Fungicides for the control of take-all disease of plants
First Claim
Patent Images
1. A method of controlling disease in a plant caused by Gaeumannomyces sp. comprising applying to the plant locus a fungicidally effective amount of a fungicide of the formula wherein Z1 and Z2 are C and are part of an aromatic ring which is benzene;
- A is selected from the group consisting of —
C(X)-amine, wherein the amine is substituted with a first and a second amine substituent or with an alkylaminocarbonyl and a hydrogen;
—
C(O)—
SR3, —
NH—
C(X)R4, and —
C(═
NR3)—
XR7;
the first amine substituent is selected from the group consisting of C1-C10 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof optionally substituted with one or more halogen, hydroxy, alkoxy, alkylthio, nitrile, alkylsulfonate, haloalkylsulfonate, phenyl, a 5-membered heteroaryl, C3-C6 cycloalkyl and C5-C6 cycloalkenyl;
phenyl optionally substituted with one or more C1-C4 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof, cycloalkyl, cycloalkenyl, haloalkyl, alkoxy and nitro;
C3-C6 cycloalkyl, C5-C6 cycloalkenyl, alkoxy, alkenoxy, alkynoxy, dialkylamino, and alkylthio;
and the second amine substituent is selected from the group consisting of hydrogen, C1-C6 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof optionally substituted with one or more halogen;
hydroxy, alkylcarbonyl, haloalkylcarbonyl, alkoxycarbonyl, and dialkylphosphonyl;
B is —
Wm—
Q(R2)3 or selected from o-tolyl, 1-naphthyl, 2-naphthyl, and 9-phenanthryl, each optionally substituted with halogen or R4;
Q is C, Si, Ge, or Sn;
W is —
C(R3)pH(2−
p)—
;
or when Q is C, W is selected from —
C(R3)pH(2−
p)—
, —
N(R3)mH(1−
m)—
, —
S(O)p—
, and —
O—
;
X is O or S;
n is 0, 1, 2, or 3;
m is 0 or 1;
p is 0, 1, or 2;
each R is independently selected from a) halo, formyl, cyano, amino, nitro, thiocyanato, isothiocyanato, trimethylsilyl, and hydroxy;
b) C1-C4 alkyl, alkenyl, alkynyl, C3-C6 cycloalkyl, and cycloalkenyl, each optionally substituted with halo, hydroxy, thio, amino, nitro, cyano, formyl, phenyl, C1-C4 alkoxy, alkylcarbonyl, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, (alkylthio)carbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsufinyl, or alkylsulfonyl;
c) phenyl, furyl, thienyl, pyrrolyl, each optionally substituted with halo, formyl, cyano, amino, nitro, C1-C4 alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkylamino, dialkylamino, haloalkyl, and haloalkenyl;
d) C1-C4 alkoxy, alkenoxy, alkynoxy, C3-C6 cycloalkyloxy, cycloalkenyloxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkylcarbonylamino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, (alkylthio)carbonyl, phenylcarbonylamino, phenylamino, each optionally substituted with halo;
each R2 is independently selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl and phenyl, each optionally substituted with R4 or halogen; and
wherein, when Q is C, R2 may also be selected from halo, alkoxy, alkylthio, alkylamino, and dialkylamino;
wherein two R2 groups may be combined to form a cyclo group with Q;
R3 is C1-C4 alkyl;
R4 is C1-C4 alkyl, haloalkyl, alkoxy, alkylthio, alkylamino, or dialkylamino; and
R7 is C1-C4 alkyl, haloalkyl, or phenyl, optionally substituted with halo, nitro, or R4;
or an agronomic salt thereof.
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Abstract
A method of controlling Take-all disease of plants, by applying, preferably to the seeds prior to planting, a fungicide of the formula
wherein Z1, and Z2 are C and are part of an aromatic ring which is benzene.
