forming step includes forming said batter substantially of biocompatible constituents.

15. A method according to claim 1, wherein the forming step includes forming said fluid mass from a batter of at least water, said natural fibers and starch, and the heating step includes heating said mold to a temperature of more than 130°

C.

16. A method according to claim 1, wherein the injecting step includes introducing said fluid mass into said mold in a relatively dry condition.

17. A method according to claim 16, wherein the forming step includes slightly prefoaming said fluid mass prior to the introduction of said fluid mass into said mold without this giving rise to gelatinization.

18. A method according to claim 1, wherein the forming step includes forming said fluid mass with a blowing agent included in said fluid mass.

19. A method of manufacturing a molded product via extrusion molding with an extrusion die designed to form said molded product, said molded product having a blown, foamy structure, said method comprising:

forming a fluid mass outside said extrusion die, said fluid mass comprising a natural polymer and natural fibers;

maintaining said fluid mass when outside said extrusion die at temperatures below a gelatinization temperature such that substantially no gelatinization of said natural polymers occurs in said fluid mass;

continuously feeding said fluid mass under pressure through an orifice in said extrusion die;

heating said fluid mass while said fluid mass moves through said extrusion die to a baking temperature at least equal to or above said gelatinization temperature, to cause gelatinization and cross linking of said natural polymers to form said molded product with said natural fibers extending throughout; and

removing said molded product from said extrusion die.

20. A method according to claim 19, further including heating said extrusion die to approximately said baking temperature prior to feeding said fluid mass through said orifice.

21. A method according to claim 19, wherein the heating step includes forming said molded product with cells substantially having a wall of natural polymers cross-linked during said heating, while the cell size across the wall thickness varies in such a manner that it decreases in an outward direction.

22. A method according to claim 19, wherein the forming step includes forming said fluid mass from a batter of at least water, said natural fibers and starch, and the heating step includes heating said extrusion die to a temperature of more than 130°

C.

23. A method according to claim 19, wherein the forming step includes slightly prefoaming said fluid mass prior to the introduction of said fluid mass into said extrusion die without this giving rise to gelatinization.

24. A method according to claim 19, wherein the forming step includes forming said fluid mass with a blowing agent.