Method for making microencapsulated gyricon beads

• US 6,524,500 B2
• Filed: 12/28/2000
• Issued: 02/25/2003
• Est. Priority Date: 12/28/2000
• Status: Expired due to Fees

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Sheridon, Nicholas K., Khonsari, Nassim, Chopra, Naveen
• Primary Examiner(s): Vargot, Mathieu D.
• Application Number:
  US09/749,379
• Publication Number:
  US 20020084539A1
• Time in Patent Office: 789 Days
• Field of Search: 264/4, 264/4.4, 264/7, 264/8, 264/1.7, 264/2.1, 425/8, 425/6
• US Class Current: 264/1.7
• CPC Class Codes: B01J 13/02 Making microcapsules or microballoons for medical preparations A61K9/50
• CPC Class Codes: G02B 26/026 based on the rotation of particles under the influence of an external field, e.g. gyricons, twisting ball displays based on orientable dipolar particles G02F1/172; based on electrophoresis G02F1/167

Abstract

A method for making microencapsulated gyricon beads comprising the steps of converging a first, second, third and fourth materials in a liquid state; forming a bead from the first and second materials, the bead having two hemispheric surfaces with one surface differing from the other in optical and electrical characteristics; surrounding the bead with the third material; encapsulating the third material with the fourth material; and solidifying the fourth material.

Claims

1. A method for making a microencapsulated gyricon bead comprising:

converging first, second, third and fourth materials in a liquid state;

forming a bead from the coalescing of the first and second materials, which have substantially the same surface tension, the formed bead having two hemispherical surfaces with one surface differing from the other in optical and electrical characteristics;

surrounding the bead with the third material by the coalescing of the third material around the bead, the third material having a surface tension less than the first material and the second material and having a melting temperature greater than the first material and the second material;

encapsulating the third material with the fourth material by coalescing of the fourth material around the third material, the fourth material having a surface tension less than the surface tension of the third material; and

,

solidifying the fourth material.

2. The method of claim 1, wherein converging the first, second, third and fourth materials comprises introducing the first, second, third and fourth materials to disks of a multiple disk bead generator;

and rotating the disks wherein the first, second, third and fourth materials exit disks and converge.

3. The method of claim 1, wherein the first material has a melting temperature that is less than a melting temperature of the fourth material.

4. The method of claim 1, wherein, during encapsulating the third material, the third material has a viscosity that is greater than a viscosity of the fourth material.

5. The method of claim 1, wherein, during converging of the first, second, third and fourth materials, a temperature of the third material is less than a temperature of the fourth material.

6. The method of claim 1, wherein, during converging of the first, second, third and fourth materials, a temperature of the first material is less than a temperature of the third material.

7. The method of claim 1, wherein, during converging of the first, second, third and fourth materials, a temperature of the second material is less than a temperature of the third material.

8. The method of claim 1, wherein solidifying the fourth material comprises cooling the fourth material using ambient air.

9. The method of claim 1, wherein converging the first, second, third and fourth materials comprises converging at least a first layer of each of the first and second materials and at least two layers of each of the third and fourth materials.

10. The method of claim 9, wherein:

a first one of the at least two layers of the third material is adjacent to one of the first and second materials; and

,

a second one of the at least two layers of the third material is adjacent to the other of the first and second materials.

11. The method of claim 10, wherein, surrounding the bead comprises flowing at least the first and second layers of the third material around both of the first and second materials.

12. The method of claim 9, wherein:

a first one of the at least two layers of the fourth material is adjacent to a first one of the at least two layers of the third material; and

,

a second one of the at least two layers of the fourth material is adjacent to a second one of the at least two layers of the third material.

13. The method of claim 12, wherein encapsulating the third material comprises flowing at least the first and second layers of the fourth material around the third material.

14. A method for making a microencapsulated gyricon bead, comprising:

introducing a first, second, third and fourth materials in a liquid state on separate surfaces of a multi-disc spinner; and

,

rotating the multi-disc spinner to eject and converge the first, second, third and fourth materials from the multi-disc spinner, wherein;

the first material and the second material have substantially the same surface tension so as to coalesce to form a bead having two hemispheric surfaces with one surface differing from the other in an optical characteristic and a second characteristic;

the third material has a surface tension less than the first material and the second material so that it surrounds the bead; and

the fourth material encapsulates the third material to form the microencapsulated gyricon bead by coalescing of the fourth material around the third material, the fourth material having a surface tension less than the surface tension of the third material.

15. A method for manufacturing an encapsulated bead, comprising:

converging a first, second, third and fourth materials in a liquid state; and

cooling the first, second, third and fourth materials, wherein;

the first and second materials are converged adjacent one another,

the third material includes a first layer and a second layer with the first layer converged adjacent the first material and the second layer converged adjacent the second material;

the fourth material includes a first layer and a second layer with the first layer converged adjacent the first layer of the third material and the second layer converged adjacent the second layer of the third material;

the first, second, third and fourth materials each have a surface tension while in a liquid state;

the surface tension of the third material is less than the surface tension of the first material and the surface tension of the second material and the surface tension of the first material and the second material are substantially equal so that the first and second materials coalesce to form a bead and the third material coalesces to surround the bead, which is formed to have two hemispheric surfaces with one surface differing from the other in an optical characteristic and a second characteristic;

the surface tension of the fourth material is less than the surface tension of the third material so that the fourth material engulfs the third material; and

the first, second and third materials solidify during the cooling step to form the encapsulated bead.

16. The method as recited in claim 15, wherein the second characteristic is an electrical characteristic.