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Citations
37 Claims
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1. A method of controlling disease in a plant caused by Gaeumannomyces sp. comprising applying to the plant locus a fungicidally effective amount of a fungicide of the formula
wherein Z1 and Z2 are C and are part of an aromatic ring which is benzene; -
A is selected from the group consisting of —
C(X)-amine, wherein the amine is substituted with a first and a second amine substituent or with an alkylaminocarbonyl and a hydrogen;
—
C(O)—
SR3, —
NH—
C(X)R4, and —
C(═
NR3)—
XR7;
the first amine substituent is selected from the group consisting of C1-C10 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof optionally substituted with one or more halogen, hydroxy, alkoxy, alkylthio, nitrile, alkylsulfonate, haloalkylsulfonate, phenyl, a 5-membered heteroaryl, C3-C6 cycloalkyl and C5-C6 cycloalkenyl;
phenyl optionally substituted with one or more C1-C4 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof, cycloalkyl, cycloalkenyl, haloalkyl, alkoxy and nitro;
C3-C6 cycloalkyl, C5-C6 cycloalkenyl, alkoxy, alkenoxy, alkynoxy, dialkylamino, and alkylthio;
and the second amine substituent is selected from the group consisting of hydrogen, C1-C6 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof optionally substituted with one or more halogen;
hydroxy, alkylcarbonyl, haloalkylcarbonyl, alkoxycarbonyl, and dialkylphosphonyl;
B is —
Wm—
Q(R2)3 or selected from o-tolyl, 1-naphthyl, 2-naphthyl, and 9-phenanthryl, each optionally substituted with halogen or R4;
Q is C, Si, Ge, or Sn;
W is —
C(R3)pH(2−
p)—
;
or when Q is C, W is selected from —
C(R3)pH(2−
p)—
, —
N(R3)mH(1−
m)—
, —
S(O)p—
, and —
O—
;
X is O or S;
n is 0, 1, 2, or 3;
m is 0 or 1;
p is 0, 1, or 2;
each R is independently selected from a) halo, formyl, cyano, amino, nitro, thiocyanato, isothiocyanato, trimethylsilyl, and hydroxy;
b) C1-C4 alkyl, alkenyl, alkynyl, C3-C6 cycloalkyl, and cycloalkenyl, each optionally substituted with halo, hydroxy, thio, amino, nitro, cyano, formyl, phenyl, C1-C4 alkoxy, alkylcarbonyl, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, (alkylthio)carbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsufinyl, or alkylsulfonyl;
c) phenyl, furyl, thienyl, pyrrolyl, each optionally substituted with halo, formyl, cyano, amino, nitro, C1-C4 alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkylamino, dialkylamino, haloalkyl, and haloalkenyl;
d) C1-C4 alkoxy, alkenoxy, alkynoxy, C3-C6 cycloalkyloxy, cycloalkenyloxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkylcarbonylamino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, (alkylthio)carbonyl, phenylcarbonylamino, phenylamino, each optionally substituted with halo;
each R2 is independently selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl and phenyl, each optionally substituted with R4 or halogen; and
wherein, when Q is C, R2 may also be selected from halo, alkoxy, alkylthio, alkylamino, and dialkylamino;
wherein two R2 groups may be combined to form a cyclo group with Q;
R3 is C1-C4 alkyl;
R4 is C1-C4 alkyl, haloalkyl, alkoxy, alkylthio, alkylamino, or dialkylamino; and
R7 is C1-C4 alkyl, haloalkyl, or phenyl, optionally substituted with halo, nitro, or R4;
or an agronomic salt thereof. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 31, 32, 33, 34)
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16. A compound of the formula
wherein Z1, and Z2 are C and are part of a benzene ring; -
A is selected from the group consisting of —
C(X)-amine, wherein the amine is substituted with a first and a second amine substituent or with an alkylaminocarbonyl and a hydrogen;
—
C(O)—
SR3, —
NH—
C(X)R4, and —
(═
NR3)—
XR7;
the first amine substituent is selected from the group consisting of C1-C10 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof optionally substituted with one or more halogen, hydroxy, alkoxy, alkylthio, nitrile, alkylsulfonate, haloalkylsulfonate, phenyl, a 5-membered heteroaryl, C3-C6 cycloalkyl and C5-C6 cycloalkenyl;
phenyl optionally substituted with one or more C1-C4 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof, cycloalkyl, cycloalkenyl, haloalkyl, alkoxy and nitro;
C3-C6 cycloalkyl, C5-C6 cycloalkenyl, alkoxy, alkenoxy, alkynoxy, dialkylamino, and alkylthio;
and the second amine substituent is selected from the group consisting of hydrogen, C1-C6 straight or branched alkyl, alkenyl, or alkynyl groups or mixtures thereof optionally substituted with one or more halogen;
hydroxy, alkylcarbonyl, haloalkylcarbonyl, alkoxycarbonyl, and dialkylphosphonyl;
B is —
Wm—
Q(R2)3 or selected from o-tolyl, 1-naphthyl, 2-naphthyl, and 9-phenanthryl, each optionally substituted with halogen or R4;
Q is C, Si, Ge, or Sn;
W is —
C(R3)pH(2−
p)—
;
or when Q is C, W is selected from —
C(R3)pH(2−
p)—
, —
N(R3)mH(1−
m)—
, —
S(O)p—
, and —
O—
;
X is O or S;
n is 0, 1, 2, or 3;
m is 0 or 1;
p is 0, 1, or 2;
each R is independently selected from a) halo, formyl, cyano, amino, nitro, thiocyanato, isothiocyanato, trimethylsilyl, and hydroxy;
b) C1-C4 alkyl, alkenyl, alkynyl, C3-C6 cycloalkyl, and cycloalkenyl, each optionally substituted with halo, hydroxy, thio, amino, nitro, cyano, formyl, phenyl, C1-C4 alkoxy, alkylcarbonyl, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, (alkylthio)carbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsufinyl, or alkylsulfonyl;
c) phenyl, furyl, thienyl, pyrrolyl, each optionally substituted with halo, formyl, cyano, amino, nitro, C1-C4 alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkylamino, dialkylamino, haloalkyl, and haloalkenyl;
d) C1-C4 alkoxy, alkenoxy, alkynoxy, C3-C6 cycloalkyloxy, cycloalkenyloxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkylcarbonylamino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, (alkylthio)carbonyl, phenylcarbonylamino, phenylamino, each optionally substituted with halo;
each R2 is independently selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl and phenyl, each optionally substituted with R4 or halogen; and
wherein, when Q is C, R2 may also be selected from halo, alkoxy, alkyloxy, alkylthio, alkylamino, and dialkylamino;
wherein two R2 groups may be combined to form a cyclo group with Q;
R3 is C1-C4 alkyl;
R4 is C1-C4 alkyl, haloalkyl, alkoxy, alkylthio, alkylamino, or dialkylamino; and
R7 is C1-C4 alkyl, haloalkyl, or phenyl, optionally substituted with halo, nitro, or R4;
or an agronomic salt thereof;
provided that when A is —
C(X)amine and B is —
C(R2)3, the compound is notN-phenyl-2-(tert-butyl)benzamide, N,N-dimethyl-2-(tert-butyl)benzamide, N,N-dimethyl-2-(tert-butyl)thiobenzamide, N-methyl-N-(2-methoxyphenyl)-2-(tert-butyl)benzamide, N,N-(didecyl)-2,4-di(tert-butyl)-6-hydroxybenzamide, N,N-dimethyl-2,4,6-tri(tert-butyl)benzamide, N-methyl-2,4,6-tri(tert-butyl)benzamide, N-methyl-N-benzyl-2,4,6-tri(tert-butyl)benzamide, N-phenyl-2,4,6-tri(tert-butyl)benzamide, 2,4,6-tri(tert-butyl)benzoyl imidazolide, N-benzyl-2,4,6-tri(tert-butyl)benzamide, or N-(tert-butyl)-2,4,6-tri(tert-butyl)benzamide;
further provided that when A is —
NH—
C(X)R4 and B is —
C(R2)3, the compound is notN-acetyl-2,4-dimethyl-6-(tert-butyl)aniline, N-acetyl-2-(tert-butyl)-5-(acetylamino)aniline, N-acetyl-2,6-di(tert-butyl)-4-nitroaniline, N-acetyl-2,6-di(tert-butyl)-4-(acetylamino)aniline, N-acetyl-2,4,-di(tert-butyl)-5-nitro-6-methylaniline, N-(bromoacetyl)-2-(1,1-dimethylbutyl)-5,6-dimethylaniline, N-(chloroacetyl)-2-(1,1-dimethylbutyl)-5,6-dimethylaniline, N-(chloroacetyl)-2-(1,1-dimethylpropyl)-5,6-dimethylaniline, N-(iodoacetyl)-2-(tert-butyl)-5,6-dimethylaniline, N-(bromoacetyl)-2-(tert-butyl)-5,6-dimethylaniline, N-(chloroacetyl)-2-(1,1,3,3-tetramethylbutyl)-6-methylaniline, N-(iodoacetyl)-2-(tert-butyl)-6-methoxyaniline, N-(chloroacetyl)-2-(tert-butyl)-5-methylaniline, N-(bromoacetyl)-2-(tert-butyl)-5-methylaniline, N-(bromoacetyl)-2,6-di(tert-butyl)aniline, N-(chloroacetyl)-2-(1,1-dimethylbutyl)-6-methylaniline, N-(chloroacetyl)-2-(tert-butyl)-6-isopropylaniline, N-(bromoacetyl)-2-(1,1,-dimethylbutyl)-6-methylaniline, N-(bromoacetyl)-2-(tert-butyl)-6-isopropylaniline, N-(chloroacetyl)-2-(1,1-dimethylpropyl)-6-methylaniline, N-(bromoacetyl)-2-(1,1-dimethylpropyl)-6-methylaniline, N-(bromoacetyl)-2-(tert-butyl)-6-methoxyaniline, N-(chloroacetyl)-2-(tert-butyl)-5-nitro-6-methylaniline, N-(bromoacetyl)-2-(tert-butyl)-5-chloro-6-methylaniline, N-acetyl-2-(tert-butyl)-4-chloroaniline, N-acetyl-2-(tert-butyl)-4,6-dibromoaniline, N-acetyl-2-(tert-butyl)-6-(chloromethyl)aniline, N-acetyl-2-(tert-butyl)-4-(diethylamino)aniline, N-acetyl-2-(1,1-dimethylbenzyl)-4-methylaniline, N-(isopropylcarbonyl)-2-(1,1-dimethylbenzyl)-4-methylaniline, N-(tert-butylcarbonyl)-2-(1,1-dimethylbenzyl)-4-methylaniline, N-acetyl-2-(tert-butyl)aniline, N-acetyl-2,4-di(tert-butyl)-6-methylaniline, N-(ethoxycarbonyl)-2-(tert-butyl)aniline, N-acetyl-2,4-di(tert-butyl)aniline, N-acetyl-2,4-di(tert-butyl)-6-chloroaniline, N-acetyl-2,4-di(tert-butyl)-6-bromoaniline, N-acetyl-2,4-di(tert-butyl)-6-iodoaniline, N-(ethoxycarbonyl)-2,4,6-tri(tert-butyl)aniline, N-(dimethylaminocarbonyl)-2,4,6-tri(tert-butyl)aniline, N-acetyl-2,4,6-tri(tert-butyl)aniline, N-(1-bromoethylcarbonyl)-2-(tert-butyl)aniline, N-acetyl-2,4-di(1,1,2,2-tetramethylpropyl)aniline, N-(methoxycarbonyl)-2,4-di(tert-butyl)-6-isopropylaniline, N-acetyl-2,5,-di(tert-butyl)-3-acetoxy-6-hydroxyaniline, N-acetyl-2,5-di(tert-butyl)-4-acetoxy-6-hydroxyaniline, N-(chloroacetyl)-2-(tert-butyl)-6-methylaniline, N-acetyl-2,4-di(tert-butyl)-6-nitroaniline, N-acetyl-2,4-di(tert-butyl)-5-methoxyaniline, N-acetyl-2-(tert-butyl)-5-methoxycarbonyl-6-nitroaniline, N-acetyl-2-(tert-butyl)-4-nitro-5-(methoxycarbonyl)aniline, N-acetyl-2,5-di(tert-butyl)-4-acetoxyaniline, N-(propionyl)-2-(tert-butyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-ethylaniline, N-acetyl-2,4-di(tert-butyl)-6-hydroxyaniline, N-(bromoacetyl)-2-(tert-butyl)-6-methylaniline, N-acetyl-2,5-di(tert-butyl)-4,6-dinitroaniline, N-acetyl-2,5-di(tert-butyl)-4-nitroaniline, N-acetyl-2,5-di(tert-butyl)aniline, N-(bromoacetyl)-2-(tert-butyl)-6-ethylaniline, N-(iodoacetyl)-2-(tert-butyl)-6-ethylaniline, N-(iodoacetyl)-2,6-di(tert-butyl)aniline, N-acetyl-2-(tert-butyl)-5-chloroaniline, N-(tert-butyl)-N′
-[2,5-di(tert-butyl)phenyl]thiourea,N-(tert-butyl)-N′
-[2,5-di(tert-butyl)-4-methoxyphenyl]thiourea,N-(tert-butyl)-N′
-[2,5-di(tert-butyl)-4-chlorophenyl]thiourea,N-isopropyl-N′
-[2,5-di(tert-butyl)phenyl]thiourea,N-(tert-butyl)-N′
-[2-(tert-butyl)-4-bromo-5-methoxyphenyl]thiourea,N-(tert-butyl)-N′
-[2-(tert-butyl)-5-(methylthio)phenyl]thiourea,N-(tert-butyl)-N′
-[2-(tert-butyl)-5-(tert-butoxycarbonyl)phenyl]thiourea,N-(tert-butyl)-N′
-[2,5-di(tert-butyl)-4-bromophenyl]thiourea,N-isopropyl-N′
-[2,5-di(tert butyl)-4-chlorophenyl]thiourea,N-(tert-butyl)-N′
-[5-(tert-butyl)-1,3-dihydro-1,1-dimethyl-4-isobenzofuranyl]thiourea,N-(tert-butyl)-N′
-[2-(tert-butyl)-4-bromo-6-methylphenyl]thiourea,N-(chloroacetyl)-2-(tert-butyl)-5-(chloroacetylamino)-6-methylaniline, N-(chloroacetyl)-2-(tert-butyl)-4-methyl-5-(chloroacetylamino)aniline, N-(chloroacetyl)-2-(tert-butyl)-4-(chloroacetylamino)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-formylaniline, N-(chloroacetyl)-2-(tert-butyl)-5,6-dimethylaniline, N-(chloroacetyl)-2-(tert-butyl)-6-(methoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(ethoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(isopropoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(butoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-propoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(dimethoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-5,6-bis(methoxymethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-[(tert-butoxy)methyl]aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(bromomethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-5,6-bis(bromomethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-3-chloro-6-methylaniline, N-(chloroacetyl)-2-(tert-butyl)-6-(dibromomethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-5-chloro-6-(bromomethyl)aniline, N-(chloroacetyl)-2-(tert-butyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-methoxyaniline, N-(chloroacetyl)-2-(tert-butyl)-6-(methoxycarbonyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(ethoxycarbonyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(isopropoxycarbonyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(tert-butoxycarbonyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-(tert-amyloxycarbonyl)aniline, S-methyl-N-[2-(tert-butyl)-6-methylphenyl]thiocarbamate, N-acetyl-2-(tert-butyl)-4-bromoaniline, N-(1-methylpropyl)-N′
-[2,4,-di(tert-butyl)-6-methylphenyl]thiourea,N-(tert-butyl)-N′
-[2,4-di(tert-butyl)-6-methylphenyl]thiourea,N-isopropyl-N′
-[2,4-di(tert-butyl)-6-methylphenyl]thiourea,N-methyl-N′
-[2-(tert-butyl)phenyl]thiourea,N-acetyl-2-(tert-butyl)-4-(bromomethyl)aniline, N-(bromoacetyl)-2-(tert-butyl)aniline, N-(chloroacetyl)-2-(tert-butyl)-6-chloroaniline, N-(bromoacetyl)-2-(tert-butyl)-6-chloroaniline, N-(chloroacetyl)-2-(tert-amyl)aniline, N-(chloroacetyl)-2-(1,1-dimethylbutyl)aniline, N-(iodoacetyl)-2-(tert-butyl)aniline, 1-(bromoacetylamino)-2-(tert-butyl)napthalene, 1-(chloroacetylamino)-2-(tert-butyl)napthalene, N-acetyl-2-(tert-butyl)-4-hydroxyaniline, N-propionyl-2-(tert-butyl)-4-hydroxyaniline, N-propionyl-2-(tert-butyl)-4-butoxyaniline, N-(chloroacetyl)-2-(2,4,4,5-tetramethyl-1,3-dioxolan-2-yl)-6-methylaniline, N-(chloroacetyl)-2-(2-methyl-4-ethyl-1,3-dioxolan-2-yl)-6-methylaniline, N-(chloroacetyl)-2-(2-methyl-1,3-dioxolan-2-yl)-6-methylaniline, N-(chloroacetyl)-2-(2,4,5-trimethyl-1,3-dioxolan-2-yl)-6-methylaniline, N-(chloroacetyl)-2-(2-methyl-4,5-diethyl-1,3-dioxolan-2-yl)-6-methylaniline, N-(chloroacetyl)-2-(2,4-dimethyl-1,3-dioxolan-2-yl)-6-methylaniline, N-(chloroacetyl)-2-(1,1-dimethoxyethyl)-6-methylaniline, N-(chloroacetyl)-2-(1-ethoxy-1-methylethyl)-6-methylaniline, N-(chloroacetyl)-2-(1-propoxy-1-methylethyl)-6-methylaniline, N-(chloroacetyl)-2-(1-methoxy-1-methylpentyl)-6-methylaniline, N-(chloroacetyl)-2-(1-methoxy-1-ethylpropyl)-6-methylaniline, N-(chloroacetyl)-2-(1-methoxy-1,2-dimethylpropyl)-6-methylaniline, N-(chloroacetyl)-2-(1-methoxy-1-methylethyl)-6-methylaniline, N-(chloroacetyl)-2-(2-methyl-1,3-dioxolan-2-yl)-6-ethylaniline, N-(chloroacetyl)-2-(2-methyl-1,3-dioxan-2-yl)-6-ethylaniline, N-(chloroacetyl)-2-(2-methyl-1,3-dioxolan-2-yl)-6-isopropylaniline, N-(chloroacetyl)-2-(2,4,5-trimethyl-1,3-dioxolan-2-yl)-6-isopropylaniline, N-(chloroacetyl)-2-(2,4,5-trimethyl-1,3-dioxolan-2-yl)-6-ethylaniline, or N-acetyl-2-(1-methoxy-1-methylethyl)aniline;
further provided that when A is —
C(═
NR3)—
XR7 and B is —
C(R2)3, the compound is notN-methyl-O-methyl-2,4,6-tri(tert-butyl)benzimidate;
further provided that when A is —
C(X)amine and B is —
WC(R2)3 where R2 is C, N, O, or S groups and W is C, O, N, or S(O)p, the compound is notN,N-diethyl-2-(tert-butylsulfonyl)benzamide, N,N-diethyl-2-(tert-butylsulfinyl)benzamide, N-phenyl-2-(tert-butylsulfinyl)benzamide, N-phenyl-2-(tert-butylsulfinyl)-5-nitrobenzamide, N-phenyl-2-(tert-butylsulfonyl)benzamide, N,N-diethyl-2-(tert-butylsulfonyl)-3-methylbenzamide, N-methyl-2-(tert-butylsulfinyl)benzamide, N,N-diethyl-2-(tert-butylamino)benzamide, 1-[2-(tert-butylamino)benzoyl]pyrazole, N-(2-bromo-4-methylphenyl)-2-(tert-butylthio)benzamide, N-hydroxy-N-methyl-2-(tert-butylthio)benzamide, or N-phenyl-2-neopentyl-3-methylbenzamide;
further provided that when A is —
NH—
C(X)R4 and B is —
WC(R2)3 where R2 is C, N, O, or S groups and W is C, O, N, or S(O)p, the compound is notN-acetyl-2-neopentylaniline, N-chloroacetyl-2-(tert-butylamino)-3-chloroaniline, N-acetyl-2-(1,1,3,3-tetramethylbutoxy)-5-nitroaniline, N-(tert-butoxycarbonyl)-2-(tert-butylsulfonyl)benzamide, N-(tert-butoxycarbonyl)-2-(tert-butylsulfonyl)-3-methylaniline, N-acetyl-2-(tert-butylsulfonyl)aniline, or N-acetyl-2-(tert-butylthio)aniline. - View Dependent Claims (17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 35, 36, 37)
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Specification